Abstract
In general, the local current density j x varies along an electrode. Similarly, the potential difference at the electrode-solution interface can depend on location. For example, the current density tends to be larger on the crests of an electrode with a serrated profile (Figure 8), or near the edges of an electrode that does not entirely fill the cross section of the electrolysis cell (Figures 3 and 10). This is due to the fact that, at these privileged spots, the cross section of the solution available for the passage of charges through the electrolyte increases with increasing distance from the electrode, so that the resistance for the current flow from the anode to the cathode is smaller at these spots than in other parts of the electrode.
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Ibl, N. (1983). Current Distribution. In: Yeager, E., Bockris, J.O., Conway, B.E., Sarangapani, S. (eds) Comprehensive Treatise of Electrochemistry. Comprehensive Treatise of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-6690-8_4
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