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Mechanically driven syntheses of carbides and silcides

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Abstract

Most metal carbides or slicides may be synthesized at room temperature, by ball milling mixtures of elemental powders for some tens of hours with a vibratory mill. Both stable and metastable compounds containing a high density of defects can be obtained. In general, phases stable at low temperatures are synthesized. This observation allows us to confirm recent estimations for the maximum temperature (∼600 K) attained in these powders during mechanical alloying. Exceptions are found for some MSi2 suicides with M = titanium, iron or molybdenum for which both low- and high-temperature phases are formed.

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Authors and Affiliations

  1. Laboratoire de Science et Génie des Matériaux Métallaiques, associé au CNRS U.A., 159, Ecole des Mines, F-54042, Nancy Cedex, France

    G. Le Caër, E. Bauer-Grosse, A. Pianelli & E. Bouzy

  2. Istituto di Chimica, Universita degli Studi di Udine, Viale Ungheria 43, I-33100, Udine, Italy

    P. Matteazzi

Authors
  1. G. Le Caër
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  2. E. Bauer-Grosse
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  3. A. Pianelli
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  4. E. Bouzy
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  5. P. Matteazzi
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Le Caër, G., Bauer-Grosse, E., Pianelli, A. et al. Mechanically driven syntheses of carbides and silcides. J Mater Sci 25, 4726–4731 (1990). https://doi.org/10.1007/BF01129932

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  • DOI: https://doi.org/10.1007/BF01129932

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