Skip to main content
Log in

Memory effects in isothermal crystallization. I. Theory

  • Original Contributions
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

A theoretical analysis of transient isothermal crystallization, including relaxational and athermal effects is given. The analysis is based on Kolmogoroff-Avrami-Evans transformation equation and nucleation theory of Turnbull and Fisher. The memory of previous structures manifests itself in the distribution of atomic (molecular) clusters which determines the initial number of crystal nuclei and the initial rate of thermal nucleation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kolmogoroff AN (1937) Izvestiya Akademii Nauk SSSR, Ser Math 3:335

    Google Scholar 

  2. Avrami M, J Chem Phys 7:1103 (1939); ibid 8:212 (1940); ibid 9:177 (1941)

    Google Scholar 

  3. Evans UR (1945) Trans Faraday Soc 41:365

    Google Scholar 

  4. Johnson WA, Mehl RF (1939) Trans AIME 135:416

    Google Scholar 

  5. Turnbull D, Fisher JC (1949) J Chem Phys 17:71

    Google Scholar 

  6. Ziabicki A (1986) J Chem Phys 85:3042

    Google Scholar 

  7. Fisher JC, Hollomon JH, Turnbull DJ (1948) Appl Phys 19:775

    Google Scholar 

  8. Ziabicki AJ (1968) Chem Phys 66

  9. Ziabicki A, IUPAC Symposium on Macromolecules, Prague 1965, preprint p-344

  10. Coenen M (1964) Kolloid Z 194:136

    Google Scholar 

  11. Monasse B, Haudin JM (1986) Colloid & Polymer Sci 264:117

    Google Scholar 

  12. Colomer Vilanova P, Monserrat Ribes S, Martin Guzman G (1985) Polymer 26:423

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ziabicki, A., Alfonso, G.C. Memory effects in isothermal crystallization. I. Theory. Colloid Polym Sci 272, 1027–1042 (1994). https://doi.org/10.1007/BF00652372

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00652372

Key words

Navigation