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Work of adhesion and contact-angle isotherm of binary alloys on ionocovalent oxides

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Abstract

Using the monolayer approximation for metal-vapour and metal-oxide interfaces and Bragg-Williams statistics, a simple thermodynamic model has been constructed to calculate the variation in contact angle and work of adhesion as a function of composition in binary alloyionocovalent oxide systems. This model has been used to classify the curves of contact angle and the work of adhesion as a function of composition into three main types of isotherm. Model predictions and experimental results are compared using data on binary alloy-monocrystalline alumina systems.

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Authors and Affiliations

  1. Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques, UA 29 CNRS, ENSEEG, BP 75, 38402, Saint Martin D'Heres Cédex, France

    J. G. Li, L. Coudurier & N. EustathoPouLos

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  1. J. G. Li
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  2. L. Coudurier
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  3. N. EustathoPouLos
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Li, J.G., Coudurier, L. & EustathoPouLos, N. Work of adhesion and contact-angle isotherm of binary alloys on ionocovalent oxides. J Mater Sci 24, 1109–1116 (1989). https://doi.org/10.1007/BF01148806

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  • DOI: https://doi.org/10.1007/BF01148806

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