Abstract
Procedures are described for the fabrication of fibrous composites based on magnesiumlithium alloys as a matrix. Such composites have been produced containing planar random and aligned (continuous and discontinuous) fibres of carbon, alumina and silicon carbide. For all of these, except silicon carbide whiskers, significant fibre degradation occurred, during fabrication or subsequent heat treatments, either by chemical reaction or by grain boundary penetration of lithium. Further consequences of the high atomic mobility exhibited by the matrix are manifest in the mechanical behaviour of the composites. Although considerable property enhancement is possible by fibre reinforcement, a significant diffusional contribution to the stress relaxation mechanisms results in a dependence of work hardening rate and failure strain on temperature and strain rate, even around room temperature and at relatively high strain rates. It is concluded that, although the system presents many practical difficulties, it is worthy of further study.
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References
T. W. Chou, A. Kelly andA. Okura,Composites 16 (1985) 187–206.
B. A. Mickucki, S. O. Shook, W. E. Mercer andW. G. Green, “Magnesium-matrix composites at DOW: Status Update”, Conference International Magnesium Association, Los Angeles, (International Magnesium Association, 1986).
B. J. MacLean andM. S. Misra, “Thermal mechanical behaviour of graphite/magnesium composites”, 195–212, Proceedings Symposium. “Mechanical Behaviour of MetalMatrix Composites” (1982), edited by J. E. Hack and M. F. Amateau, Metallurgical Society of AIME, Pennsylvania, (1983).
J. E. Hack, R. A. Page andG. R. Leverant,Metall. Trans. 15A (1984) 1389–1396.
R. A. Page, J. E. Hack, R. Sherman andG. R. Leverant,ibid. 15A (1984), 1397–1405.
J. T. Evans,Acta Metall. 34 (1986) 2075–2083.
D. Webster,Metall. Trans. 13A (1982) 1511–1519.
R. T. Swann andD. M. Easterling,Composites 15 (1984) 305–309.
A. A. Nayeb-Hashemi, J. B. Clark andA. D. Petton,Bull. Alloy Phase Diagrams 5 (1984) 365–374.
J. H. Jackson, P. D. Frost, A. C. Loonam, L. W. Eastwood andC. H. Lorig,Trans. TMS-AIME 185 (1949) 149–168.
Y. Iwadate, M. Lassouari, F. Lantelme andM. Chemla,J. Appl. Electrochem. 17 (1987) 385–397.
F. D. Richardson, “Physical chemistry of melts in metallurgy”, (Academic, New York 1974).
T. W. Clyne andJ. F. Mason,Metall. Trans. 18A (1987) 1519–1530.
C. A. Stanford-Beale andT. W. Clyne,Composites Sci. and Technol. 35 (1989) 121–157.
J. D. Birchall,Trans. J. Brit. Ceram. Soc. 82 (1983) 143–145.
G. R. Cappleman, J. F. Watts andT. W. Clyne,J. Mater. Sci. 20 (1985) 2159–2168.
S. Yajima, Y. Hasegawa, J. Hayashi andM. Iimura,ibid. 13 (1978) 2569–2576.
G. Simon andA. R. Bunsell,ibid. 19 (1984) 3649–3657.
C. M. Warwick andT. W. Clyne, “Microstructural stability of fibrous composites based on Mg-Li alloys” in 3rd European Conference on Composite Materials, Bordeaux, edited by A. Bunsell, P. Lamicq and A. Massiah. (Elsevier, 1989) pp. 205–212.
R. Warren andC. H. Andersson,Composites 15 (1984) 16–24, 101–111.
R. C. Mehan, M. R. Jackson andM. D. McConnell,J. Mater. Sci. 18 (1983) 3195–3205.
R. R. Kieschke, R. E. Somekh andT. W. Clyne, “The protection of SiC monofilaments against attack in metal matrix composites by sputter-deposited barrier layers”, in preparation.
“Janaf Thermochemical Tables, 2nd edn”, US Department of Commerce, NSRDS-NBS, 37 (1971).
I. Barin andO. Knacke, “Thermochemical Properties of Inorganic Substances”, (Springer, New York, 1973).
A. YamamotoTokai Carbon, UK patent GB211533A, (1983).
J. F. Mason andT. W. Clyne, “Microstructural development and mechanical behaviour of whisker-reinforced Mg-Li alloys”, in 3rd European Conference on Composite Materials, Bordeaux, edited by A. Bunsell, P. Lamicq and A. Massiah (Elsevier, 1989) pp. 213–220.
J. Harding, M. Taya, B. Derby andS. Pickard, “An investigation of the high strain rate deformation of SiCw/2124 Al composite”, Proc. ICCM VI/ECCM 2, 2.224–2.233, edited by F. L. Mathews, N. C. R. Buskell, J. M. Hodgkinson and J. Morton (Elsevier, London, 1987).
S. M. Pickard, B. Derby, J. Harding andM. Taya,Scripta Metall. 22 (1988) 601–606.
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Mason, J.F., Warwick, C.M., Smith, P.J. et al. Magnesium-lithium alloys in metal matrix composites — A preliminary report. J Mater Sci 24, 3934–3946 (1989). https://doi.org/10.1007/BF01168957
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DOI: https://doi.org/10.1007/BF01168957