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The electrochemistry of Magnéli phase titanium oxide ceramic electrodes Part II: Ozone generation at Ebonex and Ebonex/lead dioxide anodes

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Abstract

Uncoated Ebonex is not a suitable anode material for the generation of ozone. By contrast, Ebonex electroplated with PbO2 can be highly stable in the forcing conditions essential to the formation of ozone and gives current yields comparable to lead dioxide on other substrates in both acid and neutral electrolytes.

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References

  1. D. P. Semchenko, V. I. Lyubushkin and E. T. Lyubushkina,Soviet Electrochem. 9 (1973) 1641.

    Google Scholar 

  2. H. P. Fritz, J. C. G. Thanos and D. W. Wabner,Z. Naturforsch. 34b (1979) 1617.

    Google Scholar 

  3. P. C. Foller and C. W. Tobias,J. Phys. Chem. 85 (1981) 3238.

    Google Scholar 

  4. ,J. Electrochem. Soc. 129 (1982) 506.

    Google Scholar 

  5. 129 (1982) 567.

    Google Scholar 

  6. J. C. G. Thanos, H. P. Fritz and D. W. Wabner,J. Appl. Electrochem. 14 (1984) 389.

    Google Scholar 

  7. J. C. G. Thanos and D. W. Wabner,Electrochim. Acta 30 (1985) 753.

    Google Scholar 

  8. J. Electroanal. Chem. 182 (1985) 37.

    Google Scholar 

  9. E. R. Kötz and S. Stucki,J. Electroanal. Chem. 228 (1987) 407.

    Google Scholar 

  10. S. Stucki, G. Theis, R. Kötz, H. Devantay and H. J. Christen,J. Electrochem. Soc. 132 (1985) 367.

    Google Scholar 

  11. H. Baumann and S. Stucki,Swiss Chem. 8 (1986) 31.

    Google Scholar 

  12. L. Vogel and H. P. Klein,Brown Boveri Review 8 (1986) 451.

    Google Scholar 

  13. S. Stucki, H. Baumann, R. Kötz and H. J. Christen,J. Appl. Electrochem. 17 (1987) 773.

    Google Scholar 

  14. P. C. Foller and M. L. Goodwin,Ozone Sci. and Engng. 6 (1984) 29.

    Google Scholar 

  15. ,Chem. Eng. Prog. 81 March (1985) 49.

    Google Scholar 

  16. R. L. Clarke, Second International Forum on Electrolysis in the Chemical Industry, Deerfield Beach, Florida, November, 1988.

  17. P. C. S. Hayfield and R. L. Clarke, in Proceedings of the Electrochemical Society Meeting, Los Angeles (1989).

  18. R. L. Clarke and S. K. Harnsberger,Am. Lab. 20 (6A) (1988) 6.

    Google Scholar 

  19. P. C. S. Hayfield, US Patent 4422917 (1983).

  20. R. J. Pollock, J. F. Houlihan, A. N. Bain and B. S. Coryea,Mater. Res. Bull. 19 (1984) 17.

    Google Scholar 

  21. S. K. Harnsberger and I. Romoda,Plat. & Surf. Finish July (1990).

  22. M. Mayr, W. Blatt, B. Busse and H. Heinke, Fourth International Forum on Electrolysis in the Chemical Industry, Fort Lauderdale, Florida, November, 1990.

  23. R. L. Clarke, unpublished work.

  24. R. R. Miller-Folk, R. E. Noftle and D. Pletcher,J. Electroanal. Chem. 274 (1989) 257.

    Google Scholar 

  25. J. E. Graves, D. Pletcher, R. L. Clarke and F. C. Walsh,J. Appl. Electrochem.,22 (1991) 848.

    Google Scholar 

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Graves, J.E., Pletcher, D., Clarke, R.L. et al. The electrochemistry of Magnéli phase titanium oxide ceramic electrodes Part II: Ozone generation at Ebonex and Ebonex/lead dioxide anodes. J Appl Electrochem 22, 200–203 (1992). https://doi.org/10.1007/BF01030178

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  • DOI: https://doi.org/10.1007/BF01030178

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