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Morphological and mechanical properties of extruded polypropylene/nylon-6 blends

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Abstract

Blends of polypropylene and nylon-6 extruded into ribbons at varying draw ratios generated laminar morphologies under our conditions. For the binary system, the size and distribution of the dispersed phase is coarse. The addition of an ionomer to the nylon prior to blending compatibilized the phases and produced much finer domains. The tensile properties of the virgin matrix material respond to the draw ratio in a parabolic manner attaining a maximum at intermediate values. Blending with nylon-6 attenuates the effect without improving the tensiles markedly. The compatibilized system however demonstrates greatly improved mechanical properties.

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References

  1. J. M. Starita,Trans. Soc. Rheol. 16 (1972) 339.

    Google Scholar 

  2. W. M. Barentsen andD. Heikens,Polymer 14 (1973) 579.

    Google Scholar 

  3. D. Heikens andW. M. Barentsen,ibid. 18 (1977) 69.

    Google Scholar 

  4. T. Kunori andP. H. Geil,J. Macromol. Sci.-Phys. B18 (1980) 93, 135.

    Google Scholar 

  5. A. P. Plochocki,Polym. Engng Sci. 23 (1983) 618.

    Google Scholar 

  6. K. Min, J. L. White, J. F. Fellers,J. Appl. Polym. Sci. 29 (1984) 2117.

    Google Scholar 

  7. S. Endo, K. Min, J. L. White andT. Kyu,Polym. Engng Sci. 26 (1986) 45.

    Google Scholar 

  8. B. D. Favis, J. P. Chalifoux andP. Van Gheluwe,SPE Technical Papers 33 (1987) 1326.

    Google Scholar 

  9. B. D. Favis andJ. P. Chalifoux,Polym. Engng Sci. 27 (1987) 1591.

    Google Scholar 

  10. J. R. Stell, D. R. Paul, J. W. Barlow,Polym. Engng Sci. 16 (7) 496 (1976).

    Google Scholar 

  11. N. P. Krasmikova, E. V. Kotova, G. V. Vinogradov andZ. Pelzbauer,J. Appl. Polym. Sci. 22 (1978) 2081.

    Google Scholar 

  12. M. V. Tsebrenko, N. M. Renzanova andG. V. Vinogradov,Polym. Engng Sci. 20 (1980) 1023.

    Google Scholar 

  13. P. Albihn, P. Franzen, J. Kubat andM. Rigdahl,J. Appl. Polym. Sci. 32 (1986) 4837.

    Google Scholar 

  14. P. M. Subramanian,Polym. Engng Sci. 25 (1985) 483.

    Google Scholar 

  15. P. M. Subramanian andV. Mehra,ibid. 27 (1987) 663.

    Google Scholar 

  16. V. E. Dreval, G. V. Vinogradov, E. P. Plotnikova, M. P. Zabugina, N. P. Krasnikova, E. V. Kotova andZ. Pelzbauer,Rheol Acta 22 (1983) 102.

    Google Scholar 

  17. J. J. Elmendorp,Polym. Engng Sci. 26 (1986) 418.

    Google Scholar 

  18. M. R. Kamal, I. A. Jinnah andL. A. Utracki,ibid. 24 (1984) 1337.

    Google Scholar 

  19. J. H. Briston, “Plastic Films”, 2nd Edn, Longman, New York (1983) pp. 19, 51.

    Google Scholar 

  20. P. Galli, S. Danesi andT. Simonazzi,Polym. Engng Sci. 24 (1984) 544.

    Google Scholar 

  21. F. Ide andA. Hasegawa,J. Appl. Polym. Sci. 18 (1974) 963.

    Google Scholar 

  22. D. Braun andU. Eisenlohr,Kunstoffe 65 (1975) 9.

    Google Scholar 

  23. B. R. Liang, J. L. White, J. E. Spruiell andB. Goswami,J. Appl. Polym. Sci. 28 (1983) 2011.

    Google Scholar 

  24. H. K. Chuang andC. D. Han,Adv. Chem. 206 (1984) 172.

    Google Scholar 

  25. K. Min, J. L. White andJ. F. Fellers,Polym. Engng Sci. 24 (1984) 1327.

    Google Scholar 

  26. W. J. MacKnight, R. W. Lenz, P. V. Musto andR. J. Somani,ibid. 25 (1985) 1124.

    Google Scholar 

  27. C. D. Han andH. K. Chuang,J. Appl. Polym. Sci. 30 (1985) 2431, 2457.

    Google Scholar 

  28. L. A. Utracki, M. Dumoulin andP. Toma,Polym. Engng Sci. 26 (1986) 34.

    Google Scholar 

  29. L. D'Orazio, C. Mancarella, E. Martuscelli, A. Casale, A. Filipi andF. Speroni,J. Mater. Sci. 21 (1986) 989.

    Google Scholar 

  30. E. C. Bernhardt, “Processing of Thermoplastic Materials” SPE Plastics Engineering Series (1974) p. 258.

  31. H. J. Yoo,Polym. Engng Sci. 27 (1987) 192.

    Google Scholar 

  32. H. Brody,J. Appl. Polym. Sci. 31 (1986) 2753.

    Google Scholar 

  33. L. E. Nielsen, “Mechanical Properties of Polymers and Composites”, Vol. 2, Dekker, New York (1974) p. 285.

    Google Scholar 

  34. M. J. Shankernarayanan, D. C. Sun, M. Kojima andJ. H. Magill,Int. Pol. Processing 1 (1987) 66.

    Google Scholar 

  35. B. Brew andI. M. Ward,Polymer 19 (1978) 1338.

    Google Scholar 

  36. M. A. Hallam, D. L. M. Cansfield, I. M. Ward andG. Pollard,J. Mater. Sci. 21 (1986) 4199.

    Google Scholar 

  37. P. G. Andersen, S. H. Carr,Polym. Engng Sci. 16 (1976) 217.

    Google Scholar 

  38. J. W. Ladbury,Plast. Instit., Trans. 28 (1960) 184.

    Google Scholar 

  39. I. Lee, S. Turner andR. T. Woodhams,Pol. Compos. 3 (1982) 212.

    Google Scholar 

  40. H. Voss, J. H. Magill andK. Friedrich,J. Appl. Polym. Sci. 33 (1987) 1745.

    Google Scholar 

  41. C. L. Beatty andW. J. Stauffer,Adv. Chem. 154 (1976) 112.

    Google Scholar 

  42. P. Van Gheluwe, to be published.

  43. A. Rudin andH. P. Schreiber,Polym. Engng Sci. 23 (1983) 422.

    Google Scholar 

  44. D. Campbell andM. M. Qayyum,J. Polym. Sci. 18 (1980) 83.

    Google Scholar 

  45. L. Bartosiewicz andC. J. Kelly,Adv. Pol. Technol. 7 (1987) 21.

    Google Scholar 

  46. S. L. Sakellarides andA. J. McHugh,Rheol. Acta. 26 (1987) 64.

    Google Scholar 

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Van Gheluwe, P., Favis, B.D. & Chalifoux, J.P. Morphological and mechanical properties of extruded polypropylene/nylon-6 blends. J Mater Sci 23, 3910–3920 (1988). https://doi.org/10.1007/BF01106813

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