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Synthesis, Properties and Applications of Ultrananocrystalline Diamond pp 241–252Cite as

Purification and Functionalization of Nanodiamond

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Part of the book series: NATO Science Series ((NAII,volume 192))

Abstract

This paper briefly discusses the advantages of commercial nanodiamond and analyses its structural and chemical impurities, polyfunctional surface termination, agglomeration, and other features that may restrict the ND application in academic research and industrial practice. We have designed and tested a novel approach to detonation nanodiamond purification and surface functionalization, using a high temperature treatment in gaseous media containing hydrogen and chlorine. A drastic change in the hydrophily (by a factor of 20) due to thermal treatment at 450’C in a CC14/Ar mixture is demonstrated. The characterization techniques employed (chemical analyses; Raman, FTIR, and ESR spectroscopy; chromatomass spectrometry) can provide a profound nanodiamond modification and its prescribed functionalization.

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References

  1. B.V. Spitsyn, L.L. Bouilov, and B.V. Deriaguin. Vapor growth of diamond on diamond and other surfaces. J. Cryst. Growth 52(1), 219–26 (1981).

    Article  Google Scholar 

  2. B.V. Spitsyn, L.L. Bouilov, and A.E. Alexenko. Origin, state of the art and some prospects of diamond CVD. Braz. J. Phys. 30, 471–81 (2000).

    Article  Google Scholar 

  3. V.Y. Dolmatov. Detonation synthesis ultradispersed diamond: properties and applications. Russian Chem. Reviews 70, 607–26 (2001).

    Article  Google Scholar 

  4. O.A. Shenderova, V.V. Zhimov, and D.W. Brenner. Carbon Nanostructures. Critical Reviews in Solid State and Materials Sciences, 27, 227–356 (2002)

    Google Scholar 

  5. V.V. Danilenko. Synthesis and sintering of diamond by detonation. Energoatomizdat, 2003.

    Google Scholar 

  6. T.L. Daulton. Nanodiamonds in the Cosmos. this Proceedings, p. 49.

    Google Scholar 

  7. Yu.G. Gogotsi et al. Conversion of silicon carbide to crystalline diamond-structured carbonate ambient pressure. Nature 411(6835), 283–87 (2001).

    PubMed  Google Scholar 

  8. S. Mitura. Nucleation of diamond powder particles in an RF methane plasma. J. Cryst. Growth 80, 417–24 (1987).

    Article  Google Scholar 

  9. M. Frenklach, R. Kematick, D. Huang, W. Howard, K.E. Spear, R. Koba, and A.W. Phelps. J. Appl. Phys. 66, 1247 (1989).

    Article  Google Scholar 

  10. B.V. Spitsyn. Nanodiamond for science and practice. Repts. Russian Acad. Sci. 73(5), 433–35 (2003).

    Google Scholar 

  11. O.A. Shenderova, Z. Hu, and D. Brenner. Carbon Family at the Nanoscale. This Proceedings, p. 1.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, RAS, Moscow, 119991, Russia

    B.V. Spitsyn, T.B. Galushko, T.A. Karpukhina & N.V. Serebryakova

  2. M. V. Lomonosov State University, Moscow, 119992, Russia

    M.N. Gradoboev & I.I. Kulakova

  3. P.N. Lebedev Physical Institute, RAS, Moscow, 117924, Russia

    N.N. Melnik

Authors
  1. B.V. Spitsyn
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  2. M.N. Gradoboev
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  3. T.B. Galushko
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  4. T.A. Karpukhina
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  5. N.V. Serebryakova
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  6. I.I. Kulakova
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  7. N.N. Melnik
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Editor information

Editors and Affiliations

  1. Argonne National Laboratory, Argonne, IL, USA

    Dieter M. Gruen

  2. International Technology Center, North Carolina, USA

    Olga A. Shenderova

  3. Ioffe Physico-Technical Institute, St. Petersburg, Russia

    Alexander Ya. Vul’

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© 2005 Springer

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Spitsyn, B. et al. (2005). Purification and Functionalization of Nanodiamond. In: Gruen, D.M., Shenderova, O.A., Vul’, A.Y. (eds) Synthesis, Properties and Applications of Ultrananocrystalline Diamond. NATO Science Series, vol 192. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3322-2_18

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