Abstract
The hydrostatic extrusion behaviour of two grades of polymethylmethacrylate (PMMA) is reported and an analysis of the mechanics of the extrusion process is presented. Although the maximum degree of deformation achieved is considerably lower than that obtained for crystalline polymers, the process mechanics are controlled by the same factors (i.e. the billet-die friction, and the effects of strain rate and pressure on the material flow stress). A method for equating the effects of pressure and friction is described, following the work of Tabor on the adhesive mechanism of friction in polymers. This method gives a friction coefficient in the range 0.1 to 0.2 for the hydrostatic extrusion of PMMA, compared to values in the region 0.03 to 0.08 for crystalline polymers, suggesting conditions of boundary lubrication. The relatively high values of friction for PMMA are consistent with the requirement for careful preparation of the billet surface prior to extrusion, and the observation of the ″stick-slip″ phenomenon during extrusion. The differences between the grades of PMMA in both extrusion behaviour and tensile drawing behaviour are explicable in terms of their different glass transition temperatures.
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References
A. Buckley andH. A. Long,Polymer. Eng. Sci. 9 (1969) 115.
K. Imada, T. Yamamoto, K. Shigematsu andM. Takayanagi,J. Mater. Sci. 6 (1971) 537.
T. Williams,ibid. 8 (1973) 59.
A. G. Gibson, I. M. Ward, B. N. Cole andB. Parsons,ibid. 9 (1974) 1193.
A. G. Kolbeck andD. R. Uhlmann,J. Polymer Sci. Polymer Phys. Ed. 15 (1977) 27.
A. G. Gibson andI. M. Ward,ibid. 16 (1978) 2015.
P. D. Coates andI. M. Ward,ibid. 16 (1978) 2031.
P. S. Hope, A. G. Gibson, B. Parsons andI. M. Ward,Polymer Eng. Sci. in press.
P. S. Hope andB. Parsons,ibid. in press.
P. S. Hope, A. G. Gibson andI. M. Ward,J. Polymer Sci., Polymer Phys. Ed. in press.
S. Abdul Jawad andI. M. Ward,J. Mater. Sci. 13 (1978) 1381.
A. G. Gibson, D. Greig, M. Sahota, I. M. Ward andC. L. Choy,J. Polymer Sci. Polymer Lett. Ed. 15 (1977) 183.
J. M. Alexander andP. J. H. Wormell,Ann. C.I.R.P. 19 (1971) 21.
K. D. Pye, S. K. Bhatega andJ. A. Sauer, Proceedings of the NEL/AIRAPT International Conference on Hydrostatic Extrusion (NEL, Glasgow, 1973).
N. Kahar, R. A. Duckett andI. M. Ward,Polymer 19 (1978) 136.
P. S. Hope, A. G. Gibson andI. M. Ward, unpublished work.
O. Hoffman andG. Sachs, ″Introduction to the Theory of Plasticity for Engineers″ (McGraw-Hill, New York, 1953).
B. Avitzur, ″Metal Forming: Processes and Analysis″ (McGraw-Hill, New York, 1968).
S. Maryama, K. Imada andM. Takayanagi,International J. Polymeric Mater. 1 (1972) 211.
Idem, ibid. 2 (1973) 105.
Idem, ibid. 2 (1973) 125.
A. G. Gibson, P. D. Coates andI. M. Ward, ″Science and Technology of Polymer Processing″ Edited by N. P. Suh and N. H. Sung, (M.I.T. Press, Massachusetts 1979).
P. D. Coates, A. G. Gibson andI. M. Ward,J. Mater. Sci. 15 (1980) 359.
P. S. Hope, R. A. Duckett andI. M. Ward,J. Appl. Polymer Sci., in press.
H. Li. D. Pugh, ″Mechanical Behaviour of Materials under Pressure″, (Elsevier, Amsterdam, 1970).
J. S. Harris, I. M. Ward andJ. S. C. Parry,J. Mater. Sci. 6 (1971) 110.
P. D. Coates andI. M. Ward,J. Mater. Sci. 13 (1978) 1957.
P. I. Vincent,Polymer 1 (1967) 7.
A. S. Argon, in ″The Inhomogeneity of Plastic Deformation″, (A.S.M. Metals Park Ohio, 1973) ch. 7.
C. Bauwens-Crowet,J. Mater. Sci. 8 (1973) 968.
R. N. Haward andG. Thackray,Proc. Roy. Soc. A302 (1968) 453.
I. M. Ward,J. Mater. Sci. 6 (1971) 1397.
L. A. Davis andC. A. Pampillo,J. Appl. Phys. 42 (1971) 4659.
S. Rabinowitz, I. M. Ward andJ. S. C. Parry,J. Mater. Sci. 5 (1970) 29.
″Handbook of Chemistry and Physics″ Edited by R. C. Weast (Chemical Rubber Publishing Co., Cleveland, 1973).
Manufacturers data.
B. J. Briscoe andD. Tabor, in ″Polymer Surfaces″ Edited by D. T. Clark and W. J. Feast (Wiley-Interscience, New York, 1978) ch. 1.
Idem, J. Adhesion 9 (1978) 145.
B. J. Briscoe, private communication.
P. B. Bowden andJ. A. Jukes,J. Mater. Sci. 3 (1968) 183.
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Hope, P.S., Ward, I.M. & Gibson, A.G. The hydrostatic extrusion of polymethylmethacrylate. J Mater Sci 15, 2207–2220 (1980). https://doi.org/10.1007/BF00552308
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DOI: https://doi.org/10.1007/BF00552308