Abstract
By using pulse surface reaction rate analysis (PSRA), the detailed structure of the intermediate hydrocarbon species was revealed by measuring the dynamic behavior of both CO and H2 produced from the CO2-CH4 reaction on supported Ni catalysts. It was found that the number of hydrogen atoms involved in the intermediate was different from one catalyst support to another: 2.7 for MgO, 2.5 for ZnO, 2.4 for Al2O3,1.9 for TiO2, and 1.0 for SiO2.
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Osaki, T., Masuda, H. & Mori, T. Intermediate hydrocarbon species for the CO2-CH4 reaction on supported Ni catalysts. Catal Lett 29, 33–37 (1994). https://doi.org/10.1007/BF00814249
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DOI: https://doi.org/10.1007/BF00814249