Abstract
It is well known that multicomponent bismuth molybdates are most active and selective catalysts for the allylic oxidation and ammoxidation of lower olefins.(1) They are widely used in industrial processes, but, owing to their complicated compositions and structures, little has been reported for the working mechanism and role of each element in the multicomponent catalyst system. In contrast, catalytic oxidations of lower olefins over simple bismuth molybdates have been extensively investigated. The reaction mechanism via allylic intermediates and participation of the lattice oxide ion intQ the surface reaction according to the Mars and van Klevelen mechanism(2) have been well established. Extension of the 18O2 tracer technique developed by Keulks(3) and Wragg et al.(4) made it possible to measure the diffusion rate of oxide ions in the typical phases of bismuth molyb-date and to determine the depth of the oxide ion layers which can be involved in the oxidation reaction.(5)
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For example: (a) Grasselli, R. K., and Callahan, J. L. (Standard Oil Ohio), U.S. Patent 3, 414, 631 (1968); (b) Grasselli, R. K., and Hardman, H. F. (Standard Oil Ohio), U. S. Patent 3, 642, 930 (1972); (c) Takenaka, S., and Yamaguchi, G. (Non Kayaku), Japan Patent 69-6, 245 and 69-6, 246 (1969).
Mars, P., and van Krevelen, D. W., Chem. Eng. Sci., Suppl. 3, 41 (1954).
Keulks, G. W., J. Catalysis 19, 232 (1970).
Wragg, R. D. Ashmore, P. G., and Hockey, J. A., J. Catalysis 22, 49 (1971); 28, 337 (1973).
Keulks, G. W., and Krenzke, L. D., in Proceedings of 6th International Congress on Catalysis, London, 1976, G. C. Bond, P. B. Wells, and F. C. Tompkins, eds., Vol.2, p. 806, The Chemical Society, London, 1977
Keulks, G. W., and Krenzke, L. D. J. Catalysis 61, 316 (1980).
Ueda, W., Moro-oka, Y., and Ikawa, T., J. Catalysis 70, 409, (1981).
Ueda, W., Moro-oka, Y., Ikawa, T., and Matsuura, I., Chem. Lett. 1365 (1982).
Ueda, W., Moro-oka, Y., and Ikawa, T., J. Catalysis 88, 214 (1984).
Moro-oka, Y., Ueda, W., Tanaka, S., and Ikawa, T., in Proceedings of 7th International Congress on Catalysis, Tokyo, 1980, T. Seiyama and K. Tanabe, eds., Part B, p. 1086 Kodansha-Elsevier/Tokyo (1981).
Ueda, W., Asakawa, K., Chen, C. L., Moro-oka, Y., and Ikawa, T., J. Catalysis 101, 360 (1986).
Ueda, W., Chen, C. L., Asakawa, K., Moro-oka, Y., and Ikawa, T., J. Catalysis 101, 369 (1986).
Aykan, K., Sleight, A. W., and Rogers, D. B., J. Catalysis 29, 185 (1973)
Aykan, K., Halvorson, D., and Sleight, A. W., J. Catalysis 35, 401 (1974).
Wolfs, M. W. J., and Batist, Ph. A., J. Catalysis 32, 25 (1974).
Matsura, I., and Wolfs, M. W. J., J. Catalysis 37, 174 (1975).
LoJacono, M., Notermann, T., and Keulks, G. W., J. Catalysis 40, 19 (1975).
Linn, W. J., and Sleight, A. W., J. Catalysis 41, 134 (1976).
Matsura, I., in Proceedings of 7th Intern. Congr. on Catalysis, Tokyo, 1980, T. Seiyama and K. Tanabe, eds., Part B, p. 1099, Kodansha-Elsevier (1981).
Ooij, W. J. V., and Muizebelt, W. J., in Proceedings of Intern. Vacuum Congr. and 3rd Intern. Conf. of Solid Surface, Vienna, p. 839 (1977).
Rao, T. S. R. P., and Menon, P. G., J. Catalysis 51, 64 (1978).
Umemura, S., Ohdan, K., and Asada, H., in 5th Japan-Soviet Catalysis Seminar, p. 60 (1979).
Moro-oka, Y., Ueda, W., and He, De-Hua, in Structure-Activty and Selectivity Relationships in Heterogeneous Catalysis, R. K. Grasselli and A. W. Sleight, eds., Elsevier Science Publishers, Amsterdam, p. 57.
Sleight, A. W., Aykan, K., and Rojers, D. B., J. Solid State Chem. 13, 231 (1975)
Sleight, A. W., Advanced Materials in Catalysis, p. 181, Academic Press, New York (1977).
Hashiba, H., Kanesaka, M., and Matsuura, I., Shokubai 27, 434 (1985).
Hoefs, E. V., Monnier, J. R., and Keulks, G. W. J. Catalysis 57, 331 (1979).
Ueda, W., Moro-oka, Y., and Ikawa, T., J. Chem. Soc. Faraday Trans. I 78, 495 (1982).
Glaeser, L. C, Brazdil, J. F., Hazle, M. A., Mehicic, M., Grasselli, R. K., J. Chem. Soc. Faraday Trans. I 81, 2903 (1985).
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Moro-oka, Y., Ueda, W., He, DH. (1993). Surface Reactions Controlled by the Bulk Migration of Oxide Ions. In: Tamaru, K. (eds) Dynamic Processes on Solid Surfaces. Fundamental and Applied Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1636-5_11
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DOI: https://doi.org/10.1007/978-1-4899-1636-5_11
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