Abstract
Incoherent Z-contrast imaging in the scanning transmission electron microscope allows atom column positions to be deduced directly from the experimental image, including locations where the column separation is less than the resolution limit. Maximum entropy analysis applied to the incoherent image locates the high-Z columns to an accuracy of ±0.2 Å. Oxygen coordination at the boundary plane can be deduced by high spatial resolution electron energy loss spectroscopy, and approximate column positions determined by simple bond-valence sum calculations. Observations of 25° (Σ=85), 36° (Σ=5) and 67° (Σ=13) [001] symmetric tilt grain boundaries in SrTiO3 bicrystals show that “half columns” are a ubiquitous feature of grain boundary structural units. The observed structural units can be combined to produce structural models for symmetric tilt boundaries over a 0–90° range. The Σ=17 (410), Σ=5 (310), and Σ=5 (210) are found to be favored boundaries and the structures of all the other tilt boundaries are comprised of these units combined with Σ=1 (100) and Σ=1 (110) structural units. All the proposed boundary models show continuity of grain boundary structure over the entire misorientation range. The Σ=17 (410) structural unit is asymmetric which induces microfacetting on all boundaries less than the Σ=5, 36.87° misorientation.
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Work Supported by the U.S. Department of Energy under contract DE-Ac05-84OR21400.
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Browning, N.D., Pennycook, S.J., Chisholm, M.F. et al. Observation of structural units at symmetric [001] tilt boundaries in SrTiO3 . Interface Sci 2, 397–423 (1995). https://doi.org/10.1007/BF00222626
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DOI: https://doi.org/10.1007/BF00222626