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Studies on the alkali extract from beech holocellulose

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Summary

The alkali extract (5% KOH) from beech holocellulose was fractionated by ion exchange chromatography, resulting in several fractions containing different amounts of polyoses and lignin. The separated polyoses varied to some extent in the ratios of their sugar components. Three different 4-0-methylglucurono-xylans and three arabinogalactans were isolated. There was a direct relationship between the chemical composition and the ultrastructure of the fractions. Those containing a pure 4-0-methylglucurono-xylan showed bundles of thin and stiff fibrils while in fractions with a high percentage of lignin coiled fibrils and globular particles could be observed in the electron microscope.

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References

  • Aspinall, G. O., Hirst, H. L., Mahomed, R. S. 1954. Hemicellulose A of beechwood (Fagus sylvatica). J. Chem. Soc. 1954; 1734–1738

    Google Scholar 

  • Corbett, W. M., Ewart, J. A. D. 1959. Separation of xylan from beech holocellulose. Svensk Papperstid. 62: 277–283

    Google Scholar 

  • Fengel, D. 1967. Untersuchungen zur übermolekularen Struktur der Zellwandbestandteile. Teil 1: Alkalilösliche Polysaccharide. Svensk Papperstid. 70: 70–77

    Google Scholar 

  • Fengel, D. 1976a. Fraktionierungsversuche am Alkali-Extrakt aus Fichtenholocellulose. Teil 1. Elektrophorese, Gelchromatographie und Ionenaustauschchromatographie. Holzforschung 30: 73–78

    Google Scholar 

  • Fengel, D. 1976 b. Fraktionierungsversuche am Alkali-Extrakt aus Fichtenholocellulose. Teil 2. Optimierung der ionenaustauschromatographischen Trennung. Holzforschung 30: 143–148

    Google Scholar 

  • Fengel, D. 1976 c. Chemische und elektronenmikroskopische Untersuchungen an schonend isoliertem Nadelholzlignin. Holzforschung 30: 1–6

    Google Scholar 

  • Fengel, D., Przyklenk, M. 1975a. Studies on the supermolecular structure of cell wall components. Part 3. Fractionation of alkali extract from spruce holocellulose by ion exchange chromatography: Methods and first results. Svensk Papperstid. 78: 17–21

    Google Scholar 

  • Fengel, D., Przyklenk, M. 1975b. Studies on the supermolecular structure of cell wall components. Part 4. Composition of the fractions from ion exchange chromatography. Svensk Papperstid. 78: 617–620

    Google Scholar 

  • Fengel, D., Przyklenk, M., Wegener, G. 1976. Hydrolyse von Polysacchariden mit Trifluoressigsäure. Papier 30: 240–243

    Google Scholar 

  • Kirillova, V. V., Beinart, I. I. 1974. Uniformity of the structure of the macromolecules of birch glucuronoxylan (russ.). Khim. Drev. No. 15: 27–31

  • Kuo, C. M., Timell, T. E. 1969. Isolation and characterization of a galactn from tension wood of American beech (Fagus grandifolia Ehrl.). Svensk Papperstid. 72: 703–716

    Google Scholar 

  • Kürschner, K., Karácsonyi, S. 1961. Zur Isolierung von Hemicellulosen aus Buchenholz (Fagus sylvatica L.) und aus Buchenholz-Holocellulose. Holzforschung 15: 107–114

    Google Scholar 

  • McDonald, I. R. C. 1952. The chemistry of the wood cell wall. Part III. The isolation of beech hemicellulose A. J. Chem. Soc. 1952: 3183–3186

    Google Scholar 

  • Rak, J. 1966. Morfologické stúdium tvorby med'natého komplexu s polysacharidmi bukových hemicelulóz rozpustnými vo vode. Chem. Zvesti 20: 373–380

    Google Scholar 

  • Timell, T. E. 1960. Isolation of hardwood glucomannans. Svensk Papperstid. 63: 472–476

    Google Scholar 

  • Treiber, E., Toplak, H., Ruck, M. u. H. 1955. Physikalisch-chemische Untersuchungen an einigen Hemicellulosen. Ein Beitrag zur Kenntnis des übermolekularen Aufbaus von Holzpolyosen. Holzforschung 9: 49–59

    Google Scholar 

  • Uçar, H. 1976. Einfluß der Delignifizierung auf die Bestandteile des Buchenholzes. Dissertation (in preparation)

  • Waldmann, E., Prey, V., Krandalsky, W. 1954. Probleme der Hemicellulosen-Forschung. Papier 8: 84–89

    Google Scholar 

  • Wegener, G. 1975. Beitrag zur Charakterisierung der Natriumchlorit-Delignifizierung von Fichtenholz. Dissertation, Universität München

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Submitted by Arbeitsgemeinschaft Industrieller Forschungsvereinigungen (AIF) via Deutsche Gesellschaft für Holzforschung. The conscientious preparation of the electron microscopic specimens by Miss U. Schwarz is appreciated.

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Fengel, D., Przyklenk, M. Studies on the alkali extract from beech holocellulose. Wood Science and Technology 10, 311–320 (1976). https://doi.org/10.1007/BF00350834

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  • DOI: https://doi.org/10.1007/BF00350834

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