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Indication of an order-order-transition by a partial disordering in ABC-triblock copolymers

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Summary

Poly(ethylene-alt-propylene)-block-polyethylethylene-block-polystyrene (PEP-b-PEE-b-PS) triblock copolymers were synthesized by anionic polymerization and subsequent hydrogenation of poly-1,4-isoprene-block-poly-1,2-butadiene-block-polystyrene triblock copolymers (1,4PI-b-1,2PB-b-PS). Differential scanning calorimetry and dynamic mechanical spectroscopy reveal an order-order transition which is induced by the mixing of PEP and PEE above their respective order-disorder transition (ODT).

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Authors and Affiliations

  1. Institut für Organische Chemie, Johannes-Gutenberg-Universität Mainz, Postfach 3980, D-55099, Mainz, Germany

    Claudius Neumann, Volker Abetz & Reimund Stadler

Authors
  1. Claudius Neumann
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  2. Volker Abetz
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  3. Reimund Stadler
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Dedicated to Prof. W. Borchard on the occasion of his 60th birthday

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Neumann, C., Abetz, V. & Stadler, R. Indication of an order-order-transition by a partial disordering in ABC-triblock copolymers. Polymer Bulletin 36, 43–50 (1996). https://doi.org/10.1007/BF00296006

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  • DOI: https://doi.org/10.1007/BF00296006

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