Abstract
Thermal desorption spectra are calculated for a one-dimensional chain and for a two-dimensional square lattice using the transfer-matrix technique and Monte Carlo simulations. Lateral interactions of adsorbed particles cause a splitting of spectra. The repulsive three-body interactions are shown to lead to an inequality of the integral intensities of the thermal desorption peaks.
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Myshlyavtsev, A.V., Sales, J.L., Zgrablich, G. et al. The effect of three-body interactions on thermal desorption spectra. J Stat Phys 58, 1029–1039 (1990). https://doi.org/10.1007/BF01026561
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DOI: https://doi.org/10.1007/BF01026561