Abstract
Resistivity and magnetic susceptibility measurements of HgSe:Fe have been performed down to 30 mK and in the magnetic field range 50 mOe-3 kOe. Previously observed high conductivities of HgSe:Fe in the mixed valence region of Fe donors have been found to remain unchanged down to the lowest measured temperatures, indicating a minor influence of the resonant scattering and Kondo effect. This points to a weak k-d hybridization and substantiates classification of HgSe:Fe as an inhomogeneous mixed-valence system in which intersite Coulomb interactions impose spatial correlations in positions of charged centers. A resistive and inductive indication of superconductivity has been detected in some samples. The phenomenon is assigned to the presence of Hg-related superconducting inclusions and the associated proximity effect. This interpretation explains the field and temperature dependence of the resistivity and magnetic susceptibility, as well as being consistent with a sensitivity of the effect on deviations from stoichiometry and on annealing in Se vapor.
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Lenard, A., Dietl, T., Sawicki, M. et al. Millikelvin studies of mixed-valence HgSe:Fe. J Low Temp Phys 80, 15–29 (1990). https://doi.org/10.1007/BF00683112
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DOI: https://doi.org/10.1007/BF00683112