Skip to main content
Log in

Crystallization of gel-derived alumina and alumina-zirconia ceramics

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The crystallization behaviour and phase relations in gel-derived alumina and alumina-zirconia ceramics has been investigated. Zirconia was found to form a limited metastable solid solution with the alumina matrix. When present in solid solution, zirconia phase appeared to enhance rapid growth of corundum grains. There was no apparent grain refinement in the alumina-zirconia composites. The implications of microporous gel structures on the modification of microstructures in these gel-derived ceramics are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. P. Rooksby, in “The X-ray Identification and Crystal Structure of Clay Minerals”, edited by G. Brown (Mineral. Society, London, 1961) pp. 345–92.

    Google Scholar 

  2. R. McPherson,J. Mater. Sci. 8 (1973) 859.

    Google Scholar 

  3. M. S. G. Gani andR. McPherson,ibid. 12 (1977) 999.

    Google Scholar 

  4. P. F. Becher,J. Amer. Ceram. Soc. 64 (1981) 37.

    Google Scholar 

  5. N. Claussen,ibid. 59 (1976) 49.

    Google Scholar 

  6. N. Claussen, J. Steeb andR. Pabst,Bull. Amer. Ceram. Soc. 56 (1977) 559.

    Google Scholar 

  7. J. Steven andG. Evans,Br. Ceram. Trans. J. 83 (1984) 28.

    Google Scholar 

  8. E. P. Butler andA. H. Heuer,Commun. Amer. Ceram. Soc. 65 (1982) C206.

    Google Scholar 

  9. P. F. Becher,J. Amer. Ceram. Soc. 66 (1983) 485–88.

    Google Scholar 

  10. F. F. Lang andM. M. Hirlinger,ibid. 67 (1984) 164.

    Google Scholar 

  11. D. J. Green,ibid. 65 (1982) 610.

    Google Scholar 

  12. S. Hori, M. Yoshimura andS. Somiya, in “Zirconia Ceramics”, edited by S. Somiya and K. Uchida (Rokakuho, Tokyo, 1983) 1–7.

    Google Scholar 

  13. S. Hori, R. Kurita, M. Yoshimura andS. Somiya,J. Mater. Sci. Lett., in press.

  14. M. Yoshimura, S. Kikuyawa andS. Somiya,J. Jpn Ceram. Soc. 91 (1983) 51.

    Google Scholar 

  15. N. Claussen, G. Lindemann andG. Petzow,Ceram. Int. 9 (1983) 83.

    Google Scholar 

  16. B. C. Lippens andJ. H. De Boer,Acta. Crystallogr. 17 (1964) 1312.

    Google Scholar 

  17. A. M. Lejus andR. C. Collongues, “Proceedings of the 5th International Conference on Reactivity of Solids”, edited by Schwab (Elsevier, Amsterdam, 1965) pp. 373–9.

    Google Scholar 

  18. G. C. Whitaker,Adv. Chem. Ser. 23 (1957) 184.

    Google Scholar 

  19. I. M. Low, PhD thesis, Monash University, Australia, 1986.

    Google Scholar 

  20. I. M. Low andR. McPherson, Proceedings of the 11th Australian Ceramic Society Conference (1984) pp. 471–4.

  21. B. E. Yoldas,Bull. Amer. Ceram. Soc. 54 (1975) 289.

    Google Scholar 

  22. P. Tarte,Silicate Ind. 28 (1963) 345.

    Google Scholar 

  23. S. Komarneni andR. Roy,J. Amer. Ceram. Soc. 68 (1985) C243.

    Google Scholar 

  24. B. E. Yoldas,J. Appl. Chem. Biotech. 23 (1973) 803.

    Google Scholar 

  25. M. Kumagai andG. L. Messing,J. Amer. Ceram. Soc. 68 (1985) 500.

    Google Scholar 

  26. S. J. Wilson,J. Solid State Chem. 30 (1979) 247.

    Google Scholar 

  27. F. W. Dynys andJ. W. Halloran,J. Amer. Ceram. Soc. 65 (1982) 442.

    Google Scholar 

  28. R. K. Iller,ibid. 44 (1961) 618.

    Google Scholar 

  29. S. J. Wilson,Mineral. Mag. 43 (1979) 301.

    Google Scholar 

  30. Idem, Proc. Br. Ceram. Soc. 28 (1979) 281.

    Google Scholar 

  31. S. J. Wilson andM. H. Stacey,J. Colloid Interface Sci. 82 (1981) 507.

    Google Scholar 

  32. S. J. Wilson andK. McConnell,J. Solid State Chem. 34 (1980) 315.

    Google Scholar 

  33. F. W. Dynys andJ. W. Halloran, “Ultrafine Processing of Ceramics, Glasses and Composites”, edited by L. L. Hench and D. R. Ulrich (Wiley, New York, 1984) pp. 242–51.

    Google Scholar 

  34. A. F. Wells, “Structural Inorganic Chemistry”, 4th Edn (Clarendon, Oxford, 1975) pp. 450–3.

    Google Scholar 

  35. J. Nedoma,Zesz. Nauk. Akad. Gorn. -hutu. Krakow 22 (1973) 7.

    Google Scholar 

  36. C. R. Kennedy andR. C. Bradt,J. Amer. Ceram. Soc. 56 (1973) 608.

    Google Scholar 

  37. S. J. Bennison andM. P. Harmer,ibid. 66 (1983) C90.

    Google Scholar 

  38. A. Mocellin andW. D. Kingery,ibid. 56 (1973) 309.

    Google Scholar 

  39. M. P. Harmer, E. W. Roberts andR. J. Brook,Trans. J. Br. Ceram. Soc. 78 (1979) 22.

    Google Scholar 

  40. R. J. Brook, Treatise on Materials Science and Technology, Vol. 9, edited by F. F. Y. Wang (Academic, 1976) pp. 331–64.

  41. C. Baudin andJ. S. Moya,J. Amer. Ceram. Soc. 67 (1984) C134.

    Google Scholar 

  42. Y. Suwa, R. Roy andS. Komarneni,ibid. 68 (1985) C238.

    Google Scholar 

  43. Y. Wakao andT. Hibino,J. Jpn Ceram. Soc. 11 (1962) 588.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Low, I.M., McPherson, R. Crystallization of gel-derived alumina and alumina-zirconia ceramics. J Mater Sci 24, 892–898 (1989). https://doi.org/10.1007/BF01148774

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01148774

Keywords

Navigation