Abstract
Recent results on the crystallization of block copolymers with more than one crystallizable block are reviewed. The effect that each block has on the nucleation, crystallization kinetics and location of thermal transitions of the other blocks has been considered in detail. Depending on the thermodynamic repulsion between the blocks, the initial melt morphology in weakly segregated double crystalline diblock copolymers can be sequentially transformed by the crystallization of the different blocks. The crystallization kinetics of each block can be dramatically affected by the presence of the other, and by the crystallization temperature; the magnitude of the effect is a function of thermodynamic repulsion. Also the morphology has been investigated and peculiar double crystalline spherulites with intercalated semi-crystalline lamellae of each component have been observed in weakly segregated diblock copolymers. In the case of ABC triblock copolymers with more than one crystallizable block, many interesting effects have been found; among them, self-nucleation, sequential or coincident crystallization, and fractionated crystallization can be mentioned. Additionally, the effect of the topological constrains due to the number of free ends has been studied. Factors like chemical structure, molecular weight, molecular architecture and number of crystallizable blocks provide a very large number of possibilities to tailor the morphology and properties of these interesting novel materials.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
I.W. Hamley: Adv. Polym. Sci. 148, 113 (1999).
Y.L. Loo, R.A. Register: Crystallization within block copolymer mesophases. In: Developments in block copolymer science and technology, ed by I.W. Hamley (Wiley, New York 2004).
A.J. Müller, V. Balsamo, M.L. Arnal: Adv. Polym. Sci., 190, 1 (2005).
I.W. Hamley: The Physics of Block Copolymers (Oxford University Press, Oxford 1998).
N. Hadjichristidis, S. Pispas, G. Floudas: Block Copolymers: Synthetic Strategies, Physical Properties, and Applications (Wiley, New Jersey 2003).
R. Perret, A. Skoulios: Die Makromol. Chem., 156, 143 (1972).
R. Perret, A. Skoulios: Die Makromol. Chem., 156, 291 (1972).
P. Cerrai, M. Tricoli, F. Andruzzi, M. Paci, M. Paci: Polymer 30, 338 (1989).
S. Nojima, M. Ono, T. Ashida: Polym. J., 24, 1271 (1992).
Z. Gan, B. Jiang, J. Zhang: J. Appl. Polym. Sci. 59, 961 (1996).
Z. Gan, J. Zhang. B. Jiang: J. Appl Polym Sci. 63, 1793 (1997).
Z. Zhu, C. Xiong, L. Zhang, X. Deng: J. Polym. Sci., A:Polym. Chem. 35, 709 (1997).
T. Petrova, N. Manolova, I. Rashkov, S. Li, M. Vert: Polym. Intern. 45, 419 (1998).
B. Bogdanov, A. Vidts, A. Van Den Bulcke, R. Verbeeck, E. Schacht: Polymer 39, 1631 (1998).
B. Bogdanov, A. Vidts, E. Schacht, H. Berghmans: Macromolecules 32, 726 (1999).
T. Shiomi, K. Imai, K. Takenaka, H. Takeshita, H. Hayashi, Y. Tezuka: Polymer 42, 3233 (2001).
L. Piao, Z. Dai, M. Deng, X. Chen, X. Jing: Polymer 44, 2025 (2003).
C. He, J. Sun, C. Deng, T. Zhao, M. Deng, X. Chen, X. Jing: Biomacromol. 5, 2042 (2004).
C. He, J. Sun, T. Zhao, Z. Hong, X. Zhuang, X. Chen, X. Jing: Biomacromol. 7, 252 (2006).
O. Lambert, P. Dumas, G. Hurtrez, G. Riess: Macromol. Rapid Commun. 18, 343 (1997).
O. Lambert, S. Reutenauer, G. Hurtrez, G. Riess, P. Dumas: Polym. Bull. 40, 143 (1998).
G. Floudas, G. Reiter, O. Lambert, P. Dumas: Macromolecules 31, 7279 (1998).
G. Floudas, G. Reiter, O. Lambert, P. Dumas, F.J. Yeh, B. Chu, ACS Symposium, Series 739, Chapter 28, 448 (2000).
A.J. Müller, M.L. Arnal, F. López-Carrasquero: Macromol. Symp. 183, 199 (2002).
M.L. Arnal, V. Balsamo, F. López-Carrasquero, J. Contreras, M. Carrillo, H. Schmalz, V. Abetz, E. Laredo, A.J. Müller: Macromolecules 34, 7973 (2001).
M.L. Arnal, F. López-Carrasquero, E. Laredo, A.J. Müller: Europ. Polym. J. 40, 1461 (2004).
M. Vivas, J. Contreras, F. López-Carrasquero, A.T. Lorenzo, M.L. Arnal, V. Balsamo, A.J. Müller, E. Laredo, H. Schmalz, V. Abetz, Macromol. Symp., 239, 58 (2006).
S. Vainionpaa, P. Pentti Rokkamen, P. Tormala: Prog. Polym. Sci. 14, 679 (1989).
J.K. Kim, D.J. Park, M.S. Lee, K.J. Ihn: Polymer 42, 7429 (2001).
R.-M. Ho, P.-Y. Hsieh, W.-H. Tseng, C.-C. Lin, B.-H. Huang, B. Lotz: Macromolecules 36, 9085 (2003).
G. Maglio, A. Migliozzi, R. Palumbo: Polymer 44, 369 (2003).
O. Jeon, S.-H. Lee, S.H. Kim, Y.M. Lee, Y.H. Kim: Macromolecules 36, 5585 (2003).
I.W. Hamley, V. Castelleto, R.V. Castillo, A.J. Müller, C.M. Martin, E. Pollet, Ph. Dubois: Macromolecules 38, 463 (2005).
I.W. Hamley, P. Parras, V. Castelleto, R.V. Castillo, A.J. Müller, E. Pollet, Ph. Dubois, C.M. Martin: Macromol. Chem. Phys., 207, 941 (2006).
C. Jacobs, Ph. Dubois, R. Jerome, Ph. Teyssie: Macromolecules 24, 3027 (1991).
D. Shin, K. Shin, K. Aamer, G.N. Tew, T.P. Russell, J.H. Lee, J.Y. Jho: Macromolecules 38, 104 (2005).
M.A. Sabino, G. Ronca, A.J. Müller: J. Mater. Sci. 35, 5071 (2000).
M.A. Sabino, J.L. Feijoo, A.J. Müller: Macromol. Chem. Phys. 201, 2687 (2000).
M.A. Sabino, J.L. Feijoo, A.J. Müller: Polym. Degrad. Stab. 73, 541 (2001).
M.A. Sabino, L. Sabater, G. Ronca, A.J. Müller: Polym. Bull. 48, 291 (2002).
M.A. Sabino, J. Albuerne, A.J. Müller, J. Brisson, R.E. Prud’homme: Biomacromolecules: 5, 358 (2004).
J. Albuerne, L. Marquez, A.J. Müller, J.M. Raquez, Ph. Degee, Ph. Dubois, V. Castelletto, I.W. Hamley: Macromolecules, 36, 1633 (2003).
A.J. Müller, J. Albuerne, L.M. Esteves, L. Márquez, J.M. Raquez, Ph. Degée, Ph. Dubois, S. Collins, I.W. Hamley: Macromol. Symp. 215, 369 (2004).
A.J. Müller, J. Albuerne, L. Márquez, J.M. Raquez, Ph. Degée, Ph. Dubois, J. Hobbs, I.W. Hamley: Faraday Discuss. 128, 231 (2005).
J. Albuerne, L. Marquez, A.J. Müller, J.M. Raquez, P. Degée, P. Dubois: Macromol. Chem. Phys. 206, 903 (2005).
M. Ueda, K. Sakurai, S. Okamoto, D. Lohse, W.J. MacKnight, S. Shinkai, S. Sakurai, S. Nomura: Polymer 44, 6995 (2003).
K.-S. Kim, S. Chung, I.-J. Chin, M.-N. Kim, J.-S. Yoon: J. Appl. Polym. Sci. 72, 341 (1999).
L. Zhu, B.H. Calhoun, Q. Ge, R.P. Quirk, S.Z.D. Cheng, E.L. Thomas, B.S. Hsiao, F. Yeh, L. Liu, B. Lotz: Macromolecules 34, 1244 (2001).
C. De Rosa, C. Park, B. Lotz, J.C. Wittmann, L. Fetters, E.L. Thomas: Macromolecules 33, 4871 (2000).
C. Park, C. De Rosa, E.L. Thomas: Macromolecules 34, 2602 (2001).
V. Balsamo, A.J. Müller, F. von Gyldenfeldt, R. Stadler: Macrom. Chem. Phys. 199, 1063 (1998).
V. Balsamo, A.J. Müller, R. Stadler: Macromolecules 31, 7756 (1998).
V. Balsamo, Y. Paolini, G. Ronca, A.J. Müller: Macromol. Chem. Phys. 201, 2711 (2000).
V. Balsamo, N. Urdaneta, L. Pérez, P. Carrizales, V. Abetz, A.J. Müller: Europ. Polym. J. 40, 1033 (2004).
S. Nojima, Y. Akutsu, A. Washino, S. Tanimoto: Polymer 45, 7317 (2004).
S. Nojima, Y. Akutsu, M. Akaba, S. Tanimoto: Polymer 46, 4060 (2005).
V. Balsamo, G. Gil, C. Urbina de Navarro, I.W. Hamley, F. von Gyldenfeldt, V. Abetz, E. Cañizales: Macromolecules 36, 4515 (2003).
V. Balsamo, R. Stadler: Macromolecules 32, 3994 (1999).
S.M. Li, I. Rashkov, J.L. Espartero, N. Manolova, M. Vert: Macromolecules 29, 57 (1996).
A.J. Müller, V. Balsamo, M.L. Arnal, T. Jakob, H. Schmalz, V. Abetz: Macromolecules 35, 3048 (2002).
M.L. Arnal, M.E. Matos, R.A. Morales, O.O. Santana, A.J. Müller: Macromol. Chem. Phys. 199, 2275 (1998).
C.P. Radano, O.A. Scherman, N. Stingelin-Stutzmann, C. Müller, D.W. Breiby, P. Smith, R.A.J. Janssen, E.W. Meijer: J. Am. Chem. Soc. 127, 12502 (2005).
V. Balsamo, A.J. Müller, R. Stadler: Macromolecules 31, 7756 (1998).
X. Shuai, F.E. Porbeni, M. Wei, I.D. Shin, A.E. Tonelli, Macromolecules 34, 7355 (2001)
X. Shuai, M. Wei, F.E. Porbeni, T.A. Bullions, A.E. Tonelli, Biomacromol. 3, 201 (2002)
M. Wei, X. Shuai, A.E. Tonelli, Biomacromol. 4, 783 (2003)
F.E. Porbeni, I.D. Shin, X. Shuai, X. Wang, J.L. White, X. Jia, A.E. Tonelli, Polymer 43, 2086 (2005)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2007 Springer
About this chapter
Cite this chapter
Müller, A.J., Arnal, M.L., Balsamo, V. (2007). Crystallization in Block Copolymers with More than One Crystallizable Block. In: Reiter, G., Strobl, G.R. (eds) Progress in Understanding of Polymer Crystallization. Lecture Notes in Physics, vol 714. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-47307-6_13
Download citation
DOI: https://doi.org/10.1007/3-540-47307-6_13
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-47305-3
Online ISBN: 978-3-540-47307-7
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)