Abstract
The reaction of CO and H2 on alumina-supported Pd catalysts (2, 5 and 10 wt% Pd) has been studied by a transient pulse technique in vacuum (Temporal-Analysis-of-Products (TAP) reactor). CHO species were formed on a hydrogen-treated catalyst surface at temperatures between 423 and 530 K by the interaction of hydrogen solved in the palladium metal and CO (adsorbed at 300 K after reduction). The CHO species were released into the gas phase when hydrogen was pulsed over the catalysts. CHO is assumed to be an intermediate in the hydrogenation of CO to CH4 starting at 560 K. No methanol was observed under the experimental conditions applied.
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References
L. Kieken and M. Boudart,Proc. 10th Int. Congr. on Catalysis, O 90, Budapest 1992.
J.A. Anderson, J. Chem. Soc. Faraday Trans. 88 (1992) 1197.
K.I. Choi and M.A. Vannice, J. Catal. 131 (1992) 1.
M.A. Vannice and R.L. Garten, Ind. Eng. Chem. Prod. Res. Dev. 18 (1979) 186.
H. Niizuma, T. Mori, A. Miyamoto, T. Hattori, H. Masuda, H. Imai and Y. Murakami, J. Chem. Soc. Chem. Commun. (1982) 562.
M.L. Poutsma, L.F. Elek, P.A. Ibarbia, A.P. Risch and J.A. Rabo, J. Catal. 52 (1978) 157.
J.P. Hindermann. A. Chakor-Alami and R. Kieffer,Proc. 8th Int. Congr. on Catalysis, II-163, Berlin 1988.
V. Ponec, Surf. Sci. 272 (1992) 111.
J.P. Hindermann, G.J. Hutchings and A. Kiennemann, Catal. Rev.-Sci. Eng. 35 (1993) 1.
S. Trautmann, M. Baerns and A. Auroux, J. Catal. 136 (1992) 613.
A. Palazov, G. Kadinov, Ch. Bonev and D. Shopov, J. Catal. 74 (1981) 44.
G. Pacchioni, P. Fantucci, J. Koutecky and V. Ponec, J. Catal. 112 (1988) 34.
K.J. Leary, J.N. Michaels and A.M. Stacy, Langmuir 4 (1988) 1251.
E.C. Hsiao and J.L. Falconer, J. Catal. 132 (1991) 145.
B. Chen and J.L. Falconer, J. Catal. 134 (1992) 737.
L.V. Nosova, M.V. Stenin and Yu.A. Ryndin, Appl. Surf. Sci. 55 (1992) 43.
G. van der Lee and V. Ponec, Catal. Rev.-Sci. Eng. 29 (1987) 183.
S. Trautmann, PhD. Thesis, Ruhr-University Bochum, Germany (1994).
J.S. Rieck and A.T. Bell, J. Catal. 99 (1986) 262.
S. Karski and T. Paryjczak, React. Kinet. Catal. Lett. 18 (1981) 405.
J.T. Gleaves, J.R. Ebner and T.C. Kuechler, Catal. Rev.-Sci. Eng. 30 (1988) 49.
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Rothaemel, M., Zanthoff, H.W. & Baerns, M. Formation of CHO during interaction of CO and H2 on alumina-supported Pd catalysts. Catal Lett 28, 321–328 (1994). https://doi.org/10.1007/BF00806062
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DOI: https://doi.org/10.1007/BF00806062