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Study of local environment and cation distribution in Al(III) oxides by27Al-NMR with sample rotation at a “magic” angle

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Abstract

The possible use of the27Al-NMR method with sample rotation at a “magic” angle to study the local environment and cation distribution of Al(III) ions in the oxide lattice are exemplified by γ-, х-, χ-, α-Al2O3 and commercial A-1 A1(III) oxide.

Abstract

На примере γ-, х, χ-, α-Al2O3 и промышленной окиси Al(III) “A-1” показаны возможности ЯМР 27 Al при вращении образцов под “магическим” углом для изучения локаьного окружения и катионного распределения ионов Al(III) в решëтке оксидов.

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Mastikhin, V.M., Krivoruchko, O.P., Zolotovskii, B.P. et al. Study of local environment and cation distribution in Al(III) oxides by27Al-NMR with sample rotation at a “magic” angle. React Kinet Catal Lett 18, 117–120 (1982). https://doi.org/10.1007/BF02065148

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  • DOI: https://doi.org/10.1007/BF02065148

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