Skip to main content
Log in

Effects of Nitrogen on the Glass Formation and Mechanical Properties of a Ti-Based Metallic Glass

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Effects of nitrogen addition on glass formation and mechanical properties of the Ti42.5Cu40Zr10Ni5Sn2.5 metallic glass were systematically investigated. It was found that a small amount of nitrogen addition facilitated the glass formation by suppressing formation of the competing eutectic structure. Unlike large atomic size elements such as Hf and Pd which usually deteriorate specific strength, nitrogen can also increase the specific strength of the current Ti-based BMGs. The results are not only helpful for understanding glass-forming ability in general, but also useful in developing cost-effective, high-performance Ti-based bulk metallic glasses with enhanced glass-forming ability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. G. Duan, A. Wiest, M.L. Lind, A. Kahl, W.L. Johnson, Scr. Mater. 58, 465 (2008)

    Article  Google Scholar 

  2. P. Gong, K.F. Yao, Y. Shao, J. Non Cryst. Solids 358, 2620 (2012)

    Article  Google Scholar 

  3. X.H. Lin, W.L. Johnson, J. Appl. Phys. 78, 6514 (1995)

    Article  Google Scholar 

  4. Z.Y. Zhang, Y. Wu, J. Zhou, W.L. Song, D. Cao, H. Wang, X.J. Liu, Z.P. Lu, Intermetallics 42, 68 (2013)

    Article  Google Scholar 

  5. Z.Y. Zhang, Y. Wu, J. Zhou, H. Wang, X.J. Liu, Z.P. Lu, Scr. Mater. 69, 73 (2013)

    Article  Google Scholar 

  6. H. Ma, L.L. Shi, J. Xu, Y. Li, E. Ma, J. Mater. Res. 21, 2204 (2006)

    Article  Google Scholar 

  7. H. Ma, Q. Zheng, J. Xu, Y. Li, E. Ma, J. Mater. Res. 20, 2252 (2005)

    Article  Google Scholar 

  8. C.L. Dai, H. Guo, Y. Shen, Y. Li, E. Ma, J. Xu, Scr. Mater. 54, 1403 (2006)

    Article  Google Scholar 

  9. P. Jia, H. Guo, Y. Li, J. Xu, E. Ma, Scr. Mater. 54, 2165 (2006)

    Article  Google Scholar 

  10. Z.P. Lu, C.T. Liu, J.R. Thompson, W.D. Porter, Phys. Rev. Lett. 92, 245503 (2004)

    Article  Google Scholar 

  11. E.S. Park, H.K. Lim, W.T. Kim, D.H. Kim, J. Non Cryst. Solids 298, 15 (2002)

    Article  Google Scholar 

  12. Y.L. Wang, E. Ma, J. Xu, Philos. Mag. Lett. 88, 319 (2008)

    Article  Google Scholar 

  13. Y.L. Wang, J. Xu, Metall. Mater. Trans. A 39, 2990 (2008)

    Article  Google Scholar 

  14. M.Q. Tang, H.F. Zhang, Z.W. Zhu, H.M. Fu, A.M. Wang, H. Li, Z.Q. Hu, J. Mater. Sci. Technol. 26, 481 (2010)

    Article  Google Scholar 

  15. C.L. Ma, H. Soejima, S. Ishihara, K. Amiya, N. Nishiyama, A. Inoue, Mater. Trans. 45, 3223 (2004)

    Article  Google Scholar 

  16. J. Shen, Y.J. Huang, J.F. Sun, J. Mater. Res. 22, 3067 (2007)

    Article  Google Scholar 

  17. S.L. Zhu, X.M. Wang, A. Inoue, Intermetallics 16, 1031 (2008)

    Article  Google Scholar 

  18. Z.Q. Liu, R. Li, H. Wang, T. Zhang, J. Alloys Compd. 509, 5033 (2011)

    Article  Google Scholar 

  19. D.J. Wang, Y.J. Huang, J. Shen, J. Non Cryst. Solids 355, 986 (2009)

    Article  Google Scholar 

  20. B. Murty, D. Ping, K. Hono, A. Inoue, Appl. Phys. Lett. 76, 55 (2000)

    Article  Google Scholar 

  21. D. Turnbull, Contemp. Phys. 10, 473 (1969)

    Article  Google Scholar 

  22. Z.P. Lu, C.T. Liu, Acta Mater. 50, 3501 (2002)

    Article  Google Scholar 

  23. Z.P. Lu, C.T. Liu, Phys. Rev. Lett. 91, 115505 (2003)

    Article  Google Scholar 

  24. A. Inoue, T. Zhang, T. Masumoto, Mater. Trans., JIM 31, 177 (1990)

    Article  Google Scholar 

  25. Z.P. Lu, D. Ma, C.T. Liu, Y.A. Chang, Intermetallics 15, 253 (2007)

    Article  Google Scholar 

  26. Z.P. Lu, C.T. Liu, J. Mater. Sci. 39, 3965 (2004)

    Article  Google Scholar 

  27. Z.P. Lu, C.T. Liu, W.D. Porter, Appl. Phys. Lett. 83, 2581 (2003)

    Article  Google Scholar 

  28. H.A. Wriedt, J.L. Murray, Bull. Alloy Phase Diagrams 8, 378 (1987)

    Article  Google Scholar 

  29. Z. Bian, H. Kato, C.L. Qin, W. Zhang, A. Inoue, Acta Mater. 53, 2037 (2005)

    Article  Google Scholar 

  30. A. Inoue, H. Kimura, K. Sasamori, T. Masumoto, Mater. Trans., JIM 36, 1219 (1995)

    Article  Google Scholar 

  31. M.W. Chen, T. Zhang, A. Inoue, A. Sakai, T. Sakurai, Appl. Phys. Lett. 75, 1697 (1999)

    Article  Google Scholar 

  32. U. Köster, J. Meinhardt, S. Roos, H. Liebertz, Appl. Phys. Lett. 69, 179 (1996)

    Article  Google Scholar 

  33. Y.C. Kim, J.H. Na, J.M. Park, D.H. Kim, J.K. Lee, W.T. Kim, Appl. Phys. Lett. 83, 3093 (2003)

    Article  Google Scholar 

  34. J. Saida, M. Matsushita, A. Inoue, Mater. Trans., JIM 41, 543 (2000)

    Article  Google Scholar 

  35. J.L. Libbert, K.F. Kelton, Philos. Mag. Lett. 71, 153 (1995)

    Article  Google Scholar 

  36. D. Zander, R. Janlewing, A. Rüdiger, U. Köster, Mater. Sci. Forum 307, 25 (1999)

    Article  Google Scholar 

  37. B. Murty, D. Ping, K. Hono, A. Inoue, Acta Mater. 48, 3985 (2000)

    Article  Google Scholar 

  38. Y.H. Liu, C.T. Liu, W.H. Wang, A. Inoue, T. Sakurai, M.W. Chen, Phys. Rev. Lett. 103, 065504 (2009)

    Article  Google Scholar 

  39. B. Yang, C.T. Liu, T. Nieh, Appl. Phys. Lett. 88, 221911 (2006)

    Article  Google Scholar 

  40. P.F. Guan, M.W. Chen, T. Egami, Phys. Rev. Lett. 104, 205701 (2010)

    Article  Google Scholar 

  41. O.N. Senkov, D.B. Miracle, Mater. Res. Bull. 36, 2183 (2001)

    Article  Google Scholar 

  42. M. Telford, Mater. Today 7, 36 (2004)

    Article  Google Scholar 

  43. Z.B. Jiao, H.X. Li, J.E. Gao, Y. Wu, Z.P. Lu, Intermetallics 19, 1502 (2011)

    Article  Google Scholar 

  44. Y. Wu, H. Wang, Y.Q. Cheng, X.J. Liu, X.D. Hui, T.G. Nieh, Y.D. Wang, Z.P. Lu, Sci. Rep. 5, 12137 (2015)

    Article  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 51451001, 51531001, 51422101, 51271212 and 51371003), 111 Project (No. B07003) and Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_14R05). The authors would like to thank Dr. L. You for the help on TEM experiment.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yuan Wu or Z. P. Lu.

Additional information

Available online at http://link.springer.com/journal/40195

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cao, D., Wu, Y., Wang, H. et al. Effects of Nitrogen on the Glass Formation and Mechanical Properties of a Ti-Based Metallic Glass. Acta Metall. Sin. (Engl. Lett.) 29, 173–180 (2016). https://doi.org/10.1007/s40195-016-0374-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-016-0374-5

Keywords

Navigation