Skip to main content
SpringerLink
Log in

Corrosion protection on copper by new polymeric agents — polyvinylimidazoles

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Fourier transform infrared reflection-absorption spectroscopy (FTIRRAS) is applied to the study of corrosion protection of copper by an organic coating. Poly-N-vinylimidazole (PVI(1)) and poly-4(5)-vinylimidazole (PVI(4)) are demonstrated to be effective new polymeric anticorrosion agents for copper at elevated temperatures. Oxidation of copper is suppressed even at 400° C. PVI(1) and PVI(4) are more effective anti-oxidants than the most commonly used corrosion inhibitors, benzotriazole and undecylimidazole, at elevated temperatures. These new polymeric agents are water soluble and easy to treat the metal surface with.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. B. Cotton, Proceedings of the 2nd International Congress on Metallic Corrosion, NACE, New York (1963).

    Google Scholar 

  2. J. B. Cotton andI. R. Scholes,Brit. Corros. J. 2 (1967) 1.

    Google Scholar 

  3. S. Yoshida andH. Ishida,J. Mater. Sci. 19 (1984) 2323.

    Google Scholar 

  4. I. Dugdale andJ. B. Cotton,Corros. Sci. 3 (1963) 69.

    Google Scholar 

  5. R. Walker,Anti-Corrosion 17 (1970) 9.

    Google Scholar 

  6. S. M. Mayanna andT. H. V. Setty,Corros. Sci. 15 (1975) 625.

    Google Scholar 

  7. S. Yoshida andH. Ishida,J. Chem. Phys. 78 (1983). 6960.

    Google Scholar 

  8. N. K. Patel, J. Franco andI. S. Patel,J. Ind. Chem. Soc. 54 (1977) 815.

    Google Scholar 

  9. G. W. Poling, International Copper Research Association Project No. 185, February (1979).

  10. G. N. Ekilik, V. P. Grigorev andV. V. Ekilik,Zashch. Met. 14 (1978) 357.

    Google Scholar 

  11. D. Chadwick andT. Hashemi,J. Electron. Spectrosc. Rel. Phenom. 10 (1977) 79.

    Google Scholar 

  12. Idem, Corros. Sci. 18 (1978) 39.

    Google Scholar 

  13. A. R. Siedle, R. A. Velapoldi andN. Erickson,Appl. Surf. Sci. 3 (1979) 229.

    Google Scholar 

  14. S. Thiboult,Corros. Sci. 17 (1977) 701.

    Google Scholar 

  15. N. D. Hobbins andR. F. Roberts,Surf. Technol. 9 (1979) 235.

    Google Scholar 

  16. G. W. Poling,Corros. Sci. 10 (1970) 359.

    Google Scholar 

  17. J. Benard,Acta Metall. 8 (1960) 272.

    Google Scholar 

  18. F. Mansfeld, T. Smith andE. P. Parry,Corrosion 27 (1971) 289.

    Google Scholar 

  19. R. F. Roberts,J. Electron Spectrosc. Rel. Phenom. 4 (1974) 273.

    Google Scholar 

  20. D. Chadwick andT. Hashemi,Corros. Sci. 18 (1979) 457.

    Google Scholar 

  21. J. W. Truesdell andM. R. Van De Mark,J. Electrochem. Soc. 129 (1982) 2673.

    Google Scholar 

  22. Katayama Chemical Works Co, Ltd., Jpn. Kokai Tokkyo Koho JP57185 988 (1982).

  23. S. D. Zeinalov, M. M. Talybov, S. A. Mamedov andN. M. Gasanov,Korroz. Zashch. Neftegazov, Prom-sti. 3 (1983) 7.

    Google Scholar 

  24. P. Guerit, P. Du Manoir andJ. Oliver, Ger. Offen. DE 3220931 (1982).

  25. Katayama Chemical Works Co, Ltd., Jpn. Kokai Tokkyo Koho JP 58 58 285 (1983).

    Google Scholar 

  26. Katayama Chemical Works Co, Ltd., Jpn. Kokai Tokkyo Koho JP 58 67 873 (1983).

    Google Scholar 

  27. A. Lupu, R. Avram, P. Popescu, M. V. Popescu, M. V. Spiliadis andV. P. Pietris,Rom. RO 79 (1982) 222.

    Google Scholar 

  28. M. Fradique, Eur. Pat. Appl. EP 79236 (1983).

  29. J. C. Lumaret, S. Gosset, M. Huchette, Ger. Offen. DE 3 232 396 (1983).

  30. S. S. Abd El Rehim, F. M. Tohamy andM. M. Seleet,Surf. Technol. 21 (1984) 169.

    Google Scholar 

  31. A. P. Brynza, L. I. Gerasyutina, V. P. Fedash andE. Ya Baibarova,Zashch. Met. 19 (1983) 961.

    Google Scholar 

  32. Kurita Water Industries, Ltd., Jpn. Kokai Tokkyo Koho JP 58164790 (1983).

  33. Sanyo Chemical Industries, Ltd., Jpn. Kokai Tokkyo Koho JP 59 23 885 (1984).

    Google Scholar 

  34. R. Annand, D. Redmore andB. Rushton, US Patent 3 450 646 (1969).

  35. Idem, US Patent 3 509046 (1970).

  36. J. Ehreke andW. Stichel,GWF, Gas-Wasserfach: Wasser/Abwasser 124 (1983) 473.

    Google Scholar 

  37. M. G. Bondar, N. Ya. Kirillova, L. I. Makhonina, V. I. Martynenko, V. I. Nazarova, A. G. Ovcharov andV. P. Reshetov, USSR SU 1067086 (1984).

  38. S. A. Francis andA. H. Ellison,J. Opt. Soc. Amer. 49 (1959) 130.

    Google Scholar 

  39. R. G. Greenler,J. Chem. Phys. 44 (1966) 310.

    Google Scholar 

  40. J. S. Tan andA. R. Sochor,Macromolecules 14 (1981) 1700.

    Google Scholar 

  41. P. M. Henrichs, L. R. Whitlock, A. R. Sochor andJ. S. Tan,ibid. 13 (1980) 1375.

    Google Scholar 

  42. C. G. Overberger andN. Vorchheimer,J. Amer. Chem. Soc. 85 (1963) 951.

    Google Scholar 

  43. R. G. Greenler, R. R. Rahn andJ. P. Schwartz,J. Catal. 23 (1971) 42.

    Google Scholar 

  44. P. Dawson, M. M. Hargreave andG. R. Wilkinson,J. Phys. Chem. Sol. 34 (1973) 2201.

    Google Scholar 

  45. F. J. Boerio andL. Armogan,Appl. Spectrosc. 32 (1978) 509.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Macromolecular Science, Case Western Reserve University, 44106, Cleveland, Ohio, USA

    Frederick P. Eng & Hatsuo Ishida

Authors
  1. Frederick P. Eng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hatsuo Ishida
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eng, F.P., Ishida, H. Corrosion protection on copper by new polymeric agents — polyvinylimidazoles. J Mater Sci 21, 1561–1568 (1986). https://doi.org/10.1007/BF01114709

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01114709

Keywords

Search

Navigation