Skip to main content
Log in

Reaction behaviour of monomeric β-ketoesters

2. Synthesis, characterization and polymerization of methacrylate group containing enamines

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Polymerizable enamines were synthesized by the reaction of 2-acetoacetoxyethyl methacrylate (AAEMA) with various aliphatic mono- and diamines. The enamines were characterized by elemental analyses, IR,1H NMR and13C NMR spectroscopy. Radical polymerization of synthesized enamines yielded polymers with pendant enamine groups which were also prepared by the reaction of poly(AAEMA) with the corresponding amines.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P.W. Hickmott, Tetrahedron38 (1982) 1975, 3363.

    Article  Google Scholar 

  2. A.G. Cook, Eamines, 2.Ed., M. Dekker, New York-Basel 1988.

    Google Scholar 

  3. R. Willstätter, M. Bonner, Liebigs Ann. Chem.422 (1921) 512.

    Google Scholar 

  4. G.R. Allen, Org. React.20 (1973) 337.

    Google Scholar 

  5. H. Hanecka, Chemie der Beta-Dicarbonyl-Verbindungen, Springer-Verlag, Berlin-Heidelberg-Göttingen 1950, 189

    Google Scholar 

  6. G.O. Dudeck, R.H. Holm, J. Amer. Chem. Soc.84 (1962) 2691

    Google Scholar 

  7. F.D. Rector, W.W. Blount, D.R. Leonard, Proceedings of the Fifteenth Water-Borne and Higher-Solids Coatings Symposium (1988) 68.

  8. A. Noomen, Progr. Org. Coatings17 (1989) 27

    Google Scholar 

  9. R.J. Clemens, J.S. Witzman, F.D. Rector, submitted for publication.

  10. N. Moszner, M. Hartmann, P. Zalusky, D. Vegh and J. Kovac: J. Macromol. Sci.-Chem.A-27 (1990) 59.

    Google Scholar 

  11. G.O. Dudek and R.H. Holm, J. Amer. Chem. Soc.83 (1961) 2099

    Google Scholar 

  12. G.O. Dudek and R.H. Holm, J. Amer. Chem. Soc.84 (1962) 2691

    Google Scholar 

  13. E. Pretsch, J. Seibel, W. Simon and T. Clerc, Spectral Data for Structure Determination of Organic Compounds, 2. Ed., Springer-Verlag, Berlin-Heidelberg-New York 1989.

    Google Scholar 

  14. J.K.M. Sanders, B.K. Hunter: Modern NMR spectroscopy, Oxford University Press, Oxford/New York/Toronto 1989, 252

    Google Scholar 

  15. M. Labelle, D. Gravel, Can. J. Chem.63 (1985) 1884.

    Google Scholar 

  16. B. Witkop, J. Amer. Chem. Soc.78 (1956) 873.

    Google Scholar 

  17. A.E. Martell, R.L. Belford, M. Calvin, J. Inorg. Nucl. Chem.5 (1958) 170.

    Google Scholar 

  18. P. Remp, E. Meril, Polymersynthesis, Hüthing & Wepf Verlag, Basel/New York 1986, 76.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Moszner, N., Salz, U. & Rheinberger, V. Reaction behaviour of monomeric β-ketoesters. Polymer Bulletin 32, 419–426 (1994). https://doi.org/10.1007/BF00587883

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00587883

Keywords

Navigation