Abstract
From the ethyl-cyanoethyl cellulose (E-CE)C/acrylic acid (AA) solution, the (E-CE)C/PAA composite can be prepared by polymerizing the AA with ultraviolet initiation. The (E-CE)C/PAA composite prepared from the cholesteric liquid crystalline solution shows the lamellar structure with a periodicity ranging from 400 to 600 nm. In the lamellation there is no preferential orientation direction for polymer chains. The PAA is dispersed between the lamellea with small strip-like domains and the PAA and (E-CE)C have been homogeneously mixed in the system.
Similar content being viewed by others
References
E. L. Thomas, The Structure of Crystalline Polymers, ed.I.,Hall (Applied Science Publishers, Essex), 1984.
E. L. Thomas and B. A. Wood, Faraday Discuss. Chem. Soc., 79, paper 15(1985).
T. Tsutsui and T. Tanaka, J. Polym. Sci., Polym. Phys. Ed., 15, 475(1977).
T. Tsutsui and R. Tanaka, Polymer, 22, 117(1981).
Y. Nishio, T. Yamane and T. Takahashi, J. Polym. Sci., Polym. Phys. Ed., 23, 1043(1985).
S. J. Kozakiewcz and J. E. Maginess, J. Appl. Polym. Sci., 34, 1109(1987).
Y. Huang, Ch. J. Polym. Sci., 7, 340(1989).
D. G. Gray, Appl. Polym. Symp., 37, 179(1983).
Y. Huang, M. C. Chen and L. S. Li, Acta Chimica Sinica(Ch), 46, 367(1988).
S. H. Jiang, B. K. Wu, H. L. Wang and Y. Huang, The 3rd National Symposium on LCPs (Jinan, China), April 20–23, 1991, P90.
J. Giasson, J. F. Revol, A. M. Ritcey and D. G. Gray, Biopolymers, 27, 1999(1988).
S. X. Chen, Y. Z. Jin, S. R. Hua and M. Xu, Polym. Commun., 28, 208(1987).
Y. Huang, J. Macromol. Sci. Phys., B28, 131(1989).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Huang, Y., Jiang, S.H. TEM observation of (E-CE)/PAA composite polymerized by ultraviolet initiation. Polymer Bulletin 27, 535–542 (1992). https://doi.org/10.1007/BF00300601
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00300601