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Erschienen in:
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2012 | OriginalPaper | Buchkapitel

1. General Theory of Disperse Metal Electrodeposits Formation

verfasst von : Konstantin I. Popov, Nebojša D. Nikolić

Erschienen in: Electrochemical Production of Metal Powders

Verlag: Springer US

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Abstract

The most frequently used form of the cathodic polarization curve equation for flat or large spherical electrode of massive metal is given by
$$ j = \frac{{{j_0}({f_{\rm{c}}} - {f_{\rm{a}}})}}{{{1} + \frac{{{j_{{0}}}{f_{\rm{c}}}}}{{{j_{\rm{L}}}}}}}, $$

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Nächstes Kapitel Morphology of Different Electrodeposited Pure Metal Powders
Fußnoten
1
The reversible potential of a surface with radius of curvature r cur would depart from that of a planar surface by the quantity \( \Delta {E_{\rm{r}}} = 2\sigma V{/}(nF{r_{\rm{cur}}}) \), where σ is the interfacial energy between metal and solution, and V is the molar volume of metal [5]. It is valid at extremely low r cur, being of the order of few millivolts, and it can be neglected except in some special cases, like the stability of the shape of the tips of dendrites [5].
 
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Metadaten
Titel
General Theory of Disperse Metal Electrodeposits Formation
verfasst von
Konstantin I. Popov
Nebojša D. Nikolić
Copyright-Jahr
2012
Verlag
Springer US
Buch
Electrochemical Production of Metal Powders

Print ISBN: 978-1-4614-2379-9

Electronic ISBN: 978-1-4614-2380-5

Copyright-Jahr: 2012

DOI
https://doi.org/10.1007/978-1-4614-2380-5_1