Abstract
Poly(dimethylsiloxane- c o-methyl-hydridosiloxane) (PDMSMHS) with a OSi(CH 3) 2/OSi(HCH 3) molar ratio of 21:1 was functionalized with dimethylallylamine (DMAA) via catalytic hydrosilylation using Karstedt’s catalyst and then quaternized with 1-iodooctane. The functionalized and quaternized co-polysiloxanes (PDMSMHS-1 and PDMSMHS-QAS) were characterized using 1H, 13C and 29Si NMR. The physicochemical properties of the polymeric systems (the differential refractive index increment (dn/dc), the square root of the mean square radius of gyration \((< RMS_{\text {radius}}^{2}>^{1/2})\), the average molecular weight (M), and the second virial coefficient (A 2)) were measured in ethanol using gel permeation chromatography/light scattering (GPC/LS). The low percentage (3–4 %) of amino side groups has an unexpected effect on the co-polymers physicochemical properties because the A 2 experimental value for PDMSMHS-1 and PDMSMHS-QAS (8.87×10−3and 1.51×10−2molmLg −2, respectively) indicates that ethanol is a good solvent.
Similar content being viewed by others
References
West R, Allcock H, Mark J (2005) Polysiloxanes and Related Polymers, Inorganic Polymers, 2nd edn. Oxford University Press, New York, p 154
Jones G, Wataru A, Chojnowski J (2001) Silicon Containing Polymers and Technology of their Synthesis and Applications. Kluwer, Dordretch, pp 17–42, 185–213
Vallejo-Montesinos J, Villegas A, Jacobo-Azuara A, MartÃnez JM, RamÃrez E, Cervantes J (2012) J Inorg Organomet Polym 22(4):671–928
Gaspar PP, West R (1998). In: Rappoport Z, Apeloig Y (eds) In The Chemistry of Organic Silicon Compounds, vol 2, 2nd edn. John Wiley and Sons, New York, pp pp 2463-2568. Chapter 43
Villegas JA, Cervantes J (2006) Revista Mexicana de FÃsica 52(6):507–514
MacKenzie-Kenneth JD, Komphanchai S, Fletcher RA (2008) Ceram Eng Sci Proc 28(9):249–256
Gonzaga F, Yu G, Brook MA (2009) Chem Commun 13:1730–1732
Rahimi A, Shokrolahi P (2001) Int J Inorg Mater 3:843–847
De Jaeger R, Gleria M (2007) Inorganic Polymers, Nova Science Publishers, Chapter 2: Silicones in Industrial Applications, pp. 61-161
Villegas JA, Olayo R, Cervantes J (2003) J Inorg Organomet Polym 13(4):205–222
Loos K, Jonas G, Stadler R (2001) Macromol Chem Phys 202:3210–3218
Marciniec B (1992) Comprehensive Handbook on Hydrosilylation, 1st edn. Pergamon Press, Oxford
Safa KD, Tofangdarzadeh S, Hassanpour A (2009) J Organomet Chem 694:4107–4115
Xu Y, Tang S (2001) Huagong Jinzhan 20(1):31–35
Putzien S, Nuyken O, Kühn FE (2010) Prog Polym Sci 35:687–713
Jankowiak M, Maciejewski H, Gulinski J (2005) J Organomet Chem 690:4478–4487
Zak P, Skrobanska M, Pietraszuk C, Marciniec B (2009) J Organomet Chem 694:1903–1906
Cui M, Li Z, Huang X, Xi J, Tang X, Zheng S (2005) Polymer 46:9162–9169
Teixeira A, Guardani R, Braun A, Oliveros E, Nascimento C (2005) Chem Eng Process 44:923–931
Xie K, Hou A, Shi Y, Yu J (2007) Color Technol 123:293–297
Yahaya GO, Brisdon BJ, Maxwell M, England R (2001) J Appl Polym Sci 82:808–817
Abe Y, Gunji T (2004) Prog Polym Sci 29:149–182
Xie K, Yu J, Jiang D (2007) J Appl Polym Sci 106:1256–1262
Hou A, Yu J, Shi Y (2008) Eur Polym J 44:1696–1700
Bes L, Huan K, Khoshdel E, Lowe M, McConville C, Haddleton D (2003) Eur Polym J 39:5–13
David P, Dworak M, Soucek D (2007) Macromol Chem Phys 208:2502–2509
Yining L, Paschalis A (2002) J Phys Chem B 106:10845–10853
Kongliang X, Yanhong Y, Hongdong L (2010) J Dispersion Sci Technol 31:1344–1349
Kongliang X, Keyu H, Yi C (2010) Iran Polym J 19(6):447–455
Hou A, Si C (2010) J Dispersion Sci Technol 31:102–107
Majumdar P, Lee E, Patel N, Stafslien SJ, Daniels J, Chisholm BJ (2008) J Coat Technol Res 5(4):405–417
Jun-Jie K, Wei-Ying L, Yuan L, Xue-Oing L, Xu-Rui X, Shi-Bi F (2004) Polym Adv Technol 15:61–64
Kongliang X, Lei X, Yaqi S (2008) Journal of Fiber Bioengineering and Informatics 1(2):151–156
Ye S, Majumdar P, Chisholm B, Stafslien S, Chen Z (2010) Langmuir 26(21):16455–16462
Majumdar P, et al. (2008) Biofouling: The Journal of Bioadhesion and Biofilm Research 24(3):185–200
Hou A, Shi Y (2009) Mater Sci Eng B 163:99–104
Vallejo-Montesinos J, Villegas A, Jacobo-Azuara A, MartÃnez JM, RamÃrez-Oliva E, Romero-Izquierdo A, Cervantes J (2012) J Appl Organomet Chem 26:362–368
Huglin MB (2003) Light scattering from Polymer Solutions. J Polym Science, Polym Lett Ed. doi:10.1002/pol.1973.130110113
Byoung GK et al. (2008) Macromol Res 16(1):36–44
Huglin MB, Sokro MB (1980) Polymer 21:651
Edwards CJC, Stepto RFT, Semlyen JA (1982) Polymer 23:869
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Guerra-Contreras, A., Villegas, A., RamÃrez-Oliva, E. et al. Characterization and Study of Properties in a Polar Solvent of a Functionalized and Quaternized Poly(dimethylsiloxane-co-methyl-hydridosiloxane). Silicon 9, 525–533 (2017). https://doi.org/10.1007/s12633-015-9286-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12633-015-9286-7