Abstract
The monomer [Cr3O(OCOCH=CH2)6]OH was produced by reaction of acrylic acid with fresh chromium hydroxide. This monomer was investigated by a number of physicochemical methods. It was found that acrylate residues are bonded to the metal atomsvia the carboxy group so that the double bond is not involved in coordination. A comparative study of the dissociative fragmentation of the [M3OAcr6]+ clusters, where M is Cr or Fe and Acr is OCOCH=CH2, shows that in the case of Fe the [M3OAcr3]+ fragment is the main product of decomposition of [M3OAcr3]+ cluster cation, whereas this was not observed in the case of Cr. The [M2OAcr4]+ fragments are characteristic of decomposition products of the Cr complex and do not form in the case of Fe. The radical polymerization of Cr-containing monomers results in monodentate coordination of the carboxy groups, which does not appear in the initial monomer.
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Yu. M. Shul'ga, O. S. Roshchupkina, G. I. Dzhardimalieva, I. V. Chernushevich, A. F. Dodonov, Yu. V. Baldokhin, P. Ya. Kolotyrkin, A. S. Rozenberg, and A. D. Pomogailo,Izv. Akad. Nauk, Ser. Khim., 1993, 1739 [Russ. Chem. Bull., 1993,42, 1661 (Engl. Transl.)].
Yu. M. Shul'ga, O. S. Roshchupkina, G. I. Dzhardimalieva, and A. D. Pomogailo,Izv. Akad. Nauk, Ser. Khim., 1993, 1565 [Russ. Chem. Bull., 1993,42, 1498 (Engl. Transl.)].
G. I. Dzhardimalieva, A. D. Pomogailo, V. I. Ponomarev, L. O. Atovmyan, Yu. M. Shul'ga, and A. G. Starikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1988, 1525 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1988,37, 1346 (Engl. Transl.)].
USSR Inventor's Certificate No. 1681340,Byul. Izobr., 1991, No. 36 (in Russian).
I. V. Chernushevich, Ph. D. Phys. Thesis, Chernogolovka, 1991 (in Russian).
B. N. Figgis and G. B. Robertson,Nature, 1965,205, 649.
G. J. Long, W. T. Robinson, W. P. Tappmeyer, and D. L. Bridges,J. Chem. Soc., Dalton Trans., 1973, 573.
S. C. Chang and G. A. Jeffrey,Acta Crystallogr., 1970,26B, 673.
K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, Wiley and Sons, New York, 1962.
K. Nakanishi,Infrared Absorption Spectroscopy: Practical, Holden-Day, San Francisco. 1962.
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For Part 37 seeRuss. Chem. Bull., 1994,43, 232.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1047–1051, June, 1994.
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Shul'ga, Y.M., Chernushevich, I.V., Dzhardimalieva, G.I. et al. Preparation and reactivity of metal-containing monomers. Russ Chem Bull 43, 983–987 (1994). https://doi.org/10.1007/BF01558062
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DOI: https://doi.org/10.1007/BF01558062