Abstract
A new cluster-type monomer [Fe3O(OCOCH=CH2)6]OH · 3H2O was synthesized by the reaction of acrylic acid with freshly prepared iron hydroxide. The monomer was characterized by various physicochemical methods. It has been shown that the acid residues are bound to the metal atoms through carboxyl groups in a bridge-like or bidentate fashion, and the double bond does not participate in the coordination. The mechanism of thermal fragmentation of the [Fe3O(OCOCH=CH2)6]+ cluster was studied. It was demonstrated that the radical polymerization of this monomer involved bidentate acrylate groups. No reduction of Fe3+ during the polymerization was observed.
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For part 32 see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1739–1743, October, 1993.
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Shul'ga, Y.M., Roshchupkina, O.S., Dzhardimalieva, G.I. et al. Preparation and reactivity of metal-containing monomers. Russ Chem Bull 42, 1661–1665 (1993). https://doi.org/10.1007/BF00697035
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DOI: https://doi.org/10.1007/BF00697035