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Basic mechanisms in laser etching and deposition

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Abstract

Laser-induced chemical processing of solid surfaces has the potential for being an important and powerful technique for fabrication of a variety of devices. Successful applications rest on a detailed understanding of the nature of laser-induced reactions and their effects on the properties of materials. In this paper fundamental studies illustrating key features of laser etching and deposition are reviewed. Topics covered include the effect of the choice of precursor and deposition conditions on film composition and morphology, self-propagation of exothermic reactions, thermal and electronic effects in laser-assisted etching of semiconductors, metals and polymers, and special aspects of laser-surface photophysics as they may affect chemical reactions.

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References

  1. B.M. McWilliams, I.P. Herman, F. Mitlitsky, R.A. Hyde, L.L. Wood: Appl. Phys. Lett.43, 946 (1983)

    Google Scholar 

  2. D.J. Ehrlich, J.Y. Tsao: Appl. Phys. Lett.46, 198 (1985)

    Google Scholar 

  3. R.M. Osgood, Jr: Ann. Rev. Phys. Chem.34, 77 (1983)

    Google Scholar 

  4. D.J. Ehrlich, J.Y. Tsao: J. Vac. Sci. Technol. B1, 969 (1983)

    Google Scholar 

  5. T.J. Chuang: Mat. Res. Soc. Symp. Proc.17, 45 (1983)

    Google Scholar 

  6. Y. Rytz-Froidevaux, R.P. Salathe, H.H. Gilgen: Appl. Phys. A37, 121 (1985)

    Google Scholar 

  7. R.M. Osgood, Jr., H.H. Gilgen: An. Rev. Mater. Sci.15, 549 (1985)

    Google Scholar 

  8. D.J. Ehrlich: Sol. State Technol. 81 (December 1985)

  9. H. Gerischer: “Photovoltaic and Photoelectrochemical Solar Energy Conversion” in F. Cardon, W.P. Gomes, and W. Dekeyser (eds.): Nato Adv. Study Inst. Ser. B69, 199–261 (1981)

  10. S.R. Morrison:The Chemical Physics of Surfaces (Plenum, New York 1977)

    Google Scholar 

  11. F. Kuhn-Kuhnenfeld: J. Electrochem. Soc.119, 1063 (1972)

    Google Scholar 

  12. B. Zysset, R.P. Salathe: Appl. Phys. Lett.45, 428 (1984)

    Google Scholar 

  13. F.W. Ostermayer, Jr., P.A. Kohl: Appl. Phys. Lett.39, 76 (1981)

    Google Scholar 

  14. D.V. Podlesnik, H.H. Gilgen, R.M. Osgood, Jr.: Appl. Phys. Lett.45, 563 (1984)

    Google Scholar 

  15. V.A. Tyagai, V.A. Sterligov, G.Ya. Kolbasov: Electrochim. Acta22, 819 (1977)

    Google Scholar 

  16. R.M. Lum, A.M. Glass, F.W. Ostermayer, Jr., P.A. Kohl, A.A. Ballman, R.A. Logan: J. Appl. Phys.57, 39 (1985)

    Google Scholar 

  17. R.M. Lum, F.W. Ostermayer, Jr., P.A. Kohl, A.M. Glass, A.A. Ballman: Appl. Phys. Lett.47, 269 (1985)

    Google Scholar 

  18. F.W. Ostermayer, Jr., P.A. Kohl, R.M. Lum: J. Appl. Phys.58, 4390 (1985)

    Google Scholar 

  19. F.W. Ostermayer, Jr., P.A. Kohl, R.H. Burton: Appl. Phys. Lett.43, 642 (1983)

    Google Scholar 

  20. D.V. Podlesnik, H.H. Gilgen, R.M. Osgood, Jr., A. Sanchez: Appl. Phys. Lett.43, 1083 (1983)

    Google Scholar 

  21. J.E. Bjorkholm, A.A. Ballman: Appl. Phys. Lett.43, 574 (1983)

    Google Scholar 

  22. F.A. Houle: Chem. Phys. Lett.95, 5 (1983)

    Google Scholar 

  23. F.A. Houle: J. Chem. Phys.79, 4237 (1983)

    Google Scholar 

  24. F.A. Houle: J. Chem. Phys.80, 4851 (1984)

    Google Scholar 

  25. H. Okano, Y. Horiike, M. Sekine: Jpn. J. Appl. Phys.24, 68 (1985)

    Google Scholar 

  26. M. Hirose, S. Yokoyama, Y. Yamakage: J. Vac. Sci. Technol. B3, 1445 (1985)

    Google Scholar 

  27. S.P. Kowalczyk, D.L. Miller: J. Appl. Phys.59, 287 (1986)

    Google Scholar 

  28. C.I.H. Ashby: Appl. Phys. Lett.45, 892 (1984)

    Google Scholar 

  29. C.I.H. Ashby: Appl. Phys. Lett.46, 752 (1985)

    Google Scholar 

  30. C.I.H. Ashby, R.M. Biefeld: Appl. Phys. Lett.47, 62 (1985)

    Google Scholar 

  31. T.J. Chuang: J. Chem. Phys.74, 1461 (1981)

    Google Scholar 

  32. T.J. Chuang: J. Chem. Phys.74, 1453 (1981)

    Google Scholar 

  33. H.F. Winters, J.W. Coburn: Appl. Phys. Lett.34, 70 (1979)

    Google Scholar 

  34. P.A. Schultz, A.S. Sudbo, D.J. Krajnovitch, H.S. Kwok, Y.R. Shen, Y.T. Lee: Ann. Rev. Phys. Chem.30, 379 (1979)

    Google Scholar 

  35. T.J. Chuang: J. Vac. Sci. Technol. B3, 1408 (1985)

    Google Scholar 

  36. G.P. Davis, C.A. Moore, R.A. Gottscho: J. Appl. Phys.56, 1808 (1984)

    Google Scholar 

  37. R.B. Hall, A.M. De Santolo: Surf. Sci.137, 421 (1984)

    Google Scholar 

  38. R.B. Hall: J. Phys. Chem. (to be published)

  39. W. Sesselman, T.J. Chuang: J. Vac. Sci. Technol. B3, 1507 (1985)

    Google Scholar 

  40. G. Koren, F. Ho, J.J. Ritsko: Appl. Phys. Lett.46, 1006 (1985)

    Google Scholar 

  41. R. Srinivasan: J. Vac. Sci. Technol. B1, 923 (1983)

    Google Scholar 

  42. G. Koren, J.T.C. Yeh: Appl. Phys. Lett.44, 1112 (1984)

    Google Scholar 

  43. M.W. Geis, J.N. Randall, T.F. Deutsch, P.D. DeGraff, K.E. Krohn, L.A. Stern: Appl. Phys. Lett.43, 74 (1983)

    Google Scholar 

  44. J.H. Brannon, J.R. Lankard, A.I. Baise, F. Burns, J. Kaufman: J. Appl. Phys.58, 2036 (1985)

    Google Scholar 

  45. B.J. Garrison, R. Srinivasan: J. Appl. Phys.57, 2909 (1985)

    Google Scholar 

  46. P.E. Dyer, R. Srinivasan: Appl. Phys. Lett.48, 445 (1986)

    Google Scholar 

  47. R. Solanki, W.H. Ritchie, G.J. Collins: Appl. Phys. Lett.43, 454 (1983)

    Google Scholar 

  48. G.S. Higashi, L.J. Rothberg: Appl. Phys. Lett.47, 1288 (1985)

    Google Scholar 

  49. Y. Rytz-Froidevaux, R.P. Salathe, H. Gilgen: Phys. Lett.84A, 216 (1981)

    Google Scholar 

  50. D.B. Geohegan, J.G. Eden: Appl. Phys. Lett.45, 1146 (1984)

    Google Scholar 

  51. T.H. Baum, C.R. Jones: J. Vac. Sci. Technol. B (1986)

  52. T.H. Baum, E. Marinero, C.R. Jones: Appl. Phys. Lett. (1986)

  53. M.E. Gross, G.J. Fisanick, P.K. Gallagher, K.J. Schnoes, M.D. Fennell: Appl. Phys. Lett.47, 923 (1985)

    Google Scholar 

  54. D.J. Ehrlich, R.M. Osgood, Jr., T.F. Deutsch: J. Vac. Sci. Technol.21, 23 (1982)

    Google Scholar 

  55. P.K. Boyer, C.A. Moore, R. Solanki, W.K. Ritchie, G.A. Roche, G.J. Collins: Mat. Res. Soc. Symp. Proc.17, 119 (1983)

    Google Scholar 

  56. H. Yokoyama, F. Uesugi, S. Kishida, K. Washio: Appl. Phys. A37, 25 (1985)

    Google Scholar 

  57. H. Yokoyama, S. Kishida, K. Washio: Appl. Phys. Lett.44, 755 (1984)

    Google Scholar 

  58. S.M. Shin, C.W. Draper, M.E. Mochel, J.M. Rigsbee: Mat. Lett.3, 265 (1985)

    Google Scholar 

  59. C. Arnone, M. Rothschild, J.G. Black, D.J. Ehrlich: Appl. Phys. Lett.48, 1018 (1986)

    Google Scholar 

  60. F.A. Houle, R.J. Wilson, T.H. Baum: J. Vac. Sci. Technol. A (1986)

  61. F.A. Houle, C.R. Jones, T.H. Baum, C. Pico, CA. Kovac: Appl. Phys. Lett.46, 204 (1985)

    Google Scholar 

  62. P.J. Love, R.T. Loda, P.R. La Roe, A.K. Green, V. Rehn: Mat. Res. Soc. Symp. Proc.29, 101 (1984)

    Google Scholar 

  63. J.S. Foord, R.B. Jackman: Chem. Phys. Lett.112, 190 (1984)

    Google Scholar 

  64. H. Beneking: InLaser Processing and Diagnostics, ed. by D. Bäuerle, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) p. 188

    Google Scholar 

  65. S.J.C. Irvine, J.B. Mullin, J. Tunnicliffe: J. Crystal Growth68, 188 (1984)

    Google Scholar 

  66. S.J.C. Irvine, J. Giess, J.B. Mullin, G.W. Blackmore, O.D. Dosser: J. Vac. Sci. Technol. B3, 1450 (1985)

    Google Scholar 

  67. B.J. Morris: Appl. Phys. Lett.48, 867 (1986)

    Google Scholar 

  68. M.R. Aylett, J. Haigh: Mat. Res. Soc. Symp. Proc.17, 177 (1983)

    Google Scholar 

  69. V.M. Donnelly, D. Brasen, A. Appelbaum, M. Geva: J. Appl. Phys.58, 2022 (1985)

    Google Scholar 

  70. A. Kitai, G.J. Wolga: Mat. Res. Soc. Symp. Proc.17, 141 (1983)

    Google Scholar 

  71. T.R. Jervis: J. Appl. Phys.58, 1400 (1985)

    Google Scholar 

  72. L.J. Rigby: Trans. Farad. Soc.65, 2421 (1969)

    Google Scholar 

  73. D. Braichotte, H. van den Bergh: InLaser Processing and Diagnostics, ed. by D. Bauerle, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) pp. 183–187

    Google Scholar 

  74. H. Schröder, I. Gianinoni, D. Masci, K.L. Kompa: InLaser Processing and Diagnostics, ed. by D. Bäuerle, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) p. 257

    Google Scholar 

  75. K. Suzuki, D. Lubben, J.E. Greene: J. Appl. Phys.58, 979 (1984)

    Google Scholar 

  76. T.F. Deutsch, D.J. Silversmith, R.W. Mountain: Mat. Res. Symp. Proc.17, 129 (1983)

    Google Scholar 

  77. K. Hamano, Y. Numazawa, K. Yamazaki: Jpn. J. Appl. Phys.23, 1209 (1984)

    Google Scholar 

  78. P.K. Boyer, K.A. Emery, H. Harnani, G.J. Collins: Appl. Phys. Lett.45, 979 (1984)

    Google Scholar 

  79. S. Szikora, W. Kräuter, D. Bäuerle: Mater. Lett.2, 263 (1984)

    Google Scholar 

  80. B.K. Janousek, R.C. Carsecallen, P.A. Bertrand: J. Vac. Sci. Technol. A1, 1723 (1983)

    Google Scholar 

  81. Q. Mingxin, R. Monot, H. van den Bergh: Scientia Sinica (Ser. A)27, 531 (1984)

    Google Scholar 

  82. S.P. Kowalczyk, D.L. Miller: J. Vac. Sci. Technol. B3, 1534 (1985)

    Google Scholar 

  83. G.A. West, A. Gupta, K.W. Beeson: Appl. Phys. Lett.47, 476 (1985)

    Google Scholar 

  84. T.F. Deutsch, D.D. Rathman: Appl. Phys. Lett.45, 623 (1984)

    Google Scholar 

  85. A.E. Adams, M.L. Lloyd, S.L. Morgan, N.G. Davis: InLaser Processing and Diagnostics, ed. by Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg, 1984) p. 269

    Google Scholar 

  86. Y.S. Lin, C.P. Yakymyshyn, H.R. Philipp, H.S. Cole, L.M. Levinson: J. Vac. Sci. Technol. B3, 1441 (1985)

    Google Scholar 

  87. H. Ando, H. Inuzuka, M. Konagai, K. Takahashi: J. Appl. Phys.58, 802 (1985)

    Google Scholar 

  88. T.J. Chuang: J. Vac. Sci. Technol. B3, 1408 (1985)

    Google Scholar 

  89. D.W. Squire, C.S. Dulcey, M.C. Lin: J. Vac. Sci. Technol. B3, 1513 (1985)

    Google Scholar 

  90. T.H. Wood, J.C. White, B.A. Thacker: Appl. Phys. Lett.42, 408 (1983)

    Google Scholar 

  91. T. Motooka, S. Gorbatkin, D. Lubben, J.E. Greene: J. Appl. Phys.58, 4397 (1985)

    Google Scholar 

  92. M.H. Chisholm, A.G. Massey, N.R. Thompson: Nature211, 67 (1966)

    Google Scholar 

  93. R.L. Jackson, M.R. Trusheim: J. Am. Chem. Soc.104, 6590 (1982)

    Google Scholar 

  94. M.L. Trusheim, R.L. Jackson: J. Phys. Chem.87, 1910 (1983)

    Google Scholar 

  95. R. Kaplan: J. Vac. Sci. Technol. A1, 551 (1983)

    Google Scholar 

  96. R.J. Madix, J. Benziger: Ann. Rev. Phys. Chem.29, 285 (1978)

    Google Scholar 

  97. C.R. Moylan, T.H. Baum, C.R. Jones: Appl. Phys. A40, 1 (1986)

    Google Scholar 

  98. C.R. Jones, F.A. Houle, C.A. Kovac, T.H. Baum: Appl. Phys. Lett.46, 97 (1985)

    Google Scholar 

  99. H.H. Gilgen: “Laser Chemical Processing of Semiconductor Devices”, ed. by F.A. Houle, T.F. Deutsch, and R.M. Osgood, Jr., Materials Research Society Extended Abstracts (MRS, Pittsburgh 1984) p. 55

    Google Scholar 

  100. F.A. Houle, T.H. Baum, C.R. Moylan: To be published

  101. J.G. Calvert, J.N. Pitts, Jr.:Photochemistry (Wiley, New York 1966) pp. 377–427

    Google Scholar 

  102. J.C.C. Fan, H.J. Zieger, R.P. Gale, R.L. Chapman: Appl. Phys. Lett.36, 158 (1980)

    Google Scholar 

  103. G. Auvert, D. Bensahel, A. Georges, V.T. Nguyen, P. Henoc, F. Morin, P. Coissard: Appl. Phys. Lett.38, 613 (1981)

    Google Scholar 

  104. G.J. Fisanick, J.B. Hopkins, M.E. Gross, M.D. Fennell, K.J. Schnoes: Appl. Phys. Lett.46, 1184 (1985)

    Google Scholar 

  105. R.B. Jackman, J.S. Foord, A.E. Adams, M.L. Lloyd: J. Appl. Phys.59, 2031 (1986)

    Google Scholar 

  106. S.D. Allen, R.Y. Jan, S.M. Mazuk, S.D. Vernon: J. Appl. Phys.58, 327 (1985)

    Google Scholar 

  107. S.D. Allen, J.A. Goldstone, J.P. Stone, R.Y. Jan: J. Appl. Phys.59, 1653 (1986)

    Google Scholar 

  108. K. Piglmayer, J. Doppelbauer, D. Bäuerle: Mat. Res. Soc. Symp. Proc.29, 47 (1984)

    Google Scholar 

  109. Y.C. Du, U. Kempfer, K. Piglmayer, D. Bäuerle: Appl. Phys. A39, 167 (1986)

    Google Scholar 

  110. L. Baufay, F.A. Houle, R.J. Wilson: To be published

  111. D.V. Podlesnik, H.H. Gilgen, R.M. Osgood, Jr.: Appl. Phys. Lett.45, 563 (1984)

    Google Scholar 

  112. D.V. Podlesnik, H.H. Gilgen, R.M. Osgood, Jr.: Appl. Phys. Lett.48, 496 (1986)

    Google Scholar 

  113. C. Arnone, M. Rothschild, D.J. Ehrlich: Appl. Phys. Lett.48, 736 (1986)

    Google Scholar 

  114. J. Cheng, P.A. Kohl: Mater. Res. Soc. Symp. Proc.29, 127 (1984)

    Google Scholar 

  115. B. Braren, R. Srinivasan: J. Vac. Sci. Technol. B3, 913 (1985)

    Google Scholar 

  116. P.A. Temple, M.J. Soileau: IEEE J. QE-17, 2067 (1981)

    Google Scholar 

  117. S.R.J. Brueck, D.J. Ehrlich: Phys. Rev. Lett.48, 1678 (1982)

    Google Scholar 

  118. R.M. Osgood, Jr., D.J. Ehrlich: Opt. Lett.7, 385 (1982)

    Google Scholar 

  119. R.J. Wilson, F.A. Houle: Phys. Rev. Lett.55, 2184 (1985)

    Google Scholar 

  120. J.F. Young, J.E. Sipe, H.M. van Driel: Phys. Rev. B30, 2001 (1984) and references therein

    Google Scholar 

  121. C.J. Chen, H.H. Gilgen, R.M. Osgood, Jr.: Opt. Lett.10, 173 (1985)

    Google Scholar 

  122. D.J. Ehrlich, S.R.J. Brueck: Appl. Phys. Lett.47, 216 (1985)

    Google Scholar 

  123. J. Gersten, A. Nitzan: J. Chem. Phys.75, 1139 (1981)

    Google Scholar 

  124. A. Nitzan, L.E. Brus: J. Chem. Phys.74, 5321 (1981)

    Google Scholar 

  125. A. Nitzan, L.E. Brus: J. Chem. Phys.75, 2205 (1981)

    Google Scholar 

  126. C.J. Chen, R.M. Osgood, Jr.: Phys. Rev. Lett.50, 1705 (1982)

    Google Scholar 

  127. G.M. Goncher, C.B. Harris: J. Chem. Phys.77, 3767 (1982)

    Google Scholar 

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Houle, F.A. Basic mechanisms in laser etching and deposition. Appl. Phys. A 41, 315–330 (1986). https://doi.org/10.1007/BF00616055

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