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Catalytic oxidative dimerization of methane to form C2-compounds over Arppe's phase oxychlorides of Bi, La and Sm

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Abstract

Three distinct examples of Arppe's phase (M24O31Cl10; M = Bi, La, Sm), which has a structure related to that of the layered oxychloride BiOCl, have been used as monophasic catalysts for the oxidative dehydrogenation of CH4. The stability and performance of these rival those of the best catalysts previously reported.

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Author notes

  1. Wataru Ueda

    Present address: Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, 227, Yokohama, Japan

Authors and Affiliations

  1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, 227, Yokohama, Japan

    Wataru Ueda, Fuyuhiko Sakyu, Toshio Isozaki & Yutaka Morikawa

  2. Davy Faraday Research Laboratory, The Royal Institution, 21, Albemarle Street, W1X 4BS, London, UK

    John M. Thomas

Authors
  1. Wataru Ueda
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  2. Fuyuhiko Sakyu
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  3. Toshio Isozaki
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  4. Yutaka Morikawa
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  5. John M. Thomas
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Ueda, W., Sakyu, F., Isozaki, T. et al. Catalytic oxidative dimerization of methane to form C2-compounds over Arppe's phase oxychlorides of Bi, La and Sm. Catal Lett 10, 83–89 (1991). https://doi.org/10.1007/BF00764739

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  • DOI: https://doi.org/10.1007/BF00764739

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