Abstract
Primary product compositions from FT-CO-hydrogenation have been obtained. A kinetic model has been used to calculate rate constants, rates and probabilities of the elemental surface reactions as a function of carbon number from product composition data. Formation of the catalytic system in the initial stage of an experiment is characterized by selectivity changes as related to elemental surface reactions.
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Schulz, H., Erich, E., Gorre, H. et al. Regularities of selectivity as a key for discriminating FT-surface reactions and formation of the dynamic system. Catal Lett 7, 157–167 (1990). https://doi.org/10.1007/BF00764499
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DOI: https://doi.org/10.1007/BF00764499