Skip to main content
Log in

Some fundamental aspects of levelling and brightening in metal electrodeposition

  • Reviews of Applied Electrochemistry 29
  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

This review concerns fundamental aspects of levelling and brightening in the electrodeposition of metals. The most important effects of additives, such as the grain refinement of the deposit, polarization of the cathode, incorporation of additives in the deposit, the change of the orientation of crystals and the synergism of additives are presented. The mechanisms proposed to explain the action of additives in metal electrodeposition are classified taking into account the rate determining step of the process. The main mechanisms are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. P. Hoar,Trans. Inst. Met. Finish 29 (1953) 302.

    Google Scholar 

  2. A. G. Betts, ‘Lead Refining by Electrolysis’, J. Wiley & Sons, New York (1908).

    Google Scholar 

  3. C. J. Krauss,J. Metals 28 (1976) 4.

    Google Scholar 

  4. R. C. Kerby and H. E. Jackson,Can. Metal Q 17 (1978) 125.

    Google Scholar 

  5. F. Smyers, G. B. Lantz and F. Mathers, US Pat. 2827 410 (Cl. 204-114) (1957).

  6. G. R. Quimby, US Pat. 3 554 884 (Cl. C 22d) (1968).

  7. G. H. Turner, US Pat, 2 877 165 (Cl. 207-114) (1957).

  8. G. H. Turner, Can. Pat. 681 943 (1964).

  9. L. Gianeles, US Pat. 2 773 819 (Cl. 204-53) (1954).

  10. A. G. Gray, US Pat. 2 415 169 (Cl. 204-53) (1942).

  11. E. Ghali and M. Girgis,Metall. Trans. B 16B (1985) 489.

    Google Scholar 

  12. A. V. Krusenstjern, ‘Edellmetall-Galvanotechnik’, Eugen G. Leuze Verlag, Saulgau/Württ (1970) p. 43.

    Google Scholar 

  13. L. Oniciu and E. Grünwâld, ‘Galvanotechnica’, Ed. St. Encicl., Bucureşti (1980).

    Google Scholar 

  14. M. Schlötter, Ger. Pat. 1235103 (1967),cf. [13].

  15. Riedel WMH, Ger. Pat. 1 182 014 (1964),cf. [13].

  16. R. Weiner,Metallwirtschaft 21 472 (1943).

    Google Scholar 

  17. Ger. Pat. 837 794 (1952),cf. [12].

  18. V. P. Kuppin, E. A. Nechaev, F. Y. Danilov, S. A. Panasenko and V. K. Kudinova,Elektrokhimijia 22(9) (1986) 1246.

    Google Scholar 

  19. L. L. Barber Jr., US Pat 4 502 926 (Cl. 204-451; C 25 D 3/02) (1985).

  20. A. Y. Lee, E. R. Cole Jr., D. L. Paulson, Bureau of Mines, Report of Invest. No. 8401 (1979).

  21. Th. C. Franklin, V. Tetten, A. Aktan,J. Electrochem. Soc. 135(7) (1988) 1638.

    Google Scholar 

  22. J. D. Thomas,Proc. Am. Electroplaters Soc. 43 (1956) 60.

    Google Scholar 

  23. O. Kardos, D. G. Foulke, Advances in Electrochemistry and Electrochemical Engineering, Vol. 2 (edited by Ch. W. Tobias), Interscience Publishers, New York (1966) p. 145.

    Google Scholar 

  24. V. Kohlschüter,Trans. Electrochem. Soc. 45 (1924) 229.

    Google Scholar 

  25. E. Liebreiĉh,Trans. Faraday Soc. 31 (1935) 1188.

    Google Scholar 

  26. W. Blum, A. O. Beckman and W. R. Meyer,Trans. Electrochem. Soc. 30 (1941) 249.

    Google Scholar 

  27. R. Weil and R. A. Paquin,J. Electrochem. Soc. 107 (1960). 87.

    Google Scholar 

  28. G. T. Rogers, M. J. Ware and R. V. Fellows,J. Electrochem. Soc. 107 (1960) 677.

    Google Scholar 

  29. S. A. Watson and J. Edwards,Trans. Inst. Met. Finish. 34 (1957) 167.

    Google Scholar 

  30. B. Ke, J. J. Heekstra, B. C. Sason Jr. and D. Trivich,J. Electrochem. Soc. 106 (1959) 382.

    Google Scholar 

  31. E. Raub and K. Müller,Metalloberfläche 17 (1963) 97.

    Google Scholar 

  32. H. W. Dettner and R. Elze, ‘Handbuch der Galvanotechnik’, vol. 2, C. Hanser Verlag, München (1966) 293.

    Google Scholar 

  33. E. Grünwald, Rom. Pat. 42 205/23 (1963).

  34. Idem, Cs. Värhely, Rom. Pat. 47 482/5 (1966).

  35. T. Bereczky, E. Grünwald and I. Crişan, Rom. Pat. 52 310/4 (1970).

  36. Idem, US Pat. 3 637 475 (1972).

  37. E. Grünwald,Rev. de Chimie 24 (1973) 539.

    Google Scholar 

  38. H. Benninghoff, ‘Forschung und Praxis der sowjetischen Galvanotechnik’, E. G. Leuze Verlag, Saulgau/Württ (1962).

    Google Scholar 

  39. L. Oniciu, L. Mureşan, V. A. Topan, A. Pântea and D. Gherţoiu, Proc. of 37th Meeting of ISE, Vilnius, USSR, vol IV (1986) 545.

    Google Scholar 

  40. A. R. Despić, Deposition and Dissolution of Metals and Alloys. Part B, in ‘Comprehensive Treatise of Electrochemistry’, vol. 7, Plenum, New York (1983).

    Google Scholar 

  41. C. C. Roth and H. Leidheiser,J. Electrochem. Soc. 100 (1953) 533.

    Google Scholar 

  42. P. S. Bindra, A. Ph. David, R. T. Galasco and D. N. Light, Eur. Pat. Appl. EP 114 647 (Cl. Gol, N 27/46) (1984),cf. CA 102, 105 470 f (1985).

  43. P. Delahay and I. Trachtenberg,J. Am. Soc. 80 (1958) 2094.

    Google Scholar 

  44. R. Weiner and G. Klein,Metalloberfläche 10 (1956) 17.

    Google Scholar 

  45. 13 (1959) 269.

    Google Scholar 

  46. R. Weiner,Galvanotechnik 54 (1963) 361.

    Google Scholar 

  47. O. Kardos,Plating 61 (1974) 129 229 316.

    Google Scholar 

  48. M. Jaksić,J. Electroanal. Chem. 242 (1988) 21.

    Google Scholar 

  49. S. Beacom and B. Riley,J. Electrochem. Soc. 106 (1959) 309.

    Google Scholar 

  50. 107 (1960) 785.

    Google Scholar 

  51. 108 (1961) 758.

    Google Scholar 

  52. E. B. Saubestre,Plating 45 (1958) 1219.

    Google Scholar 

  53. M. A. Loshkarev, Loginov, Sh. G. Pilarov and O. N. Tolkachev,Ukr. Khim. Zh. 51 (3) (1985) 261.

    Google Scholar 

  54. M. Leisch and K. D. Rendulic,J. Physique Tome 45 (1984) 477 (cm(suppl. no. 12, C9).

    Google Scholar 

  55. M. Leisch and K. D. Rendulic,Z. Metallkde 75 (1984) 459.

    Google Scholar 

  56. A. K. N. Reddy,J. Electroanal. Chem. 6 (1963) 141.

    Google Scholar 

  57. D. J. Mackinnon, J. M. Brannen and P. L. Fenn,J. Appl. Electrochem. 17 (1987) 1129.

    Google Scholar 

  58. D. R. Turner and G. R. Johnson,J. Electrochem. Soc. 109 (1962) 798.

    Google Scholar 

  59. E. Grünwald, Procedee moderne de protecţie a supraféţelor, MICHODPT, Bucureşti (1969).

  60. T. C. Franklin,Surf. Coat. Technol. 30 (1987) 415.

    Google Scholar 

  61. H. Leidheiser,Z. Elektrochem. 59 (1955) 756.

    Google Scholar 

  62. H. Gerischer,62 (1958) 256.

    Google Scholar 

  63. D. G. Foulke,Metal Finishing 54 (1956) 52.

    Google Scholar 

  64. L. Oniciu, V. A. Topan, L. Mureşan and D. Gherţoiu, Proc. 2nd Nat. Symp. Appl. Electrochem., Timişoara, vol 2 (1986) 231.

    Google Scholar 

  65. D. Rolle and J. W. Schultze,Electrochim. Acta 31 (1986) 991.

    Google Scholar 

  66. L. Oniciu, St. Ivăşcan, M. Apostolescu and E. Schmidt, “Coroziunea metaleler’, Ed. St. Encicl., Bucureşti (1986).

    Google Scholar 

  67. M. Sluyters-Rehbach and J. H. Sluyters,Electrochim. Acta 33 (1988) 983.

    Google Scholar 

  68. R. Andreu, M. Sluyters-Rehbach and J. H. Sluyters,J. Electroanal. Chem. 171 (1984) 139.

    Google Scholar 

  69. S. Fletcher,Mater. Australas 20 (1988) 16.

    Google Scholar 

  70. F. Miyashita and G. Miyatani,Technol. Reports of Kansai University 18 (1977) 87.

    Google Scholar 

  71. T. Bereczky and E. Grünwald, Korróziós figyelö5 (1973) 195.

    Google Scholar 

  72. Z. Stanković,Erzmetall 38 (7/8) (1985) 365.

    Google Scholar 

  73. V. F. Vargalyuk, Yu. M. Loshkarev, V. A. Polonskii and N. Kvyatovskaya,Prikl. Elektrokhim; Teor. Tekhnol. Zashch. Svoitsva Galvanicheskileh Pokrytii 27 (1984),cf. CA 102, 35 273 t (1985).

  74. T. C. Franklin, J. Darlington and R. Fierre,J. Electrochem. Soc. 133 (1986) 893.

    Google Scholar 

  75. B. A. Afanasév,Elektrochimiya 16 (1980) 296.

    Google Scholar 

  76. L. D. Kuchenenko and A. V. Lizogub,18 (1982) 282.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Oniciu, L., Mureşan, L. Some fundamental aspects of levelling and brightening in metal electrodeposition. J Appl Electrochem 21, 565–574 (1991). https://doi.org/10.1007/BF01024843

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01024843

Keywords

Navigation