Abstract
Two novel steric polymeric phthalocyanines, with copper (CuPPc) and aluminum hybrid zinc (Al/ZnPPc) as the central atoms, were synthesized by the cyclic condensation of tetrahedral tetra-phthalonitriles. The IR and UV-VIS spectra of the synthesized polymers indicated a moderate degree of polymerization, somewhere between the monomeric phthalocyanine and planar covalent polymer. Good thermal stability and a high metallic content of CuPPc and Al/ZnPPc were verified by TGA and ICA-AAS methods. The metallic atoms were distributed uniformly and exhibited different binding features with -CN, -O, -N in the polymer, as indicated by EDS and XPS analysis. High electrical conductivity was observed before and after iodine doping compared to the normal polymeric phthalocyanine.
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Liang, Q., Zhao, P., Woo, JW. et al. Synthesis, characterization and electrical properties of novel steric phthalocyanine polymers. Macromol. Res. 18, 113–119 (2010). https://doi.org/10.1007/s13233-009-0059-2
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DOI: https://doi.org/10.1007/s13233-009-0059-2