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Electrical conductivity and ESR of lithium borate glasses containing mixed transition metal oxides

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Abstract

Electron spin resonance, optical spectra and d.c. electrical conductivity of 2Li2O · 3B2O3 glasses doped with V2O5 and CuO were investigated. Spin Hamiltonian parameters of transition metal (TM) ions have been determined. The theoretical optical basicity Λth of these glasses has been calculated and related to the spin-Hamiltonian parameters of TM ions. The variation of electrical conductivity with composition has been explained.

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References

  1. M. Sayer and A. Mansingh, Phys. Rev. B6 (1972) 4629.

    Google Scholar 

  2. L. D. Bogomolova, T. F. Dolgolenko, V. N. Lazukin and I. V. Filatova, Sov. Phys. Solid State 15 (1974) 2477.

    Google Scholar 

  3. M. Sayer and G. F. Lynch, J. Phys. C: Solid State Phys. 6 (1973) 3674.

    Google Scholar 

  4. L. D. Bogomolova, M. P. Glassova and V. A. Shmueler, Phys. Khim. Stec. 5 (1979) 26.

    Google Scholar 

  5. W. Chomka, D. Samtowicz, O. Gzowski and I. Murawski, J. Non-Cryst. Solids 45 (1981) 145.

    Google Scholar 

  6. A. K. Bandyopadhyay and J. O. Isard, J. Phys. D: Appl. Phys. 10 (1977) L99.

    Google Scholar 

  7. L. D. Bogomolova, M. P. Glassova, V. M. Kalygina, S. I. Reiman, S. N. Spasibkina and I. V. Filatova, J. Non-Cryst. Solids 85 (1986) 170.

    Google Scholar 

  8. L. D. Bogomolova and M. P. Glassova, ibid. 37 (1980) 432.

    Google Scholar 

  9. R. Singh, J. Phys. D: Appl. Phys. 17 (1984) L57.

    Google Scholar 

  10. Ravishankar Harani and C. A. Hogarth, J. Mater. Sci. 21 (1986) 3509.

    Google Scholar 

  11. K. Singh and S. Rokade, J. Power Sources 13 (1984) 151.

    Google Scholar 

  12. V. P. Seth, A. Yadav and R. S. Bansal, Phys. Status Solidi (b) 132 (1985) 255.

    Google Scholar 

  13. Idem, ibid. 133 (1986) 297.

    Google Scholar 

  14. V. P. Seth, V. K. Jain and R. K. Malhotra, J. Non-Cryst. Solids 57 (1983) 199.

    Google Scholar 

  15. A. Abragam and B. Bleaney, “Electron Paramagnetic Resonance of Transition Ions” (Clarendon, Oxford, 1970) p. 175.

    Google Scholar 

  16. D. Kivelson and S. K. Lee, J. Chem. Phys. 41 (1964) 1896.

    Google Scholar 

  17. A. K. Bandyopadhyay, J. Mater. Sci. 16 (1981) 189.

    Google Scholar 

  18. V. P. Seth and A. Yadav, Phys. Chem. Glasses 28 (1987) 109.

    Google Scholar 

  19. H. G. Hecht, ibid. 9 (1968) 179.

    Google Scholar 

  20. A. Klonkowski, ibid. 26 (1985) 11.

    Google Scholar 

  21. H. Imagawa, Phys. Status Solidi (b) 30 (1968) 469.

    Google Scholar 

  22. H. Hosono, H. Kawazoe and T. Kanazawa, J. Non-Cryst. Solids 33 (1979) 103.

    Google Scholar 

  23. J. A. Duffy and M. D. Ingram, J. Inorg. Nucl. Chem. 37 (1975) 1203.

    Google Scholar 

  24. L. Pauling, “The Nature of the Chemical Bond”, 3rd Edn (Cornell University Press, New York, 1960) p. 93.

    Google Scholar 

  25. H. Hosono, H. Kawazoe and T. Kanazawa, J. Non-Cryst. Solids 33 (1979) 125.

    Google Scholar 

  26. H. Xihuai and L. Zhi Shanghai, in Proceedings of 14th Congress on Glass (1986).

  27. E. E. Khawaja, M. A. Khan, M. N. Khan, A. S. W. Li and J. S. Hwang, J. Mater. Sci. Lett. 3 (1984) 593.

    Google Scholar 

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Authors and Affiliations

  1. Physics Department, M.D. University, Rohtak, Haryana, India

    V. P. Seth & A. Yadav

  2. EPR Section, Materials Characterization Division, National Physical Laboratory, Dr K.S. Krishnan Road, 110 012, New Delhi, India

    S. K. Gupta

Authors
  1. V. P. Seth
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  2. A. Yadav
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  3. S. K. Gupta
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Seth, V.P., Yadav, A. & Gupta, S.K. Electrical conductivity and ESR of lithium borate glasses containing mixed transition metal oxides. J Mater Sci 23, 3495–3500 (1988). https://doi.org/10.1007/BF00540485

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  • DOI: https://doi.org/10.1007/BF00540485

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