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Pechini Processes: An Alternate Approach of the Sol-Gel Method, Preparation, Properties, and Applications

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Handbook of Sol-Gel Science and Technology

Abstract

This chapter highlights a process related to the sol-gel route called “Pechini, or liquid-mix, process.” This process overcomes most of the difficulties and disadvantages that frequently occur in the alkoxide based sol-gel process. After a short historical introduction on the inventor, chemical mechanisms of the process, the advantages on the preparation of ceramic materials, and the drawbacks of the process will be shown. Finally, as examples of applications of the Pechini method, the results of investigation on ceramic superconductors and on Li-ion containing metal phosphates as cathode materials for Li-ion batteries are presented. The versatility, extensive applicability of the Pechini process with low production costs and potential material applications are demonstrated.

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Change history

  • 02 September 2023

    A correction has been published.

References

  • Anderson HU, Pennell MJ, Guha JP. Polymeric synthesis of lead magnesiumniobate powders. Adv Ceram. 1987;21:91–8.

    CAS  Google Scholar 

  • Bednorz JG, Müller KA. Possible high TC superconductivity in the Ba-La-Cu-O system. Zeitschrift für Physik B. 1986;64:189–93.

    Article  CAS  Google Scholar 

  • Chiang C, Huang YT, Shei CY. A summary on the modified Pechini method to prepare high purity ceramic superconducting powders. Chinese J Mater Sci. 1993;25:50–9.

    CAS  Google Scholar 

  • Cadogan IG, MacWilliam IC, Parson R et al. Dictionary of organic compounds, Vol. 2. New York: Oxford University Press; 1965. p. 715.

    Google Scholar 

  • Dimesso L, Spanheimer C, Jacke S, Jaegermann W. Synthesis and characterization of LiFePO4/3-dimensional carbon nanostructure composites as possible cathode materials for Li-ion batteries. Ionics. 2011a;17:429–35.

    Article  CAS  Google Scholar 

  • Dimesso L, Spanheimer C, Jacke S, Jaegermann W. Synthesis and characterization of three-dimensional carbon foams–LiFePO4 Composites. J Power Sources. 2011b;196:6729–34.

    Article  CAS  Google Scholar 

  • Dimesso L, Jacke S, Spanheimer C, Jaegermann W. Investigation on 3-dimensional carbon foams/LiFePO4 composites as function of the annealing time under inert atmosphere J. Alloys Compd. 2011c;509:3777–82.

    Article  CAS  Google Scholar 

  • Dimesso L, Jacke S, Spanheimer C, Jaegermann W. Investigation on LiCoPO4 powders as cathode materials annealed under different atmospheres. J Solid State Electrochem. 2012a;16:3911–9.

    Article  Google Scholar 

  • Dimesso L, Becker D, Spanheimer C, Jaegermann W. Investigation of graphitic carbon foams/LiNiPO4 composites. J Solid State Electrochem. 2012b;16:3791–8.

    Article  CAS  Google Scholar 

  • Dimesso L, Spanheimer C, Jaegermann W. Effect of the Mg-substitution on the graphitic carbon foams – LiNi1−yMgyPO4 composites as possible cathodes materials for 5 V applications. Mater Res Bull. 2013;48:559–65.

    Article  CAS  Google Scholar 

  • Eror NG, Anderson HU. Polymeric precursor synthesis of ceramic materials. MRS Proc. 1986;73:571. https://doi.org/10.1557/PROC-73-571.

  • Julien CM, Mauger A. Review of 5-V electrodes for Li-ion batteries: status and trends. Ionics. 2013;19:951–88.

    Article  CAS  Google Scholar 

  • Kakihana M. Sol–gel preparation of high temperature superconducting oxides. J Sol-Gel Sci Technol. 1996;5:7–55.

    Article  Google Scholar 

  • Kakihana M, Yoshimura M. Synthesis and characteristics of complex multicomponent oxides prepared by polymer complex method. Bull Chem Soc Jpn. 1999;72:1427–43.

    Article  CAS  Google Scholar 

  • Kraytsberg A, Ein-Eli Y. Higher, stronger, better. A review of 5 volt cathode materials for advanced lithium-ion batteries. Adv Energy Mater. 2012;2:922–39.

    Article  CAS  Google Scholar 

  • Lee H, Hong M, Bae S, Lee H, Park E, Kim K. A novel approach to preparing nano-size Co3O4-coated Ni powder by the Pechini method for MCFC cathodes. J Mater Chem. 2003;13:2626–32.

    Article  CAS  Google Scholar 

  • Lessing PA. Mixed-cation oxide powders via polymeric precursors. Ceram Bull. 1989;68:1002–7.

    CAS  Google Scholar 

  • Lin J, Yu M, Lin C, Liu X. Multiform oxide optical materials via the versatile Pechini-Type sol–gel process: synthesis and characteristics. J Phys Chem C. 2007;111:5835–45.

    Article  CAS  Google Scholar 

  • Massachusetts College of Fine Arts (MCLA) library. “The Sprague Log” Preserving a Company Newsletter, Hardman Library Grant Project, Massachusetts College of Liberal Arts, (1988–1989). http://mcla.libguides.com/localhistory/spraguelog

  • Pechini MP. Patent US 3 330 697 (1967a).

    Google Scholar 

  • Pechini MP. Patent CA 759514 (1967b).

    Google Scholar 

  • Peng ZS, Hua ZQ, Li YN, Di J, Ma J, Chu YM, Zhen WN, Yang YL, Wang HJ, Zhao ZX. Synthesis and properties of the bi-based superconducting powder prepared by the Pechini process. J Supercond. 1998;11(6):749–54.

    Article  CAS  Google Scholar 

  • Reichenbach HM, An H, McGinn PJ. Combinatorial synthesis and characterization of mixed metal oxides for soot combustion. Appl Catal Environ. 2003;44:347–54.

    Article  CAS  Google Scholar 

  • Roy R, Osborn EF. Metal organics as ceramic precursors. Am Mineral. 1954;39:853–86.

    CAS  Google Scholar 

  • Roy DM, Roy R. Synthesis and stability of minerals in the system MgO-AI2O3-SiO2-H2O. Am Mineral. 1955;40:147–78.

    CAS  Google Scholar 

  • Tai LW, Lessing PA. Modified resin-intermediate processing of perovskite powders: part I. Optimization of polymeric precursors. J Mater Res. 1992;7:502–10.

    Article  CAS  Google Scholar 

  • Tuttle BA, Voigt JA. In: Messing GL, Fuller Jr ER, Hausner H, editors. Ceramic powder science II. Westerville: American Ceramic Society; 1988. Chapter 4: Consolidation of ceramic thick films, pp. 62–69.

    Google Scholar 

  • Yoshino M, Kakihana M, Cho WS, Kato H, Kuto A. Polymerizable complex synthesis of pure Sr2NbxTa2-xO7 solid solutions with high photocatalytic activities for water decomposition into H2 and O2. Chem Mater. 2002;14:3369–76.

    Article  CAS  Google Scholar 

  • Weber IT, Rousseau A, Guilloux-Viry M, Bouquet V, Perrin A. Microstructure comparison between KNbO3 thin films grown by polymeric precursors and PLD methods. Sol State Sci. 2005;7:1317–23.

    Article  CAS  Google Scholar 

  • Zhang SC, Messing GL, Huebner W, Coleman MM. Synthesis of YBa2Cu3O7-x fibers from an organic acid solution. J Mater Res. 1990;5:1806–12.

    Article  CAS  Google Scholar 

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Acknowledgments

I owe personally many thanks to Prof. W. Jaegermann (Head of the Surface Science Division, Earth and Material Sciences Department, Technische Universitaet Darmstadt) for giving me the possibility to contribute to this project and for the support during my work.

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Correspondence to Lucangelo Dimesso .

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Dimesso, L. (2018). Pechini Processes: An Alternate Approach of the Sol-Gel Method, Preparation, Properties, and Applications. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-32101-1_123

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