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Thermodynamic properties of liquid zinc-bismuth alloys

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Thermodynamic properties of liquid Zn−Bi alloys were investigated between 5 and 95 at % Zn from the liquidus curve to 750°C using anemf method with a molten salt electrolyte. Partial and integral values were calculated and compared with results from the literature. From theemf data the liquidus curve was calculated. The thermodynamic data of the Zn−Bi system are well established and consistent with the phase diagram. The entropies of mixing of various group IIB-VA systems are compared and discussed with respect to compound formation in the liquid state.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, University of Vienna, Vienna, Austria

    Erhard Hayer,  Kurt L. Komarek & Adolf Mikula

Authors
  1. Erhard Hayer
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  2. Kurt L. Komarek
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  3. Adolf Mikula
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Hayer, E., Komarek, K.L. & Mikula, A. Thermodynamic properties of liquid zinc-bismuth alloys. Monatshefte für Chemie 107, 1437–1448 (1976). https://doi.org/10.1007/BF01153922

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