Abstract
It is impossible to describe in detail the chemical properties of elementary boron in a few pages. The object of this article is to give general information. A more complete study of the reactions of boron with the other elements of the periodic table is presented in Chapters C VI-XIII of this volume.
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AMBERGER, E., DRUMINSKI, M., PLOOG, K.: Boron carbon system in the kinetic range of formation: Pyrolytic formation of carbon — rich boron — carbon phases. J. Less Common Metals 23, 43–52 (1971)
AMBERGER, E., RAUH, P.: Phosphorous incorporated lattice with boron — monoclinic boron — phosphorus phase B14P. J. Cryst. Growth 16, 259–64 (1972)
AMBERGER, E., SCHMIDT, H.: Nitrogen — induced lattice of boron — I tetragonal boron nitride (B12)4 B2N1–2. Z. Naturforschg. 26, 641–46 (1971)
BAHN, G.: Investigation of the concept of nitrogen reaction in Ramjet engines, West States Sec. Combust. Inst. WSS. CI 69–12 (1969)
BARTON, L., NICHOLLS, D.: The hydrogenation of boron monoxide to diborane and the reactions of boron and boron carbide with titanium and zirconium dioxide. J. Inorg, Nucl. Chem. 28, 1367–72 (1966)
BECHER, H., THEVENOT, F.: IR spectra of boron carbide and some other compounds of this structural type. 2nd IME Boron Meeting Leeds (1974) and Z. anorg. allg. Chem 410, 274–286 (1974)
BESOMBES-VAILHE, J., TRICHE, H.: Spectrographs analysis of boron monoxide bands and calculation of rotation temperature from one of these bands during titanium diboride formation in a plasma torch. Analusis 1, 135–9 (1972)
BIRYUKOV, V., VINOGRADOV, B., PEREZHOGIN, G., KHOLOPOVA, M.: Gas-phase composition during electric discharge alloying elektro. Tekh. Sb. Upr. Kach. Stand. 5, 96–9 (1970)
BLACKBURN, P., BUCHLER, A., STAUFFER, J.: Thermodynamics of vaporization in the aluminum oxide-boron oxide system, J. Phys. Chem 70, 2469–74 (1969)
BORYAKOVA, V., GRINBERG, YA.K., ZHUKOV, E., KORYAZKIN, V., MEDVEDEVA, Z.: Phase diagram of the boron-selenium system. Izv. Akad. Nauk SSSR. Neorg. Mater 5, 477–80 (1969)
BOROVINSKAYA, I., MERZHAKOV, A.: Self-propagating high temperature synthesis of refractory inorganic compounds metalloterm. Protsessy, Khim. Met. Mater. Konz. 58–65 (1971)
BOSCH, F.: Synthesis of boron carbide and nitride-slicates. Ind. 27, 587–90 (1962)
BRYANT, J., SIPPEL, N.: Ignition of metal powders in gaseous chlorine trifluoride. J. Spacecr. Rockets 8, 192–3 (1971a)
BRYANT, J., SIPPEL, N.: Amorphous Boron Dust Flames — Combust. Sci. Technol. 3, 145–51 (1971b)
CUEILLERON, J., HILLEL, R.: Preparation of boron selenide B2Se3. Bull. Soc. Chim. Fr. 2973–6 (1967)
CUEILLERON, J., LAHET, G., THEVENOT, F., PARIS, R.: New preparation of metal borides, J. Less Common Metals 24, 317–22 (1971)
CUEILLERON, J., PICHAT, P.: Action of hydrogen on boron. Bull. Soc. Chim. Fr. 10, 2547–8 (1964)
DEL DUCA, B.: Electrochemical behavior of the boron anode in aqueous solutions. N.A.S.A. Tech. Note T.N.D. 6589 (1972)
DE VRIES, R., FLEISCHER, J., Phase equilibrium pertinent to the growth of cubic boron nitride. J. Cryst. Growth 13–14, 88–92 (1972)
DEVYATYKH, G., YUSHIN, A.: Reaction of boron with hydrogen. Zh. Neorg. Khim. 14, 2015–8 (1969)
DONNET, J., KOBEL, L.: Superficial oxidation of amorphous boron by sulfuric acid. Rev. Chim. Miner. 4, 249–67 (1967a)
DONNET, J., KOBEL, L.: Superficial oxidation of amorphous boron with sulfuric acid. Rev. Chim. Miner. 4, 399–412 (1967b)
DONNET, J., MESSIET, J., Oxidation of amorphous boron, Bull. Soc. Chim. Fr. 2963–7 (1967)
ELISEEV, A., BABITSYNA, A., MEDVEDEVA, Z.: X-ray study of the boron — arsenic system. Zh. Neorgan. Khim., 9, 1158–62 (1964)
ERMOLENKO, N., TABULINA, L., EFROS, M.: Composition of a compound formed during the heat treatment of the aluminum oxide-boron system. Vestsi. Akad. Navuk. Belarus SSR, Ser. Khim. Navuk. 2, 5–10 (1973)
ETTMAYER, P., HORN, H., SCHWETZ, K.: Electron-probe microanalysis in the silicon -boron system. Mikrochim. Acta, Suppl. 4, 87–95 (1969)
FAVRE, R., THEVENOT, F.: Synthesis and study of titanium, zirconium and hafnium diborides. Bull. Soc. Chim. Fr. 3911, 16 (1971)
GAL’CHENKO, G.L., TIMOFEEV, B.I., GRINBERG, Y.K.: Heat of formation of boron phos phide. Izv. Akad. Nauk SSSR, Neorg. Mater. IB, 634–638 (1972)
GARDNER, P.J.: The standard heat of formation of boron phosphide. Inorg. Chem. 8, 1187–1188 (1969)
GOOD, W., MANSON, M.: Thermochemistry of boron and some of its compounds, J. Phys. Chem. 70, 97–104 (1966)
GRAYON, P., BUFORD, J., ARMINGTON, A.: Pressure synthesis of boron phosphide and boron arsenide. Electrochem. Technol. 3, 338–9 (1965)
GROSS, P., HAYMAN, C., STUART, M.C.: Heat of formation of boron phosphide. Trans. Faraday. Soc. 65, 2628–2632 (1969)
HAGENMULLER, P., CHOPIN, F.: Boron-sulfur system. C.R. Acad. Sci. (Paris) 255, 2259–2260 (1962)
HILLEL, R., CUEILLERON, J.: Boron selenide B2Se3, Bull. Soc. Chim. Fr 98–103 (1972)
HOLCOMBE, C, HORNE, O.: Preparation of boron suboxide B7O. J. Amer. Ceram. Soc., 55, 106 (1972)
JEAN-BLAIN, H., CUEILLERON, J.: Synthesis of boron suboxide B7O. C.R. Acad. Sci. (Paris) Ser. C 277, 977–78 (1973)
KIEFFER, R., GUGEL, E., LEIMER, G., ETTMAYER, P.: Boron-carbon system. Ber. Deut. Keram. Ges. 48, 358–359 (1971)
KING, M.: Boron ignition and combustion in air-augmented rocket afterburners. Combustion Sci. Techn. 5, 155–164 (1972)
KIRK, R.: Synthetic chemistry of several high temperature boron-containing species. Univ. Microfilms, Ann Arbor, Michigan, Order No. 70–17, 594 (1969)
KIRK, R., TIMMS, P.: Synthesis of thioborine, HBS. Chem. Commun. 1, 18–19 (1967)
KORYAZHKIN, V.: Electronic absorption spectrum of the boron selenide (BSe2) molecule. Vestn. Mosk. Univ. Khim. 13, 719–720 (1972)
KRENEV, V., EVDOKIMOV, V.: Kinetics of the reaction of boron with boron trichloride. Zh. Neorg. Khim. 17, 327–330 (1972)
LAMIKHOV, L.: Preparation, properties and uses of refractory alloys of the silicon-boron system. Izv. Akad. Nauk. SSSR, Neorg. Mater. 4, 1076–1080 (1968)
MACEK, A., SAMPLE, J., MC KENZIE: Combustion of boron particles at elevated pres sures. 13th Symp. Combust. 859–868 (1970)
MCLAIN, W., WILLIAMS, R., WALTER, L.: Ignition and combustion of single boron particles in air at ambient pressure. West States Sect. Combust. Inst. No. 70–13 (1970)
MEDVEDEVA, Z., BORYAKOVA, V., GRINBERG, YA.KH., ZHUKOV, E.: Phase diagram of the boron disulfide — sulfur system. Zh. Neorg, Khim. 13, 1440–1443 (1968)
MOHAN, G., WILLIAMS, F.: Ignition and combustion of boron in oxygen — inert atmosphere. Am. Inst. Aeronaut. Astronaut. J. 108, 776–783 (1972)
NASLAIN, R., ETOURNEAU, J., HAGENMULLER, P.: Boron-potassium system. Bull. Soc. Chim. Fr. 2529–2538 (1967)
OSUGI, J., SHIMIZU, K., TANAKA, Y.: Reaction of boron and arsenic at high temperature and high pressure. Proc. Japan. Acad. 42, 48–53 (1966)
PERET, J.: Preparation and properties of the boron phosphiedes. J. Amer. Ceram. Soc. 47, 44–46 (1964)
PERKOVA, G., DEMIN, A., CHALYKH, E., CUNDOROVA, N.: Solubility of boron in a graphite lattice. Tsvet. Metal. 4, 42–45 (1973)
PESHEV. P.: Thermodynamic study of some reactions used for the preparation of borides of groups II-VI. Rev. Int. Hautes Temp. et Refract. 4, 289–296 (1967)
PETRAK, D., RUH, R., GOOSEY, B.: Preparation and characterization of boron suboxide. Nat. Nur. Stand. U.S. Spec. Publ. No. 364, 605–611 (1972)
PLOOG, K.: Preparation of a rhombohedral boron carbide B13C2. J. Less. Common Metals 31, 177–180 (1973)
PLOOG, K.: Tetragonal and orthorhombic boron carbide. J, Less Sommon Metals 75, 115–130 (1974a)
PLOOG, K.: Rhombohedral boron carbide. J. Less Common. Metals 35, 131–145 (1974b)
REKOV, A., SAMSONOV, V.: Boron solid solutions in boron carbide. Khim. Tverd. Topl 2, 140–142 (1971)
RHEIN, R.: Ignition of ultrafine powder boron in air, nitrogen carbon dioxide and in mixtures of nitrogen and carbon dioxide Pyrodynamics 4, 55–6 (1966)
ROSNER, D., ALLENDORF, H., Kinetics of the attack of refractory solids by atomic and molecular fluorine. J. Phys. Chem. 75, 308–317 (1971)
ROSSO, J., DUBUSC, M.: Boron sulfur and compounds boron sulfur metals. Chimie Industrie 102, 409–415 (1969)
SAMSONOV, G., SPLETSOV, V.: Manufacture of boron silicon alloys. Poroshkovaya Met. Akad, Nauk. Ukr. S.S.R. 4, 58–67 (1964)
SAVELEV, B., KRENEV, V., EVDOKIMOV, V.: Interaction of hydrogen bromide with elemen tal boron. Th. Neorg. Khim. 18, 317–319 (1973a)
SAVELEV, B., KRENEV, V., EVDOKIMOV, V.: Reaction of boron tribromide with elemental boron. Zh. Neorg. Khim. 18, 1413 (1973b)
SCHADOW, K.: Boron combustion characteristics inducted rockets. Combust, Sci. Technol. 5, 107–117 (1972)
THEVENOT, F.: Heat of formation of crystalline boron phosphide. Bull. Soc. Chim. 98–101 (1968)
THEVENOT, F., CUEILLERON, J.: Preparation of crystallized boron phosphide. Bull. Soc. Chim. 3204–3206 (1968)
THEVENOT, F., VIALA, J.: Comparison of methods of determination of impurities in boron. Analysis 3, 76–84 (1975)
ZOLOTAR, E., OZEROV, E.: Calculation of the inflammability limit of a boron particle. Fiz. Goreniya. Vzryva 9, 515–521 (1973)
ZUBOVA, E., BURDINA, K.: Synthesis of B6O at high pressures. Dok. Akad. Nauk. S.S.S.R. 197, 1055–1056 (1971)
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Cueilleron, J., Thevenot, F. (1977). Chemical Properties of Boron. In: Matkovich, V.I. (eds) Boron and Refractory Borides. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66620-9_12
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