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Crystal and molecular structure of triphenylarsine

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Abstract

Triphenylarsine crystallizes in the triclinic space groupP¯1 (No. 2),a=11.200(2),b=15.263(7),c=17.871(6) Å,α=84.63(5),β=80.21(5), γ=86.41(6)°,Z=8, with four molecules in the asymmetric unit. The structure was solved by direct methods and refined in the initial stages by full-matrix least squares and finally by block-diagonal least-squares methods toR=0.055 for 3537 reflections. The dimensions and the conformations of the four independent molecules are almost identical. The molecules do not exhibitC 3v symmetry.

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Authors and Affiliations

  1. Department of Chemistry, University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia

    Mazhar-ul-Haque, Hasan A. Tayim, Jamil Ahmed & William Horne

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  1. Mazhar-ul-Haque
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  2. Hasan A. Tayim
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  3. Jamil Ahmed
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  4. William Horne
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Mazhar-ul-Haque, Tayim, H.A., Ahmed, J. et al. Crystal and molecular structure of triphenylarsine. Journal of Crystallographic and Spectroscopic Research 15, 561–571 (1985). https://doi.org/10.1007/BF01164771

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  • DOI: https://doi.org/10.1007/BF01164771

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