Abstract
The cold-drawing of high density polyethylene has been studied over a wide range of temperatures and strain rates for a series of samples of very different molecular weight distribution. A natural draw-ratio was observed which was almost independent of temperature and strain rate, but was sensitive to the weight average molecular weight. A good correlation was observed between the Young's modulus of the drawn mono-filaments and the natural draw-ratio, and it is proposed that the Young's modulus is primarily related to molecular orientation rather than to interlamellar ties.
Similar content being viewed by others
References
S. W. Allison and I. M. Ward, Brit. J. Appl. Phys. 18 (1967) 1151.
R. Corneliussen and A. Peterlin, Makromol. Chemie 105 (1967) 193.
A. Peterlin, Polymer Eng. Sci. 9 (1969) 172.
P. R. Pinnock and I. M. Ward, Trans. Faraday Soc. 62 (1966) 1308.
V. B. Gupta and I. M. Ward, J. Macromol. Sci. (Phys.) B(i)2 (1967) 373.
D. W. Hadley, P. R. Pinnock, and I. M. Ward, J. Mater. Sci. 4 (1969) 152.
H. Determann, “Gel Chromatography” (Springer-Verlag, Berlin, 1968).
L. E. Maley, J. Polymer Sci. C 8 (1965) 253.
F. C. Frank, I. M. Ward, and T. Williams, ibid A-2 6 (1968) 1357.
I. M. Ward and T. Williams, Polymer Lett. 6 (1968) 621.
D. W. Robinson, J. Sci. Instr. 32 (1955) 2.
I. Marshall and A. B. Thompson, Proc. Roy. Soc. A221 (1954) 541.
R. D. Andrewsand W. Whitney, Textile Division, Department of Mech. Eng., Massachusetts Inst. of Tech. Report No. TD-123-64.
P. I. Vincent, Polymer 1 (1960) 7.
H. E. Bair and R. Salovey, J. Macromol. Sci. (Phys.) B3(i) (1969) 3.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Andrews, J.M., Ward, I.M. The cold-drawing of high density polyethylene. J Mater Sci 5, 411–417 (1970). https://doi.org/10.1007/BF00550003
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00550003