Skip to main content

2012 | OriginalPaper | Buchkapitel

2. Electron Paramagnetic Resonance Theory

verfasst von : Matthias J. N. Junk

Erschienen in: Assessing the Functional Structure of Molecular Transporters by EPR Spectroscopy

Verlag: Springer Berlin Heidelberg

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In 1921, Gerlach and Stern observed that a beam of silver atoms splits into two lines when it is subjected to a magnetic field. While the line splitting in optical spectra, first found by Zeeman in 1896, could be explained by the angular momentum of the electrons, the s-electron of silver could not be subject to such a momentum, not to mention that an azimuthal quantum number l = 1/2 cannot be explained by classical physics. At that time, quantum mechanics was still an emerging field in physics and it took another three years until this anormal Zeeman effect was correctly interpreted by the joint research of Uhlenbeck, a classical physicist, and Goudsmit, a fellow of Paul Ehrenfest. They postulated a so-called ‘spin’, a quantized angular momentum, as an intrinsic property of the electron. This research marks the cornerstone of electron paramagnetic resonance (EPR) spectroscopy which is based on the transitions between quantized states of the resulting magnetic moment.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Fußnoten
1
The correct term for B is magnetic induction. The term magnetic field originates from older magnetic resonance literature and is still commonly used while its symbol H was replaced by B.
 
Literatur
1.
Zurück zum Zitat Gerlach W, Stern O (1921) Z Phys 8:110–111 Gerlach W, Stern O (1921) Z Phys 8:110–111
4.
6.
8.
9.
10.
14.
Zurück zum Zitat Holczer K, Schmalbein D (1987) Bruker Rep 1:22 Holczer K, Schmalbein D (1987) Bruker Rep 1:22
15.
Zurück zum Zitat Höfer P, Maresch GG, Schmalbein D, Holczer K (1996) Bruker Rep 142:15 Höfer P, Maresch GG, Schmalbein D, Holczer K (1996) Bruker Rep 142:15
16.
Zurück zum Zitat Likhtenshtein GI, Yamauchi J, Nakatsuji S, Smirnov AI, Tamura R (2008) Nitroxides—applications in chemistry, biomedicine and materials science. Wiley-VCH, Weinheim Likhtenshtein GI, Yamauchi J, Nakatsuji S, Smirnov AI, Tamura R (2008) Nitroxides—applications in chemistry, biomedicine and materials science. Wiley-VCH, Weinheim
17.
Zurück zum Zitat Jeschke G (2006) Site-specific information on macromolecular materials by combining CW and pulsed ESR on spin probes. In: Schlick S (ed) Advanced ESR methods in polymer research. Wiley, New York Jeschke G (2006) Site-specific information on macromolecular materials by combining CW and pulsed ESR on spin probes. In: Schlick S (ed) Advanced ESR methods in polymer research. Wiley, New York
18.
Zurück zum Zitat Hinderberger D, Jeschke G (2006) Site-specific characterization of structure and dynamics of complex materials by EPR spin probes. In: Webb GA (ed) Modern magnetic resonance. Springer, London Hinderberger D, Jeschke G (2006) Site-specific characterization of structure and dynamics of complex materials by EPR spin probes. In: Webb GA (ed) Modern magnetic resonance. Springer, London
19.
Zurück zum Zitat Jeschke G, Pannier M, Spiess HW (2000) Double electron–electron resonance. In: Berliner LJ, Eaton GR, Eaton SS (eds) Biological magnetic resonance, vol 19: distance measurements in biological systems by EPR. Kluwer Academic, New York Jeschke G, Pannier M, Spiess HW (2000) Double electron–electron resonance. In: Berliner LJ, Eaton GR, Eaton SS (eds) Biological magnetic resonance, vol 19: distance measurements in biological systems by EPR. Kluwer Academic, New York
21.
Zurück zum Zitat Borbat PP, Freed JH (2000) Double-quantum ESR and distance measurements. In: Berliner LJ, Eaton GR, Eaton SS (eds) Biological magnetic resonance, vol 19: distance measurements in biological systems by EPR. Kluwer Academic, New York Borbat PP, Freed JH (2000) Double-quantum ESR and distance measurements. In: Berliner LJ, Eaton GR, Eaton SS (eds) Biological magnetic resonance, vol 19: distance measurements in biological systems by EPR. Kluwer Academic, New York
24.
Zurück zum Zitat Borbat PP, Costa-Filho AJ, Earle KA, Moscicki JK, Freed JH (2001) Science 291:266–269CrossRef Borbat PP, Costa-Filho AJ, Earle KA, Moscicki JK, Freed JH (2001) Science 291:266–269CrossRef
25.
26.
Zurück zum Zitat Schmidt-Rohr K, Spiess HW (1994) Multidimensional solid-state NMR and polymers. Academic Press, London Schmidt-Rohr K, Spiess HW (1994) Multidimensional solid-state NMR and polymers. Academic Press, London
27.
Zurück zum Zitat Dockter C, Volkov A, Bauer C, Polyhach Y, Joly-Lopez Z, Jeschke G, Paulsen H (2009) Proc Nat Acad Sci U S A 106:18485–18490CrossRef Dockter C, Volkov A, Bauer C, Polyhach Y, Joly-Lopez Z, Jeschke G, Paulsen H (2009) Proc Nat Acad Sci U S A 106:18485–18490CrossRef
28.
Zurück zum Zitat Hinderberger D, Spiess HW, Jeschke G (2010) Appl Magn Reson 37:657–683CrossRef Hinderberger D, Spiess HW, Jeschke G (2010) Appl Magn Reson 37:657–683CrossRef
29.
Zurück zum Zitat Odom B, Hanneke D, D’Urso B, Gabrielse G (2006) Phys Rev Lett 97:030801CrossRef Odom B, Hanneke D, D’Urso B, Gabrielse G (2006) Phys Rev Lett 97:030801CrossRef
31.
Zurück zum Zitat Abragam A, Pryce MHL (1951) Proc R Soc A: Math Phys Sci 205:135–153CrossRef Abragam A, Pryce MHL (1951) Proc R Soc A: Math Phys Sci 205:135–153CrossRef
32.
Zurück zum Zitat Solomon EI, Hodgson KO (1998) Spectroscopic methods in bioinorganic chemistry. Clarendon, OxfordCrossRef Solomon EI, Hodgson KO (1998) Spectroscopic methods in bioinorganic chemistry. Clarendon, OxfordCrossRef
34.
Zurück zum Zitat Molin YN, Salikhov KM, Zamaraev KI (1980) Spin exchange–principles and applications in chemistry and biology. Springer Verlag, Berlin Molin YN, Salikhov KM, Zamaraev KI (1980) Spin exchange–principles and applications in chemistry and biology. Springer Verlag, Berlin
36.
Zurück zum Zitat Hubbell WL, Cafiso DS, Altenbach C (2000) Nat Struct Biol 7:735–739CrossRef Hubbell WL, Cafiso DS, Altenbach C (2000) Nat Struct Biol 7:735–739CrossRef
37.
Zurück zum Zitat Kocherginsky N, Swartz HM (1995) Nitroxide spin labels - reactions in biology and chemistry. CRC Press, Boca Raton Kocherginsky N, Swartz HM (1995) Nitroxide spin labels - reactions in biology and chemistry. CRC Press, Boca Raton
38.
Zurück zum Zitat Fajer PG, Brown L, Song L (2007) Practical pulsed dipolar ESR (DEER). In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol 27: ESR spectroscopy in membrane biophysics. Springer, New York Fajer PG, Brown L, Song L (2007) Practical pulsed dipolar ESR (DEER). In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol 27: ESR spectroscopy in membrane biophysics. Springer, New York
39.
Zurück zum Zitat D. Hinderberger (2004) Polyelectrolytes and their counterions studied by EPR spectroscopy, Doctoral Dissertation, Johannes Gutenberg-Universität, Mainz, D. Hinderberger (2004) Polyelectrolytes and their counterions studied by EPR spectroscopy, Doctoral Dissertation, Johannes Gutenberg-Universität, Mainz,
40.
Zurück zum Zitat Beth AH, Robinson BH (1989) Nitrogen-15 and deuterium substituted spin labels for studies of very slow rotational motion. In: Berliner LJ, Reuben J (eds) Biological magnetic resonance, vol 8: Spin labeling—theory and applications. Plenum Press, New York Beth AH, Robinson BH (1989) Nitrogen-15 and deuterium substituted spin labels for studies of very slow rotational motion. In: Berliner LJ, Reuben J (eds) Biological magnetic resonance, vol 8: Spin labeling—theory and applications. Plenum Press, New York
41.
Zurück zum Zitat Edmonds AR (1960) Angular momentum in quantum mechanics. Princeton University Press, Princeton Edmonds AR (1960) Angular momentum in quantum mechanics. Princeton University Press, Princeton
42.
Zurück zum Zitat Jeschke G, Schlick S (2006) Continuous-wave and pulsed ESR methods. In: Schlick S (ed) Advanced ESR methods in polymer research. Wiley, Hoboken Jeschke G, Schlick S (2006) Continuous-wave and pulsed ESR methods. In: Schlick S (ed) Advanced ESR methods in polymer research. Wiley, Hoboken
45.
Zurück zum Zitat Schneider DJ, Freed JH (1989) Continuous-wave and pulsed ESR methods. In: Berliner LJ, Reuben J (eds) Biological magnetic resonance, vol 8: spin labeling–theory and applications. Plenum Press, New York Schneider DJ, Freed JH (1989) Continuous-wave and pulsed ESR methods. In: Berliner LJ, Reuben J (eds) Biological magnetic resonance, vol 8: spin labeling–theory and applications. Plenum Press, New York
48.
Zurück zum Zitat Wegener C, Savitsky A, Pfeiffer M, Möbius K, Steinhoff HJ (2001) Appl Magn Reson 21:441–452CrossRef Wegener C, Savitsky A, Pfeiffer M, Möbius K, Steinhoff HJ (2001) Appl Magn Reson 21:441–452CrossRef
49.
Zurück zum Zitat Bordignon E, Steinhoff HJ (2007) Membrane protein structure and dynamics studied by site-directed spin-labeling ESR. In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol 27: ESR spectroscopy in membrane biophysics. Springer, New York Bordignon E, Steinhoff HJ (2007) Membrane protein structure and dynamics studied by site-directed spin-labeling ESR. In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol 27: ESR spectroscopy in membrane biophysics. Springer, New York
51.
Zurück zum Zitat Stoll S, Schweiger A (2007) Easy spin: simulating cw ESR spectra. In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol. 27: ESR spectroscopy in membrane biophysics. Springer, New York Stoll S, Schweiger A (2007) Easy spin: simulating cw ESR spectra. In: Hemminga MA, Berliner LJ (eds) Biological magnetic resonance, vol. 27: ESR spectroscopy in membrane biophysics. Springer, New York
53.
Zurück zum Zitat Goldman SA, Bruno GV, Polnaszek CF, Freed JH (1972) J Chem Phys 56:716–735CrossRef Goldman SA, Bruno GV, Polnaszek CF, Freed JH (1972) J Chem Phys 56:716–735CrossRef
54.
Zurück zum Zitat Hwang JS, Mason RP, Hwang LP, Freed JH (1975) J Phys Chem 79:489–511CrossRef Hwang JS, Mason RP, Hwang LP, Freed JH (1975) J Phys Chem 79:489–511CrossRef
56.
Zurück zum Zitat Sørensen OW, Eich GW, Levitt MH, Bodenhausen G, Ernst RR (1983) Prog Nucl Magn Reson Spectrosc 16:163–192CrossRef Sørensen OW, Eich GW, Levitt MH, Bodenhausen G, Ernst RR (1983) Prog Nucl Magn Reson Spectrosc 16:163–192CrossRef
57.
61.
62.
Zurück zum Zitat Höfer P, Grupp A, Nebenführ H, Mehring M (1986) Chem Phys Lett 132:279–282CrossRef Höfer P, Grupp A, Nebenführ H, Mehring M (1986) Chem Phys Lett 132:279–282CrossRef
63.
Zurück zum Zitat Gemperle C, Aebli G, Schweiger A, Ernst RR (1990) J Magn Reson 88:241–256CrossRef Gemperle C, Aebli G, Schweiger A, Ernst RR (1990) J Magn Reson 88:241–256CrossRef
64.
Zurück zum Zitat Kurshev VV, Raitsimring AM, Tsvetkov YD (1989) J Magn Reson 81:441–454CrossRef Kurshev VV, Raitsimring AM, Tsvetkov YD (1989) J Magn Reson 81:441–454CrossRef
65.
Zurück zum Zitat Jeschke G, Pannier M, Godt A, Spiess HW (2000) Chem Phys Lett 331:243–252CrossRef Jeschke G, Pannier M, Godt A, Spiess HW (2000) Chem Phys Lett 331:243–252CrossRef
69.
Zurück zum Zitat Milov AD, Salikhov KM, Shirov MD (1981) Fiz Tverd Tela 23:975–982 Milov AD, Salikhov KM, Shirov MD (1981) Fiz Tverd Tela 23:975–982
70.
Zurück zum Zitat Milov AD, Maryasov AG, Tsvetkov YD (1998) Appl Magn Reson 15:107–143CrossRef Milov AD, Maryasov AG, Tsvetkov YD (1998) Appl Magn Reson 15:107–143CrossRef
71.
Zurück zum Zitat Pannier M, Veit S, Godt A, Jeschke G, Spiess HW (2000) J Magn Reson 142:331–340CrossRef Pannier M, Veit S, Godt A, Jeschke G, Spiess HW (2000) J Magn Reson 142:331–340CrossRef
72.
Zurück zum Zitat Jeschke G, Panek G, Godt A, Bender A, Paulsen H (2004) Appl Magn Reson 26:223–244CrossRef Jeschke G, Panek G, Godt A, Bender A, Paulsen H (2004) Appl Magn Reson 26:223–244CrossRef
73.
Zurück zum Zitat Jeschke G, Chechik V, Ionita P, Godt A, Zimmermann H, Banham J, Timmel CR, Hilger D, Jung H (2006) Appl Magn Reson 30:473–498CrossRef Jeschke G, Chechik V, Ionita P, Godt A, Zimmermann H, Banham J, Timmel CR, Hilger D, Jung H (2006) Appl Magn Reson 30:473–498CrossRef
74.
Zurück zum Zitat Atherton NM (1973) Principles of electron spin resonance. Ellis Horwood, Chichester Atherton NM (1973) Principles of electron spin resonance. Ellis Horwood, Chichester
75.
Zurück zum Zitat Weil A, Bolton JR, Wertz JE (1994) Electron paramagnetic resonance: elementary theory and practical applications. Wiley, New York Weil A, Bolton JR, Wertz JE (1994) Electron paramagnetic resonance: elementary theory and practical applications. Wiley, New York
76.
Zurück zum Zitat Schweiger A, Jeschke G (2001) Principles of pulse electron paramagnetic resonance. Oxford University Press, Oxford Schweiger A, Jeschke G (2001) Principles of pulse electron paramagnetic resonance. Oxford University Press, Oxford
77.
Zurück zum Zitat Hore PJ, Jones JA, Wimperis S (2000) NMR: The toolkit. Oxford University Press, Oxford Hore PJ, Jones JA, Wimperis S (2000) NMR: The toolkit. Oxford University Press, Oxford
78.
Zurück zum Zitat Jeschke G (1998) Einführung in die ESR-Spektroskopie (lecture notes), Mainz Jeschke G (1998) Einführung in die ESR-Spektroskopie (lecture notes), Mainz
79.
Zurück zum Zitat Jeschke G (2008) Kurze Einführung in die elektronenparamagnetische Resonanz-spektroskopie (lecture notes), Konstanz Jeschke G (2008) Kurze Einführung in die elektronenparamagnetische Resonanz-spektroskopie (lecture notes), Konstanz
Metadaten
Titel
Electron Paramagnetic Resonance Theory
verfasst von
Matthias J. N. Junk
Copyright-Jahr
2012
Verlag
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-25135-1_2

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.