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The effects of pH, redox, and salinity on metal release from a contaminated sediment

  • Part II Environmental Chemistry and Cycling of Metals
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Abstract

A laboratory study was conducted with a brackish marsh sediment contaminated by several trace and toxic metals to determine the effect of a range of pH, redox potential, and salinity conditions on the release of metals to the soluble phase. The purpose of the study was to provide information on factors affecting the mobilization/immobilization of metal contaminants under conditions of various possible remediation alternatives. Substantial amounts of Cd and Zn were released under moderately acid, oxidizing conditions. Under the present slightly basic, strongly anaerobic environment of the marsh sediment, the metals are being effectively immobilized compared to the release that would occur for some of the metals if the sediments were excavated and placed under upland conditions where they would eventually become oxidized and strongly acidic.

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References

  • Connell, W.E. and Patrick, W.H., Jr.: 1968, Science 159,86.

    Google Scholar 

  • Fuller, W.H. and Warrick, A.W.: 1985, Soils in Waste Treatment and Utilization. Volume I. CRC Press, Inc., Boca Raton. Florida 268 p.

    Google Scholar 

  • Gambrell, R.P., Collard, V., and Patrick, W.H. Jr.: 1980a, Cadmium Uptake by Marsh Plants as Affected by Sediment Physicochemical Conditions. In R.A. Baker (ed.) Contaminants and Sediments, Volume 2: Analysis, Chemistry, Biology. Ann Arbor Science, Ann Arbor, Michigan. pp. 425–444.

    Google Scholar 

  • Gambrell, R.P., Khalid, R.A., and Patrick, W.H., Jr.: 1980b, Environmental Science and Technology 14,431.

    Google Scholar 

  • Gambrell, R.P., Khalid, R.A., Verloo, M.G., and Patrick, W.H., Jr.: 1977, Transformations of Heavy Metals and Plant Nutrients in Dredged Sediments as Affected by Oxidation-Reduction Potential and pH: Part II. Materials and Methods, Results and Discussion. Contract Report D-77-4. U.S. Army Engineer Waterways Experiment Station, Vicksburg, Mississippi. 315 p.

    Google Scholar 

  • Gambrell, R.P., Landes, S.L., Reddy, C.N., and W.H. Patrick, Jr.: 1983, Soil Physicochemical Parameters Regulating Chemical and Biological Availability of Trace and Toxic Metals in Sludge-Amended Soils. Project Completion Report for Research Grant No. R 805789-01, Municipal Environmental Research Laboratory, U.S. Environmental Protection Agency, Cincinnati, Ohio, 100 p.

    Google Scholar 

  • Gambrell, R.P. and Patrick, W.H., Jr.: 1989, Cu, Zn, and Cd Availability in a Sludge-Amended Soil under Controlled pH and Redox Potential Conditions. (in) Ecological Studies 74: Inorganic Contaminants in the Vadose Zone. B. Bar-Yosef, N.J. Barrow, and J. Goldshmid, eds. Springer-Verlag, Berlin. pp 89–106.

    Google Scholar 

  • Harter, R.D. and McLean, E.O.: 1965, Agronomy J. 57,583.

    Google Scholar 

  • Khalid, R.A., Gambrell, R.P., and Patrick, W.H., Jr.: 1981, J. Environmental Quality 10,523.

    Google Scholar 

  • McKeague, J.A. and Day, J.H.: 1966, Canadian J. Soil Science 46,13.

    Google Scholar 

  • Nelson, D.W. and Sommers, L.E.: 1982, Total Carbon, Organic Carbon, and organic Matter. (in) Methods of Soil Analysis, Part 2, Chemical and Microbiological Properties, 2nd Edition. A.L. Page ed. American Society of Agronomy, Madison, Wisconsin.

    Google Scholar 

  • Nriagu, J.O. and Soon, Y.K.: 1985, Geochim Cosmochim Acta 49,823.

    Google Scholar 

  • Peters, D.B.: 1965, Water Availability, (in) Methods of Soil Analysis, Part 1, Physical Analyses. C.A. Black, ed. American Society of Agronomy, Madison, Wisconsin.

    Google Scholar 

  • Plumb, R.H. 1981, Procedure for Sediment Samples/ Metals/ Inorganic Analysis/ Analytical Methods. (in) Procedures for Handling and Chemical Analysis of Sediment and Water Samples. Technical Report EPA/CE-81-1, published by U.S. Army Engineer Waterways Experiment Station, Vicksburg, MS.

    Google Scholar 

  • Rhoades, J.D.: 1982, Cation Exchange Capacity. (in) A.L. Page, R.H. Miller, and D.R. Keeney (eds.) Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties, 2nd Edition. American Society of Agronomy, Madison, Wisconsin.

    Google Scholar 

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Authors and Affiliations

  1. Laboratory for Wetland Soils and Sediments, LA State University, 70803, Baton Rouge, LA, USA

    R. P. Gambrell, W. H. Patrick Jr. & M. C. Duff

  2. Air Toxics Lab, LA Dept. of Environmental Quality, 11720 Airline Highway, 70817, Baton Rouge, LA, USA

    J. B. Wiesepape

Authors
  1. R. P. Gambrell
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  2. J. B. Wiesepape
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  3. W. H. Patrick Jr.
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  4. M. C. Duff
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Gambrell, R.P., Wiesepape, J.B., Patrick, W.H. et al. The effects of pH, redox, and salinity on metal release from a contaminated sediment. Water Air Soil Pollut 57, 359–367 (1991). https://doi.org/10.1007/BF00282899

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  • DOI: https://doi.org/10.1007/BF00282899

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