Abstract
Porous α-Al2O3 thermal barrier coatings (TBCs) containing dispersed Pt particles were prepared by cathode plasma electrolytic deposition (CPED). The influence of the Pt particles on the microstructure of the coatings and the CPED process were studied. The prepared coatings were mainly composed of α-Al2O3. The average thickness of the coatings was approximately 100 μm. Such single-layer TBCs exhibited not only excellent high-temperature cyclic oxidation and spallation resistance, but also good thermal insulation properties. Porous α-Al2O3 TBCs inhibit further oxidation of alloy substrates because of their extremely low oxygen diffusion rate, provide good thermal insulation because of their porous structure, and exhibit excellent mechanical properties because of the toughening effect of the Pt particles and because of stress relaxation induced by deformation of the porous structure.
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X.F. Zhang, K.S. Zhou, X. Wei, B.Y. Chen, J.B. Song, and M. Liu, In situ synthesis of α-alumina layer at top yttrium-stabilized zirconia thermal barrier coatings for oxygen barrier, Ceram. Int., 40(2014), No. 8, p. 12703.
R.A. Miller, Thermal barrier coatings for aircraft engines: history and directions, J. Therm. Spray Technol., 6(1997), No. 1, p. 35.
J. Cai, Q.F. Guan, S.Z. Yang, S. Yang, Z.P. Wang, and Z.Y. Han, Microstructural characterization of modified YSZ thermal barrier coatings by high-current pulsed electron beam, Surf. Coat. Technol., 254(2014), p. 187.
Y. Suzuki, Phase transition temperature of ZrO2–Y2O3 solid solutions (2.4–6 mol% Y2O3), Solid State Ionics, 95(1997), No. 3-4, p. 227.
A. Cipitria, I.O. Golosnoy, and T.W. Clyne, A sintering model for plasma-sprayed zirconia TBCs: Part I. Free-standing coatings, Acta Mater., 57(2009), No. 4, p. 980.
K.W. Schlichting, K. Vaidyanathan, Y.H. Sohn, E.H. Jordan, M. Gell, and N.P. Padture, Application of Cr3+ photoluminescence piezo-spectroscopy to plasma-sprayed thermal barrier coatings for residual stress measurement, Mater. Sci. Eng. A, 291(2000), No. 1-2, p. 68.
W. Ma, S.K. Gong, H.B. Xu, and X.Q. Cao, The thermal cycling behavior of lanthanum–cerium oxide thermal barrier coating prepared by EB-PVD, Surf. Coat. Technol., 200(2006), No. 16-17, p. 5113.
P. Ctibor, P. Boháč, M. Stranyánek, and R. Čtvrtlík, Structure and mechanical properties of plasma sprayed coatings of titania and alumina, J. Eur. Ceram. Soc., 26(2006), No. 16, p. 3509.
A. Pragatheeswaran, P.V. Ananthapadmanabhan, Y. Chakravarthy, S. Bhandari, T.K. Thiyagarajan, N. Tiwari, T.K. Saha, and K. Ramachandran, Plasma spray deposition and characterization of strontium zirconate coatings, Ceram. Int., 40(2014), No. 7, p. 10441.
F. Cipri, F. Marra, G. Pulci, J. Tirillò, C. Bartuli, and T. Valente, Plasma sprayed composite coatings obtained by liquid injection of secondary phases, Surf. Coat. Technol., 203(2009), No. 15, p. 2116.
E. Reinhold, P. Botzler, and C. Deus, EB-PVD process management for highly productive zirconia thermal barrier coating of turbine blades, Surf. Coat. Technol., 120-121(1999), p. 77.
H.B. Xu, S.K. Gong, and L. Deng, Preparation of thermal barrier coatings for gas turbine blades by EB-PVD, Thin Solid Films, 334(1998), No. 1, p. 98.
D. Zhao, F. Luo, W.C. Zhou, and D.M. Zhu, Effect of critical plasma spray parameter on complex permittivity and microstructure by plasma spraying Cr/Al2O3 coatings, Appl. Surf. Sci., 264(2013), p. 545.
D.L. Youchison, M.A. Gallis, R.E. Nygren, J.M. McDonald, and T.J. Lutz, Effects of ion beam assisted deposition, beam sharing and pivoting in EB-PVD processing of graded thermal barrier coatings, Surf. Coat. Technol., 177-178(2004), p. 158.
J. Baszkiewicz, D. Krupa, J. Mizera, J.W. Sobczak, and A. Biliński, Corrosion resistance of the surface layers formed on titanium by plasma electrolytic oxidation and hydrothermal treatment, Vacuum, 78(2005), No. 2-4, p. 143.
M. Javidi and H. Fadaee, Plasma electrolytic oxidation of 2024-T3 aluminum alloy and investigation on microstructure and wear behavior, Appl. Surf. Sci., 286(2013), p. 212.
X.Z. Yang, Y.D. He, D.R. Wang, and W. Gao, Cathodic micro- arc electrodeposition of thick ceramic coatings, Electrochem. Solid- State Lett., 5(2002), No. 3, p. C33.
X. Nie, C. Tsotsos, A. Wilson, A.L. Yerokhin, A. Leyland, and A. Matthews, Characteristics of a plasma electrolytic nitrocarburising treatment for stainless steels, Surf. Coat. Technol., 139(2001), No. 2-3, p. 135.
E. Bahadori, S. Javadpour, M.H. Shariat, and F. Mahzoon, Preparation and properties of ceramic Al2O3 coating as TBCs on MCrAly layer applied on Inconel alloy by cathodic plasma electrolytic deposition, Surf. Coat. Technol., 228(2013), No. S1, p. S611.
T. Paulmier, J.M. Bell, and P.M. Fredericks, Development of a novel cathodic plasma/electrolytic deposition technique part 1: Production of titanium dioxide coatings, Surf. Coat. Technol., 201(2007), No. 27, p. 8761.
X. Pang, I. Zhitomirsky, and M. Niewczas, Cathodic electrolytic deposition of zirconia films, Surf. Coat. Technol., 195(2005), No. 2-3, p. 138.
T. Paulmier, J.M. Bell, and P.M. Fredericks, Deposition of nano-crystalline graphite films by cathodic plasma electrolysis, Thin Solid Films, 515(2007), No. 5, p. 2926.
Y.L. Wang, Z.H. Jiang, X.R. Liu, and Z.P. Yao, Influence of treating frequency on microstructure and properties of Al2O3 coating on 304 stainless steel by cathodic plasma electrolytic deposition, Appl. Surf. Sci., 255(2009), No. 21, p. 8836.
J. Wu, W.B. Xue, B. Wang, X.Y. Jin, J.C. Du, and Y.L. Li, Characterization of carburized layer on T8 steel fabricated by cathodic plasma electrolysis, Surf. Coat. Technol., 245(2014), p. 9.
S. Zhou, Y.D. He, D.R. Wang, and J. Yang, Al2O3–YAG composite coating deposited by cathodic plasma electrolysis and its high-temperature oxidation resistance, Trans. Mater. Heat Treat., 34(2013), No. 12, p. 171.
X.X. Ma, Y.D. He, and D.R. Wang, Preparation and high-temperature properties of Au nano-particles doped α-Al2O3 composite coating on TiAl-based alloy, Appl. Surf. Sci., 257(2011), No. 23, p. 10273.
P. Gupta, G. Tenhundfeld, E.O. Daigle, and D. Ryabkov, Electrolytic plasma technology: science and engineering — an overview, Surf. Coat. Technol., 201(2007), No. 21, p. 8746.
A.L. Yerokhin, X. Nie, A. Leyland, A. Matthews, and S.J. Dowey, Plasma electrolysis for surface engineering, Surf. Coat. Technol., 122(1999), No. 2-3, p. 73.
J.C. Maxwell, A Treatise on Electricity and Magnetism, Cambridge University Press, UK, 2010, p. 1881.
A.V. Hippel, Dielectrics and Waves, Artech House, USA, 1994, p. 278.
J.I. Gersten and F.W. Smith, The Physics and Chemistry of Materials, Wiley, New York, 2001, p. 96.
I. Bunget, Physics of Solid Dielectrics, Elsevier Science Ltd, Amsterdam, 1984, p. 142.
F. Zhu, J.W. Wang, S.H. Li, and J. Zhang, Preparation and characterization of anodic films on AZ31B Mg alloy formed in the silicate electrolytes with ethylene glycol oligomers as additives, Appl. Surf. Sci., 258(2012), p. 8985
S.P. Timoshenko, Analysis of bi-metal thermostats, J. Opt. Soc. Amer., 11(1925), p. 233.
H.E. Evans, Cracking and spalling of protective oxide layers, Mater. Sci. Eng. A, 120-121 (1989), p. 139.
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Wang, P., He, Yd., Deng, Sj. et al. Porous α-Al2O3 thermal barrier coatings with dispersed Pt particles prepared by cathode plasma electrolytic deposition. Int J Miner Metall Mater 23, 92–101 (2016). https://doi.org/10.1007/s12613-016-1215-2
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DOI: https://doi.org/10.1007/s12613-016-1215-2