Skip to main content
SpringerLink
Log in

Oxygen semipermeability and electronic conductivity in calcia-stabilized zirconia

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The oxygen semipermeability of calcia-stabilized zirconia tubes has been studied up to 2073 K, by determination of the oxygen flow through the electrolyte tube and it is found to be in good agreement with the theoretical expression for the oxygen electrochemical transport in these materials. The parameterp ⊝, at which the ionic transference number is equal to 0.5, has been deduced from the oxygen permeability measurements and is compared with different results obtained by various techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Janke andH. Richter,Arch. Eisenhüttenw. 50 (1979) 93.

    Google Scholar 

  2. J. Fouletier, P. Fabry andM. Kleitz,J. Electrochem. Soc. 123 (1976) 204.

    Google Scholar 

  3. A. Ounalli, B. Cales, K. Dembinski andJ. F. Baumard,Compt. Rend. Acad. Sci. Paris II-292 (1981) 1185.

    Google Scholar 

  4. P. Kofstad, “Nonstoichiometry, Diffusion and Electrical Conductivity in Binary Metal Oxides” (Wiley Interscience, New York, 1972).

    Google Scholar 

  5. T. H. Etsell andS. N. Flengas' Chem. Rev. 70 (1970) 339.

    Google Scholar 

  6. L. Heyne, “Mass Transport in Oxides” (NBS Special Publication, Washington, 1968) p. 149.

    Google Scholar 

  7. D. Janke andW. A. Fischer,Arch. Eisenhüttenw. 45 (1975) 477.

    Google Scholar 

  8. L. Heyne andN. M. Beekmans,Proc. Brit. Ceram. Soc. 19 (1979) 229.

    Google Scholar 

  9. A. M. Anthony, “Solid Electrolytes”, edited by P. Hagenmuller and W. Van Gool (Academic Press, New-York, 1978) p. 519.

    Google Scholar 

  10. A. Ounalli, Thesis, University of Orléans, France (1981).

    Google Scholar 

  11. T. H. Etsell andS. N. Flengas,J. Electrochem. Soc. 49 (1972) 1.

    Google Scholar 

  12. P. H. Scaife, D. A. J. Swinkels andS. R. Richards,High Temp. Sci. 8 (1976) 31.

    Google Scholar 

  13. M. Iwase andT. Mori,Met. Trans. 9B (1978) 653.

    Google Scholar 

  14. V. S. Stubican andS. P. Ray,J. Amer. Ceram. Soc. 60 (1977) 534.

    Google Scholar 

  15. H. Schmalzried,Z. Physik Chem. 38 (1963) 87.

    Google Scholar 

  16. H. Schmalzried, “Science and Technology of Zirconia”, edited by A. H. Heuer and L. W. Hobbs (The American Ceramic Society, Columbus, USA, 1981) p. 254.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Centre de Recherches sur la Physique des Hautes Températures, C.N.R.S., 45045, Orléans Cédex, France

    B. Cales & J. F. Baumard

Authors
  1. B. Cales
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. F. Baumard
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cales, B., Baumard, J.F. Oxygen semipermeability and electronic conductivity in calcia-stabilized zirconia. J Mater Sci 17, 3243–3248 (1982). https://doi.org/10.1007/BF01203490

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01203490

Keywords

Search

Navigation