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X-ray analysis of octakis(tri-p-tolylphosphine) enneagoldtris(hexafluorophosphate), [Au9{P(p-MeC6H4)3}8](PF6)3: A redetermination

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Abstract

A redetermination of the crystal structure of the gold cluster [Au9{P(p-MeC6H4)3}8](PF6)3 has been performed. The compound crystallizes in the tetragonal space group P¯4n2, witha=20.283,c=20.330 Å, andZ=2. The structure was determined by a combination of Patterson and Fourier methods, with diffractometer data, and refined by least-squares methods toR=0.065 for 2435 reflections.

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Authors and Affiliations

  1. Research Institute for Materials, University of Nijmegen, Toernooiveld, 6525, ED Nijmegen, The Netherlands

    Jan M. M. Smits, Paul T. Beurskens, Jan J. Bour & Frans A. Vollenbroek

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  1. Jan M. M. Smits
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  2. Paul T. Beurskens
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  3. Jan J. Bour
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  4. Frans A. Vollenbroek
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Smits, J.M.M., Beurskens, P.T., Bour, J.J. et al. X-ray analysis of octakis(tri-p-tolylphosphine) enneagoldtris(hexafluorophosphate), [Au9{P(p-MeC6H4)3}8](PF6)3: A redetermination. Journal of Crystallographic and Spectroscopic Research 13, 365–372 (1983). https://doi.org/10.1007/BF01161299

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  • DOI: https://doi.org/10.1007/BF01161299

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