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Electrokinetic Study of Layer-by-Layer Polyelectrolyte and Surfactant Adsorbed Layers

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Book cover Characterization of Polymer Surfaces and Thin Films

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 132))

Abstract

Investigations of alternate adsorption regularities of cationic polyelectrolytes a) copolymer of styrene and dimethylaminopropylmaleimide (CSDAPM) and b) poly(diallyldimethylammonium chloride) (PDADMAC) and anionic surfactant – sodium dodecyl sulfate (SDS) on fused quartz surface were carried out by capillary electrokinetic method. The adsorption/desorption kinetics, structure and properties of adsorbed layers for both polyelectrolytes and also for the second adsorbed layer were studied in dependence on different conditions: molecular weight of polyelectrolyte, surfactant and polyelectrolyte concentration, the solution flow rate through the capillary during the adsorption, adsorbed layer formation time. For PDADMAC adsorbed layers evolution of the structure and rheological properties was observed. Adsorption of anionic surfactant leads to the overcharge of preliminarily modified quartz surface by cationic polyelectrolyte and depends on the SDS concentration and prehistory of the first adsorbed layer. The desorption study showed that in all cases the partial desorption of SDS took place, the value of this desorption depended on the structure of the first adsorbed layer and SDS concentration.

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Acknowledgments

We thank Dr. S. Zschoche (IPF, Dresden, Germany) for providing us with polyelectrolyte (CSDAPM). This work was supported by the Russian Foundation for Basic Research, project no. 04-03-32455.

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Authors and Affiliations

  1. Laboratory of Thin Liquid Films, Institute of Physical Chemistry and Electrochemistry by A.N. Frumkin of Russian Academy of Science, Leninsky prospect, 31, 119991, Moscow, Russia

    Tatiana B. Ermakova, Inessa P. Sergeeva, Anna D. Anuchkina, Vladimir D. Sobolev & Nikolay V. Churaev

Authors
  1. Tatiana B. Ermakova
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  2. Inessa P. Sergeeva
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  3. Anna D. Anuchkina
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  4. Vladimir D. Sobolev
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  5. Nikolay V. Churaev
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Corresponding author

Correspondence to Tatiana B. Ermakova .

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Karina Grundke Manfred Stamm Hans-Jürgen Adler

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Ermakova, T.B., Sergeeva, I.P., Anuchkina, A.D., Sobolev, V.D., Churaev, N.V. Electrokinetic Study of Layer-by-Layer Polyelectrolyte and Surfactant Adsorbed Layers. In: Grundke, K., Stamm, M., Adler, HJ. (eds) Characterization of Polymer Surfaces and Thin Films. Progress in Colloid and Polymer Science, vol 132. Springer, Berlin, Heidelberg. https://doi.org/10.1007/2882_043

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