Abstract
Partial molar volumes in water at 25°C have been determined for a number of carbohydrates, including mono-, di-, tri-, tetra-, penta-, hexa-, hepta-, and polysaccharides and their derivatives. The experimental values can be calculated from the van der Waals volumes of the molecules if account is taken of the shrinkage in volume caused by hydrogen-bonding of solvent molecules to the hydroxyl groups of the sugars.
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References
F. Franks, J. R. Ravenhill, and D. S. Reid,J. Solution Chem. 1, 3 (1972).
S. Terasawa, H. Itsuki, and S. Arakawa,J. Phys. Chem. 79, 2345 (1975).
J. T. Edward and P. G. Farrell,Can. J. Chem. 53, 2965 (1975).
A. Bondi,J. Phys. Chem. 68, 441 (1964).
A. Bondi,Physical Properties of Molecular Crystals, Liquids, and Glasses (John Wiley, New York, 1968), Chap. XIV.
J. T. Edward,J. Chem. Educ. 47, 261 (1970).
J. T. Edward, P. G. Farrell, and F. Shahidi,J. Chem. Soc. Faraday Trans. 1, submitted.
A. Bondi,J. Phys. Chem. 58, 929 (1959).
M. Ihnat and D. A. I. Goring,Can. J. Chem. 45, 2353 (1967).
F. W. Parrish, A. S. Perlin, and E. T. Reuss,Can. J. Chem. 38, 2094 (1960).
P. C. Manor and W. Saenger,J. Am. Chem. Soc. 96, 2630 (1974).
R. K. McMullan, W. Saenger, J. Fayos, and D. Mootz,Carbohydr. Res. 31, 24 (1973).
E. W. Tiepel and K. E. Gubbins,J. Phys. Chem. 76, 3044 (1972).
L. G. Longsworth,Electrochemistry in Biology and Medicine, T. Shedlovsky, ed. (Wiley, New York, 1955), Chap. 12.
J. L. Neal and D. A. I. Goring,J. Phys. Chem. 74, 658 (1970).
J. L. Neal and D. A. I. Goring,Can. J. Chem. 48, 3745 (1970).
E. L. Eliel, N. L. Allinger, S. J. Angyal, and G. A. Morrison,Conformational Analysis (Interscience Publishers, New York, 1965), pp. 172–178; M. A. Kabayama and D. Patterson,Can. J. Chem. 36, 563 (1958).
G. Mann, M. Mühlstädt, and J. Braband,Tetrahedron 24, 3607 (1968).
M. Ihnat and D. A. I. Goring,Can. J. Chem. 45, 2353 (1967).
G. M. Brown, P. Dubreuil, F. M. Ichhaporia, and J. E. Desnoyers,Can. J. Chem. 48, 2525 (1970).
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Shahidi, F., Farrell, P.G. & Edward, J.T. Partial molar volumes of organic compounds in water. III. Carbohydrates. J Solution Chem 5, 807–816 (1976). https://doi.org/10.1007/BF01167236
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DOI: https://doi.org/10.1007/BF01167236