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Effect of Pb++/Sr++ Ratio on Physical, Structural, and Mechanical Properties of (Pb-Sr)TiO3 Borosilicate Glass Ceramics

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Abstract

Numerous attempts have been made for the fabrication of bulk glass and glass ceramics (x = 0.0, 0.1, 0.3, and 0.5) in the system 64[(Pb1-xSrx)TiO3]-25[(2SiO2.B2O3)]-7BaO.3K2O-1La2O3 via a conventional melt-quench and solid state reaction methods. In order to verify the amorphous and crystalline nature of the glass and glass ceramics, X-ray diffraction (XRD) analysis were carried out. Moreover, average crystallite size, and percentage of crystallinity were also determined using XRD data. Further, various physical parameters such as green density, sintered density, molar volume, and oxygen packing density were examined. To evaluate the structural and surface morphological properties of the sintered glass ceramics (SGCs), FTIR and SEM techniques were performed respectively. Further, to study various mechanical properties such as compressive strength, Young’s modulus, and break length of the SGC samples, UTM technique was utilized and found the maximum compressive strength, Young’s modulus, and break length, to be 250 MPa, 1.316 GPa, and 1.08 mm, for SGC sample (GC5), sintered at 850 0C for 4 h respectively.

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Acknowledgements

Authors express sincere gratitude to the Centre of Excellence Scheme of Uttar Pradesh State Government for providing the PXRD facility at Department of Physics, University of Lucknow, Lucknow.

Funding

This work was financially supported by the Council of Scientific and Industrial Research (CSIR), Human Resource Development Group, CSIR Complex, Pusa, New Delhi (India) vide File No. 09/0107(12949)/2021-EMR-I.

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Authors and Affiliations

  1. Advanced Glass and Glass Ceramics Research Laboratory, Department of Physics, University of Lucknow, Lucknow, 226007, Uttar Pradesh, India

    Rajat Kumar Mishra, Devashish Gupta, Sarvesh Kumar Avinashi, Savita Kumari, Ajaz Hussain & Chandkiram Gautam

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  1. Rajat Kumar Mishra
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  2. Devashish Gupta
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  3. Sarvesh Kumar Avinashi
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  4. Savita Kumari
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  5. Ajaz Hussain
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  6. Chandkiram Gautam
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Contributions

All authors contributed to the study, investigations, conception, and design. The experimental work and part of the editing were carried out by C. R. Gautam, R. K. Mishra and D. Gupta. The first draft of this manuscript was written by R. K. Mishra, D. Gupta and S. Kumari. The theoretical simulation was performed by A. Hussain and S. K. Avinashi, however, discussions of the results was performed by C. R. Gautam and A. Hussain. All authors read and approved the manuscript.

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Correspondence to Chandkiram Gautam.

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Mishra, R.K., Gupta, D., Avinashi, S.K. et al. Effect of Pb++/Sr++ Ratio on Physical, Structural, and Mechanical Properties of (Pb-Sr)TiO3 Borosilicate Glass Ceramics. Silicon 15, 2567–2580 (2023). https://doi.org/10.1007/s12633-022-02196-3

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