Abstract
The microstructures and the microwave dielectric characteristics of BaO·Nd2O3·5TiO2 ceramics were determined as a function of the sintering conditions. The ceramics were confirmed to have a ternary orthorhombic major phase with minor amounts of Nd2Ti2O7 and TiO2, and nearly equiaxed fine structures and homogeneous columnar structures were obtained at sintering temperatures of 1340 ‡C and 1370 ‡C, respectively, while discontinuous and excess grain growth were observed at sintering temperatures 1350–1360 ‡C and 1380 ‡C, due to the formation of a liquid phase. The desired value of Qf was achieved in ceramics with fine-grained and/or homogeneous microstructures, and the discontinuous and excess grain growth was found to be seriously harmful to the dielectric properties.
Similar content being viewed by others
References
H. M. O'BRYAN Jr, J. THOMSON Jr. and J. K. PLOUDE, J. Amer. Ceram. Soc. 57 (1974) 450.
J. K. PLOUDE, D. F. LINN, H. M. O'BRYAN Jr. and J. THOMSON Jr, J. Amer. Ceram. Soc. 58 (1975) 418.
S. HIRANO, T. HAYASHI and A. HATTORI, J. Amer. Ceram. Soc. 74 (1991) 1320.
K. WAKINO, K. MINAI and H. TAMURA, J. Amer. Ceram. Soc. 67 (1984) 278.
S. KAWASHIMA, M. NISHIDA, I. UEDA and H. OUCHI, J. Amer. Ceram. Soc. 66 (1983) 421.
S. B. DESU and H. M. O'BRYAN, J. Amer. Ceram. Soc. 68 (1985) 547.
D. KOLAR, Z. STABLER, S. GABERSCEK and D. SUVOROV, Ber. Dt. Keram. Ges. 55 (1978) 346.
D. KOLAR, S. GABERSCEK and B. VOLAVSEK, J. Solid State Chem. 38 (1981) 158.
E. S. RAZOGON, A. M. GENS, M. B. VARFOLOMEEV, S. S. KOROVIN and V. S. KOSTOMAROV, Russ. J. Inorg. Chem. 25 (1980) 10701.
J. TAKAHASHI, T. IKEGAMI and K. KAGEYAMA, J. Amer. Ceram. Soc. 74 (1991) 1868.
R. C. MATVEEVA, M. B. VARFOLOMEEV and L. S. IL'YUSCHENKO, Russ. J. Inorg. Chem. 29 (1984) 31.
T. JAAKOLA, A. UUSIMAKI, R. RAUTIOAHO and S. LEPPAVUORI, J. Amer. Ceram. Soc. C 69 (1986) 234.
J. P. GUHA, J. Amer. Ceram. Soc. C 74 (1991) 878.
B. W. HAKKI and P. D. COLEMAN, IRE Microwave Theor. Tech. 8 (1960) 402.
X. M. CHEN, Y. SUZUKI and N. SATO, Mater. Lett. 16 (1993) 75.
W. D. KINGERY, H, K. BOWEN and D. R. UHLMANN, Introduction of ceramics (Wiley, New York, 1976) p. 498.
T. NEGAS, G. YEAGER, S. BELL and R. AMREN, “Chemistry of electronic ceramic materials”, edited by P. K. Davis and R. S. Roth (NIST Spec. Publication 804, USA, 1991) p. 21.
D. KOLAR, in “Chemistry of electronic ceramic materials”, edited by P. K. Davis and R. S. Roth NIST Spec. Publication 804, USA (1991) p. 3.
D. HENNINGS, Sci. Ceram. 12 (1984) 405.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chen, X.M., Suzuki, Y. & Sato, N. Microstructures and microwave dielectric characteristics of ceramics with the composition BaO·Nd2O3·5TiO2 . J Mater Sci: Mater Electron 6, 10–16 (1995). https://doi.org/10.1007/BF00208127
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00208127