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Sol-Gel Nanocomposites

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Book cover Handbook of Sol-Gel Science and Technology

Abstract

This chapter describes nanocomposites where at least one of the phases has been obtained by the sol-gel method. In the first part, the synthesis of the nanocomposites is considered, and an attempt is made to resume the general principles and methods related to different classes of materials, with oxide, hybrid organic–inorganic, and polymeric matrices and oxide, metal, and non-oxide nanoparticles. The second part is devoted to the applications of sol-gel nanocomposites. Representative examples of nanocomposites that potentially can have commercial application are described, based on the literature of the last 10 years.

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References

  • Achilleos DS, Vamvakaki M. End-grafted polymer chains onto inorganic nano-objects. Materials. 2010;3:1981–2026.

    CAS  Google Scholar 

  • Akhavan O. Lasting antibacterial activities of Ag-TiO2/Ag/a-TiO2 nanocomposite thin film photocatalysts under solar light irradiation. J Coll Inter Sci. 2009;336:117–24.

    CAS  Google Scholar 

  • Antonello A, Brusatin G, Guglielmi M, Bello V, Perotto G, Mattei G, Maiwald M, Zöllmer V, Chiasera A, Ferrari M, Martucci A. Novel multifunctional nanocomposites from titanate nanosheets and semiconductor quantum dots. Optical Materials. 2011;33:1839–46.

    CAS  Google Scholar 

  • Arkles B. Commercial applications of sol–gel-derived hybrid materials. Mater Res Bull. 2001;26:402–8.

    CAS  Google Scholar 

  • Becker-Willinger C. Film Nanocomposites. In: Guglielmi M, Kickelbick G, Martucci A, editors. Sol-Gel Nanocomposites. New York: Springer; 2014, p. 109–130

    Google Scholar 

  • Boccaccini AR, Blaker JJ, Maquet V, Day RM, Jerome R. Preparation and characterisation of poly(lactide-co-glycolide) (PLGA) and PLGA/Bioglass® composite tubular foam scaffolds for tissue engineering applications. Mater Sci Eng C. 2005;25:23–31.

    Google Scholar 

  • Boccaccini AR, Erol M, Stark WJ, Mohn D, Hong Z, Mano JF. Polymer/bioactive glass nanocomposites for biomedical applications: a review. Comp Sci Tech. 2010;70:1764–76.

    CAS  Google Scholar 

  • Boev VI, Silva CJR, Hungerford G, Gomes M. Synthesis and characterization of a sol–gel derived ureasilicate hybrid organic-inorganic matrix containing CdS colloidal particles. J Sol-Gel Sci Technol. 2004;31:131–5.

    CAS  Google Scholar 

  • Breitscheidel B, Zieder J, Schubert U. Metal complexes in inorganic matrices. 7. nanometer-sized, uniform metal particles in a SiO2 matrix by sol-gel processing of metal complexes. Chem Mater. 1991;3:559–66.

    CAS  Google Scholar 

  • Buso D, Busato G, Guglielmi M, Martucci A, Bello V, Mattei G, Mazzoldi P, Post ML. Selective optical detection of H2 and CO with SiO2 sol–gel films containing NiO and Au nanoparticles. Nanotechnology. 2007a;18:475505.

    Google Scholar 

  • Buso D, Pacifico J, Martucci A, Mulvaney P. Gold-nanoparticle-doped TiO2 semiconductor thin films: optical characterization. Adv Func Mater. 2007b;17:347–54.

    CAS  Google Scholar 

  • Cantalini C, Post M, Buso D, Guglielmi M, Martucci A. Gas sensing properties of nanocrystalline NiO and Co3O4 in porous silica sol–gel films. Sens Actuators B. 2005;108:184–92.

    CAS  Google Scholar 

  • Cao G. Nanostructures & nanomaterials synthesis, properties & applications. London: Imperial College Press; 2004.

    Google Scholar 

  • Caragheorgheopol A, Chechik V. Mechanistic aspects of ligand exchange in Au nanoparticles. Phys Chem Chem Phys. 2008;10:5029–41.

    CAS  Google Scholar 

  • Chen B, Chiu T, Tsay S. Synthesis and characterization of polyimide/silica hybrid nanocomposites. J Appl Polym Sci. 2004;94:382–93.

    CAS  Google Scholar 

  • Datta S, Das GC. Preparation of glass-silver microcomposites by sol-gel route. Bull Mater Sci. 1992;15:363–6.

    CAS  Google Scholar 

  • Della Gaspera E, Guglielmi M, Agnoli S, Granozzi G, Post ML, Bello V, Mattei G, Martucci A. Au nanoparticles in nanocrystalline TiO2-NiO films for SPR-based, selective H2S gas sensing. Chem Mater. 2010a;22:3407–17.

    CAS  Google Scholar 

  • Della Gaspera E, Buso D, Guglielmi M, Martucci A, Bello V, Mattei G, Post ML, Cantalini C, Agnoli S, Granozzi G, Sadek AZ, Kalantar-Zadeh K, Wlodarski W. Comparison study of conductometric optical and SAW gas sensors based on porous sol-gel silica films doped with NiO and Au nanocrystals. Sens Actuators B. 2010b;143:567–73.

    CAS  Google Scholar 

  • Della Gaspera E, Antonello A, Guglielmi M, Post ML, Bello V, Mattei G, Romanato F, Martucci A. Colloidal approach to Au-loaded TiO2 thin films with optimized optical sensing properties. J Mater Chem. 2012;21:4293–300.

    Google Scholar 

  • El-Kady AM, Ali AF, Farag MM. Development, characterization, and in vitro bioactivity studies of sol–gel bioactive glass/poly(L-lactide) nanocomposite scaffolds. Mater Sci Eng C. 2010;30:120–31.

    CAS  Google Scholar 

  • Gao B, Peng C, Chen GZ, Puma GL. Photo-electro-catalysis enhancement on carbon nanotubes/titanium dioxide (CNTs/TiO2) composite prepared by a novel surfactant wrapping sol–gel method. Appl Cat B. 2008;85:17–23.

    CAS  Google Scholar 

  • Gao SJ, Shi Z, Zhang WB, Zhang F, Jin J. Photoinduced superwetting single-walled carbon nanotube/TiO2 ultrathin network films for ultrafast separation of oil-in-water emulsions. ACS Nano. 2014;8:6344–52.

    CAS  Google Scholar 

  • Giacoin T, Chaput F, Boilot JP. Metal, semiconductor and magnetic nanoparticle inclusions in gels. J Sol-Gel Sci Technol. 1994;2:679–83.

    Google Scholar 

  • Goncalves MC, Bermudez VZ, Ostrovskii D, Carlos LD. Infrared and Raman spectroscopic investigation of Eu3+-doped and di-urethanesil hybrid siliceous materials. Ionics. 2002;8:62–72.

    CAS  Google Scholar 

  • Guglielmi M, Martucci A, Righini GC, Pelli S. CdS- and PbS-doped silica-titania optical waveguides. SPIE Sol-Gel Optics III. 1994;2288:174–82.

    CAS  Google Scholar 

  • Guglielmi M, Martucci A, Menegazzo E, Righini GC, Pelli S, Fick J, Vitrant G. Control of semiconductor particle size in sol-gel thin films. J Sol-Gel Sci Technol. 1997;8:1017–21.

    CAS  Google Scholar 

  • Guo H, Tao S. Silver nanoparticles doped silica nanocomposites coated on an optical fiber for ammonia sensing. Sens Actuators B. 2007;123:578–82.

    CAS  Google Scholar 

  • Hao L, An Q, Xu W. Facile fabrication of superhydrophobic cotton fabric from stearyl methacrylate modified polysiloxane/silica nanocomposite. Fibers Polymers. 2012;13:1145–53.

    CAS  Google Scholar 

  • Hasani M, Coto García AM, Costa-Fernández JM, Sanz-Medel A. Sol–gels doped with polymer-coated ZnS/CdSe quantum dots for the detection of organic vapors. Sens Actuators B. 2010;144:198–202.

    CAS  Google Scholar 

  • Hench LL, Splinter RJ, Allen WC, Greenlee TK. Bonding mechanisms at the interface of ceramic prosthetic materials. J Biomed Mater Res. 1971;5:117–41.

    Google Scholar 

  • Hirano S, Yogo T, Sakamoto W, Yamada S, Nakamura T, Yamamoto T, Ukai H. In situ processing of electroceramic fine particles/polymer hybrids. J Eur Ceram Soc. 2001;21:1479–83.

    CAS  Google Scholar 

  • Hirano S, Yogo T, Sakamoto W, Yamada S, Nakamura T, Yamamoto T, Ukai H, Banno K, Nakafuku T, Ando Y. In situ processing of nano crystalline oxide particles/polymer hybrid. J Sol-Gel Sci Technol. 2003;26:35–41.

    CAS  Google Scholar 

  • Hong Z, Reis RL, Mano JF. Preparation and in vitro characterization of novel bioactive glass ceramic nanoparticles. J Biomed Mater Res A. 2009;88:304–13.

    Google Scholar 

  • Huang Y, Gu Y. New polyimide–silica organic–inorganic hybrids. J Appl Polym Sci. 2003;88:2210–4.

    CAS  Google Scholar 

  • Hummel DA, Torriani IL, Craievich AF, Fox de la Rosa N, Ramos AY, Lyon O. Influence of Cd content and Se doping on the formation of CdSe nanocrystals in silica xerogels: a SAXS study. J Sol-Gel Sci Technol. 1997;8:285–91.

    CAS  Google Scholar 

  • Kango S, Kalia CA, Njuguna J, Habibi Y, Kumar R. Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites; a review. Prog Polym Sci. 2013;38:1232–61.

    CAS  Google Scholar 

  • Kickelbick G. The search of a homogeneously dispersed material – the art of handling the organic polymer/metal oxide interface. J Sol-Gel Sci Technol. 2008;46:281–90.

    CAS  Google Scholar 

  • Kim HW, Kim HE, Knowles JC. Production and potential of bioactive glass nanofibers as a next-generation biomaterial. Adv Funct Mater. 2006a;16:1529–35.

    Google Scholar 

  • Kim HW, Song JH, Kim HE. Bioactive glass nanofiber–collagen nanocomposite as a novel bone regeneration matrix. J Biomed Mater Res A. 2006b;79:698–705.

    Google Scholar 

  • Kizilkaya C, Karataş S, Apohan N, Güngör A. Synthesis and characterization of novel polyimide/SiO2 nanocomposite materials containing phenylphosphine oxide via sol-gel technique. J Appl Polym Sci. 2010;115:3256–64.

    CAS  Google Scholar 

  • Kohjiya S, Ykeda Y. In situ formation of particulate silica in natural rubber matrix by the sol-gel reaction. J Sol-Gel Sci Technol. 2003;26:495–8.

    CAS  Google Scholar 

  • Lakshmi RV, Bharathidasan T, Bera P, Basu BJ. Effect of the size of silica nanoparticles on wettability and surface chemistry of sol-gel superhydrophobic and oleophobic nanocomposite coatings. Surf Coat Tech. 2012;206:3888–94.

    CAS  Google Scholar 

  • Li Y, Fu S, Li Y, Pan Q, Xu G, Yue C. Improvements in transmittance, mechanical properties and thermal stability of silica-polyimide composite films by a novel sol-gel route. Compos Sci Technol. 2007;67:2408–16.

    CAS  Google Scholar 

  • Li Y, Wang W-N, Zhan Z, Woo M-H, Wu C-Y, Biswas P. Photocatalytic reduction of CO2 with H2O on mesoporous silica supported Cu/TiO2 catalysts. Appl Catal B. 2010;100:386–92.

    CAS  Google Scholar 

  • Litrán R, Alcántara R, Blanco E, Ramirez-del-Solar M. Confinement of CdS nanocrystals in a sonogel matrix. J Sol-Gel Sci Technol. 1997;8:275–83.

    Google Scholar 

  • Lu W, Luo Y, Chang G, Sun X. Synthesis of functional SiO2-coated graphene oxide nanosheets decorated with Ag nanoparticles for H2O2 and glucose detection. Biosens Bioelectron. 2011;26:4791–7.

    CAS  Google Scholar 

  • Maquet V, Boccaccini AR, Pravata L, Notingher I, Jérôme R. Porous poly(α-hydroxyacid)/Bioglass® composite scaffolds for bone tissue engineering. I: preparation and in vitro characterization. Biomaterials. 2004;25:4185–94.

    CAS  Google Scholar 

  • Martucci A, Fick J, Schell J, Battaglin G, Guglielmi M. Microstructural and nonlinear optical properties of silica–titania sol-gel film doped with PbS quantum dots. J Appl Phys. 1999a;86:79–87.

    CAS  Google Scholar 

  • Martucci A, Innocenzi P, Fick J, Mackenzie JD. Zirconia-ormosil films doped with PbS quantum dots. J Non-Cryst Solids. 1999b;244:55–62.

    CAS  Google Scholar 

  • Martucci A, Bassiri N, Guglielmi M, Armelao L, Gross S, Pivin JC. NiO-SiO2 sol-gel nanocomposite films for optical gas sensor. J Sol-Gel Sci Technol. 2003a;26:993–6.

    CAS  Google Scholar 

  • Martucci A, Pasquale M, Guglielmi M, Post M, Pivin JC. Nanostructured silicon oxide–nickel oxide Sol–Gel films with enhanced optical carbon monoxide gas sensitivity. J Am Ceram Soc. 2003b;86:1638–40.

    CAS  Google Scholar 

  • Martucci A, Buso B, Guglielmi M, Zbroniec L, Koshizaki N, Post M. Optical gas sensing properties of silica film doped with cobalt oxide nanocrystals. J Sol-Gel Sci Tech. 2004a;32:243–6.

    CAS  Google Scholar 

  • Martucci A, Buso D, De Monte M, Guglielmi M, Cantalini C, Sada C. Nanostructured sol–gel silica thin films doped with NiO and SnO2 for gas sensing applications. J Mater Chem. 2004b;14:2889–95.

    CAS  Google Scholar 

  • Mattei G, Mazzoldi P, Post ML, Buso D, Guglielmi M, Martucci A. Cookie like Au/NiO nanoparticles with optical gas sensing properties. Adv Mat. 2007;19:561–4.

    CAS  Google Scholar 

  • Mennig M, Spanhel J, Schmidt H, Betzholz. Photoinduced formation of silver colloids in a borosilicate sol-gel system. J Non-Cryst Solids. 1992;147&148:326–30.

    Google Scholar 

  • Musto P, Ragosta G, Scarinzi G, Mascia L. Polyimide-silica nanocomposites: spectroscopic, morphological and mechanical investigations. Polymer. 2004;45:1697–706.

    CAS  Google Scholar 

  • Nogami M, Kato A. Formation of CdSxSe1-x microcrystals in sol-gel derived glasses. J Sol-Gel Sci Technol. 1994;2:751–4.

    CAS  Google Scholar 

  • Nogami M, Nagasaka K, Kato E. Preparation of small-particle-size, semiconductor cds-doped silica glasses by the sol–gel process. J Am Cer Soc. 1990a;73:2097–9.

    CAS  Google Scholar 

  • Nogami M, Nagasaka K, Kotani K. Microcrystalline PbS doped silica glasses prepared by the sol-gel process. J Non-Cryst Solids. 1990b;126:87–92.

    CAS  Google Scholar 

  • Nogami M, Suzuki S, Nagasaka K. Sol-gel processing of small-sized CdSe crystal-doped silica glasses. J Non-Cryst Solids. 1991a;135:182–8.

    CAS  Google Scholar 

  • Nogami M, Zhu Y-Q, Tohyama Y, Nagasaka K, Tokizaki T, Nakamura A. Preparation and nonlinear optical properties of quantum-sized CuCl-doped silica glass by the Sol–Gel process. J Am Ceram Soc. 1991b;74:238–40.

    CAS  Google Scholar 

  • Nogami M, Zhu Y-Q, Tohyama Y, Nagasaka K. Preparation and quantum size effect of CuBr microcrystal doped glasses by the sol-gel process. J Non-Cryst Solids. 1991c;134:71–6.

    CAS  Google Scholar 

  • Nogami M, Nagasaka K, Suzuki S. Sol–Gel synthesis of cadmium telluride-microcrystal-doped silica glasses. J Am Ceram Soc. 1992;75:220–3.

    CAS  Google Scholar 

  • Pagliaro M, Pandarus V, Béland F, Ciriminna R, Palmisano G, Demma CP. A new class of heterogeneous Pd catalysts for synthetic organic chemistry. Catal Sci Technol. 2011;1:736–9.

    Google Scholar 

  • Park H, Kim JH, Kim JK, Lee YM. Morphology of a poly(imide siloxane) segmented copolymer/silica hybrid composite. Macromol Rapid Commun. 2002;23:544–50.

    CAS  Google Scholar 

  • Peeters MPJ. An NMR Study of MeTMS based coatings filled with colloidal silica. J Sol-Gel Sci Technol. 2000;19:131–5.

    CAS  Google Scholar 

  • Peter M, Binulal NS, Nair SV, Selvamurugan N, Tamura H, Jayakumar R. Novel biodegradable chitosan-gelatin/nano-bioactive glass ceramic composite scaffolds for alveolar bone tissue engineering. Chem Eng J. 2010a;158:353–61.

    CAS  Google Scholar 

  • Peter M, Binulal NS, Soumya S, Nair SV, Furuike T, Tamura H, Jayakumar R. Nanocomposite scaffolds of bioactive glass-ceramic nanoparticles disseminated chitosan matrix for tissue engineering applications. Carbohyd Polym. 2010b;79:284–9.

    CAS  Google Scholar 

  • Piñero M, Litrán R, Fernández-Lorenzo C, Blanco E, Ramirez-Del-Solar M, De la Rosa-Fox N, Esquivias L, Craievich A, Zarzycki J. CdS semiconductor nanoparticles in silica sonogel matrices. J Sol-Gel Sci Technol. 1994;2:689–94.

    Google Scholar 

  • Ragosta G, Musto P. Polyimide/silica hybrids via the sol-gel route: high performance materials for the new technological challenges. Express Polymer Lett. 2009;3:413–28.

    CAS  Google Scholar 

  • Sadaba I, Ojeda M, Mariscal R, Granados ML. Silica-poly(styrenesulphonic acid) nanocomposites for the catalytic dehydration of xylose to furfural. Appl Catal B. 2014;150–151:421–31.

    Google Scholar 

  • Schmidt HK, Geiter E, Mennig M, Krug H, Becker C, Winkler RP. The sol-gel process for nano-technologies: new nanocomposites with interesting optical and mechanical properties. J Sol-Gel Sci Technol. 1998;13:397–404.

    CAS  Google Scholar 

  • Sepeur S, Frezer G. Commercial application of nanocomposite sol-gel coatings. In: Guglielmi M, Kickelbick G, Martucci A, editors. Sol-gel nanocomposites. New York: Springer; 2014. p. 191–221.

    Google Scholar 

  • Sowntharya L, Lavanya S, Chandra GR, Hebalkar NY, Subasri R. Investigations on the mechanical properties of hybrid nanocomposite hard coatings on polycarbonate. Ceram Int. 2012;38:4221–8.

    CAS  Google Scholar 

  • Spanhel L, Arpac E, Schmidt H. Semiconductor clusters in the sol-gel process: synthesis and properties of CdS nanocomposites. J Non-Cryst Solids. 1992;147&148:657–62.

    Google Scholar 

  • Takada T, Yano T, Yasumori A, Yamane M, Mackenzie JD. Preparation of quantum-size CdS-doped Na2O-B2O3-SiO2 glasses with high non-linearity. J Non-Cryst Solids. 1992;147&148:631–5.

    Google Scholar 

  • Takahashi R, Sato S, Sodesawa T, Kato M, Yoshida S. Preparation of Cu/SiO2 catalyst by solution exchange of wet silica Gel. J Sol-Gel Sci Technol. 2000;19:715–8.

    CAS  Google Scholar 

  • Tohge N, Asuka M, Minami T. Sol-gel preparation and optical properties of silica glasses containing Cd and Zn chalcogenide microcrystals. J Non-Cryst Solids. 1992;147&148:652–6.

    Google Scholar 

  • Xu FQ, Wang JN, Sanderson KD. Organic-inorganic composite nanocoatings with superhydrophobicity, good transparency, and thermal stability. ACS Nano. 2010;4:2201–9.

    CAS  Google Scholar 

  • Xu CX, Su PQ, Chen XF, Meng YC, Yu WH, Xiang AP, Wang YJ. Biocompatibility and osteogenesis of biomimetic bioglass-collagen-phosphatidylserine composite scaffolds for bone tissue engineering. Biomaterials. 2011;32:1051–8.

    CAS  Google Scholar 

  • Ykeda Y, Kameda Y. Preparation of “green” composites by the sol-gel process: in situ silica filled natural rubber. J Sol-Gel Sci Technol. 2004;31:137–42.

    Google Scholar 

  • Ykeda Y, Tanaka A, Kohjiya S. Reinforcement of styrene–butadiene rubber vulcanizate by in situ silica prepared by the sol–gel reaction of tetraethoxysilane. J Mater Chem. 1997;7:1497–503.

    Google Scholar 

  • Yogo T, Kikuta K, Yamada S, Hirano S. Synthesis of barium titanate/polymer composites from metal alkoxide. J Sol-Gel Sci Technol. 1994;2:175–9.

    CAS  Google Scholar 

  • Yuan J, Zhou S, Gu G, Wu L. Effect of the particle size of nanosilica on the performance of epoxy/silica composite coatings. J Mater Sci. 2005;40:3927–32.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Dipartimento di Ingegneria Industriale, Università di Padova, Padova, Italy

    Massimo Guglielmi & Alessandro Martucci

Authors
  1. Massimo Guglielmi
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  2. Alessandro Martucci
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Correspondence to Massimo Guglielmi .

Editor information

Editors and Affiliations

  1. Materials Science and Engineering, Rutgers University, Piscataway, NJ, USA

    Lisa Klein

  2. Instituto de Cerámica y Vidrio, Consejo Superior de Investigaciones Científicas (CSIC), Madrid, Spain

    Mario Aparicio

  3. Department of Chemistry, Lehman College, The City University of New York, Bronx, NY, USA

    Andrei Jitianu

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Guglielmi, M., Martucci, A. (2018). Sol-Gel Nanocomposites. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-32101-1_100

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