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Anodic polarization and corrosion of WC-Co hardmetals containing small amounts of Cr3C2 and/or VC

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Abstract

The anodic polarization and corrosion properties of commercial WC-Co hardmetals with different grain sizes and containing small amounts of Cr3C2 and/or VC in acid (pH 2.8), acid/3% NaCl, and neutral 3% NaCl solutions, have been measured using potentiokinetic and linear polarization conductance techniques. An increase in grain size increased the passive current density. Small additions of Cr3C2 increased substantially the corrosion resistance. Small additions of VC had little effect on the corrosion resistance, but in the presence of small additions of Cr3C2 it reduced the beneficial effects of chromium.

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References

  1. E. A. Almond,Mater. Design 7 (1986) 324.

    Google Scholar 

  2. Idem, Powder Metall. 25 (1982) 146.

    Google Scholar 

  3. S. Ekemar, L. Lindholm andT. Hartzell,Refractory and Hard Metals 1 (1982) 37.

    Google Scholar 

  4. E. Kny andL. Schmid,ibid. 6 (1987) 145.

    Google Scholar 

  5. M. H. Ghandehar,J. Electrochem. Soc. 127 (1980) 214.

    Google Scholar 

  6. J. B. Fink, S. A. Hoering andJ. L. Griffith,Wear 108 (1986) 97.

    Google Scholar 

  7. G. D. Mohan andB. E. Klamechi,ibid. 74 (1981) 85.

    Google Scholar 

  8. E. Mosher, L. Peterson andR. Skold,Mater. Perf. 25 (1987) 38.

    Google Scholar 

  9. M. G. Fontana, “Corrosion Engineering”, 3rd Edn (McGraw-Hill, New York, 1986) p. 502.

    Google Scholar 

  10. W. J. Tomlinson andC. R. Linzell,J. Mater. Sci. 23 (1988) 914.

    Google Scholar 

  11. R. D. Armstrong, A. E. Douglas andD. E. Keene,J. Electrochem. Soc. 118 (1971) 568.

    Google Scholar 

  12. J. M. West, “Basic corrosion and oxidation”, 2nd Edn (Ellis Horwood, Chichester, 1986) p. 85.

    Google Scholar 

  13. H. E. Exner,Int. Met. Rev. 4 (1979) 149.

    Google Scholar 

  14. T. Ohtsuka andN. Sato,J. Electrochem. Soc. 128 (1981) 2522.

    Google Scholar 

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Tomlinson, W.J., Ayerst, N.J. Anodic polarization and corrosion of WC-Co hardmetals containing small amounts of Cr3C2 and/or VC. J Mater Sci 24, 2348–2352 (1989). https://doi.org/10.1007/BF01174495

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  • DOI: https://doi.org/10.1007/BF01174495

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